Competition of superconductivity with the structural transition in Mo3Sb7

Ye, G. Z.; Cheng, J. -G.; Yan, Jiaqiang; Sun, J. P.; Matsubayashi, K.; Yamauchi, T.; Okada, T.; Zhou, Q.; Parker, David S.; Sales, Brian C.; Uwatoko, Yoshiya

doi:10.1103/PhysRevB.94.224508

Title: Competition of superconductivity with the structural transition in $M o_{3} S b_{7}$

Abstract

Prior to the superconducting transition at T_c ≈ 2.3 K, Mo₃Sb₇ undergoes a symmetry-lowering, cubic-to-tetragonal structural transition at T_s = 53 K. In this paper, we have monitored the pressure dependence of these two transitions by measuring the resistivity of Mo₃Sb₇ single crystals under various hydrostatic pressures up to 15 GPa. The application of external pressure enhances T_c but suppresses T_s until P_c ≈ 10 GPa, above which a pressure-induced first order structural transition takes place and is manifested by the phase coexistence in the pressure range 8 ≤ P ≤ 12 GPa. The cubic phase above 12 GPa is also found to be superconducting with a higher T_c ≈ 6 K that decreases slightly with further increasing pressure. The variations with pressure of T_c and T_s satisfy the Bilbro-McMillan equation, i.e. T_cⁿT_s^1-n = constant, thus suggesting the competition of superconductivity with the structural transition that has been proposed to be accompanied with a spin-gap formation at T_s. Finally, this scenario is supported by our first-principles calculations which imply the plausible importance of magnetism that competes with the superconductivity in Mo₃Sb₇.

Authors:

Ye, G. Z. ^[1]; Cheng, J. -G. ^[2]; Yan, Jiaqiang ^[3]; Sun, J. P. ^[4]; Matsubayashi, K. ^[5]; Yamauchi, T. ^[6]; Okada, T. ^[6]; Zhou, Q. ^[7]; Parker, David S. ^[3]; Sales, Brian C. ^[3]; Uwatoko, Yoshiya ^[6]

Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics. Inst. of Physics; Yunnan Univ., Kunming (China). School of Physical Science and Astronomy
Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics. Inst. of Physics; Univ. of Tokyo, Kashiwa (Japan). Inst. for Solid State Physics
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics. Inst. of Physics
Univ. of Tokyo, Kashiwa (Japan). Inst. for Solid State Physics; Univ. of Electro-Communications, Chofu (Japan). Dept. of Engineering Science
Univ. of Tokyo, Kashiwa (Japan). Inst. for Solid State Physics
Yunnan Univ., Kunming (China). School of Physical Science and Astronomy

Publication Date:: Wed Dec 14 00:00:00 EST 2016

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Tokyo, Kashiwa (Japan)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Basic Research Program of China; National Science Foundation of China; Chinese Academy of Sciences; Huazhong Univ. of Science and Technology (China)

Contributing Org.:: Yunnan Univ., Kunming (China); Univ. of Electro-Communications, Chofu (Japan)

OSTI Identifier:: 1338563

Alternate Identifier(s):: OSTI ID: 1335721

Grant/Contract Number:: AC05-00OR22725; 2014CB921500; 11574377; XDB07020100; QYZDB-SSW-SLH013; 2015KF22

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 94; Journal Issue: 22; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Ye, G. Z., Cheng, J. -G., Yan, Jiaqiang, Sun, J. P., Matsubayashi, K., Yamauchi, T., Okada, T., Zhou, Q., Parker, David S., Sales, Brian C., and Uwatoko, Yoshiya. Competition of superconductivity with the structural transition in Mo3Sb7.  United States: N. p., 2016. 
Web.  doi:10.1103/PhysRevB.94.224508.

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                    Ye, G. Z., Cheng, J. -G., Yan, Jiaqiang, Sun, J. P., Matsubayashi, K., Yamauchi, T., Okada, T., Zhou, Q., Parker, David S., Sales, Brian C., & Uwatoko, Yoshiya. Competition of superconductivity with the structural transition in Mo3Sb7.  United States.  https://doi.org/10.1103/PhysRevB.94.224508

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                    Ye, G. Z., Cheng, J. -G., Yan, Jiaqiang, Sun, J. P., Matsubayashi, K., Yamauchi, T., Okada, T., Zhou, Q., Parker, David S., Sales, Brian C., and Uwatoko, Yoshiya. Wed .  
"Competition of superconductivity with the structural transition in Mo3Sb7".  United States.  https://doi.org/10.1103/PhysRevB.94.224508.  https://www.osti.gov/servlets/purl/1338563.

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@article{osti_1338563,

  title        = {Competition of superconductivity with the structural transition in Mo3Sb7},

  author       = {Ye, G. Z. and Cheng, J. -G. and Yan, Jiaqiang and Sun, J. P. and Matsubayashi, K. and Yamauchi, T. and Okada, T. and Zhou, Q. and Parker, David S. and Sales, Brian C. and Uwatoko, Yoshiya},

  abstractNote = {Prior to the superconducting transition at Tc ≈ 2.3 K, Mo3Sb7 undergoes a symmetry-lowering, cubic-to-tetragonal structural transition at Ts = 53 K. In this paper, we have monitored the pressure dependence of these two transitions by measuring the resistivity of Mo3Sb7 single crystals under various hydrostatic pressures up to 15 GPa. The application of external pressure enhances Tc but suppresses Ts until Pc ≈ 10 GPa, above which a pressure-induced first order structural transition takes place and is manifested by the phase coexistence in the pressure range 8 ≤ P ≤ 12 GPa. The cubic phase above 12 GPa is also found to be superconducting with a higher Tc ≈ 6 K that decreases slightly with further increasing pressure. The variations with pressure of Tc and Ts satisfy the Bilbro-McMillan equation, i.e. TcnTs1-n = constant, thus suggesting the competition of superconductivity with the structural transition that has been proposed to be accompanied with a spin-gap formation at Ts. Finally, this scenario is supported by our first-principles calculations which imply the plausible importance of magnetism that competes with the superconductivity in Mo3Sb7.},

  doi          = {10.1103/PhysRevB.94.224508},

  journal      = {Physical Review B},

  number       = 22,

  volume       = 94,

  place        = {United States},

  year         = {Wed Dec 14 00:00:00 EST 2016},

  month        = {Wed Dec 14 00:00:00 EST 2016}

}

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Cited by: 6 works

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Figures / Tables:

Table 1: Characteristic temperatures and fitting parameters to the resistivity data for three Mo₃Sb₇ samples measured in this work.

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Title: Competition of superconductivity with the structural transition in M o 3 S b 7

Abstract

Citation Formats

Figures / Tables:

Development of Palm Cubic Anvil Apparatus for Low Temperature Physics [極低温用超小型キュービックアンビル圧力発生装置の開発] journal, January 2008

Muon-spin rotation measurements of the penetration depth of the Mo 3 Sb 7 superconductor journal, July 2008

Low-temperature specific heat of the superconductor Mo3Sb7 journal, November 2008

Observation of a Spin Gap in the Normal State of Superconducting Mo 3 Sb 7 journal, April 2008

Magnetic and structural phase transitions in Mo 3 Sb 7 journal, March 2009

Anomalous Properties around Magnetic Instability in Heavy Electron Systems journal, March 1995

Pressure studies on the superconductor Mo 3 Sb 7 journal, January 2011

Density functional study of FeS, FeSe, and FeTe: Electronic structure, magnetism, phonons, and superconductivity journal, October 2008

Andreev reflection study of the new magnetic superconductor Mo3Sb7: evidence of gap anisotropy journal, April 2007

The Crystal Structure of Mo3Sb7. journal, January 1966

Structural transition in the normal state of the superconductor Mo3Sb7 journal, May 2009

Low‐temperature and high-pressure apparatus developed at ISSP, University of Tokyo journal, January 2004

Spin Fluctuations and Superconductivity in Mo 3 Sb 7 journal, July 2007

Fragile structural transition in Mo 3 Sb 7 journal, August 2015

Energy gap and upper critical field of the new magnetic superconductor Mo 3 Sb 7 found by the Andreev reflection method journal, April 2006

Evidence for a spin pseudogap in the normal state of superconducting Mo 3 Sb 7 journal, October 2009

Conventional s -wave pairing in the presence of spin fluctuations in superconducting Mo 3 Sb 7 from specific heat measurements journal, March 2008

High temperature thermoelectric properties of Mo 3 Sb 7− x Te x (0.0 ≤ x ≤ 1.8) journal, December 2009

The Challenge of Unconventional Superconductivity journal, April 2011

Integrated-fin gasket for palm cubic-anvil high pressure apparatus journal, September 2014

First-principles comparison of the cubic and tetragonal phases of journal, March 2011

Comment on “Muon-spin-rotation study of the superconducting properties of Mo 3 Sb 7 ” journal, July 2010

Spin Fluctuations in Itinerant Electron Magnetism book, January 1985

Partial Gapping of the Fermi Surface and Superconductivity in Eu x Mo 6 S 8 journal, April 1982

Theoretical model of superconductivity and the martensitic transformation in A 15 compounds journal, September 1976

Single crystal growth and superconductivity of Mo3Sb7 journal, August 2002

Frustration-Induced Valence Bond Crystal and Its Melting in Mo 3 Sb 7 journal, September 2008

Competitive Coexistence of Superconductivity with Antiferromagnetism in CeRhIn 5 journal, July 2006

Critical fields, Pauli paramagnetic limiting, and material parameters of Nb 3 Sn and V 3 Si journal, May 1979

New T3B7 Compounds journal, January 1966

Transition Temperature of Strong-Coupled Superconductors journal, March 1968

Title: Competition of superconductivity with the structural transition in $M o_{3} S b_{7}$

Development of Palm Cubic Anvil Apparatus for Low Temperature Physics [極低温用超小型キュービックアンビル圧力発生装置の開発]
journal, January 2008

Muon-spin rotation measurements of the penetration depth of the ${Mo}_{3} {Sb}_{7}$ superconductor
journal, July 2008

Low-temperature specific heat of the superconductor Mo3Sb7
journal, November 2008

Observation of a Spin Gap in the Normal State of Superconducting ${Mo}_{3} {Sb}_{7}$
journal, April 2008

Magnetic and structural phase transitions in Mo ₃ Sb ₇
journal, March 2009

Anomalous Properties around Magnetic Instability in Heavy Electron Systems
journal, March 1995

Pressure studies on the superconductor Mo ₃ Sb ₇
journal, January 2011

Density functional study of FeS, FeSe, and FeTe: Electronic structure, magnetism, phonons, and superconductivity
journal, October 2008

Andreev reflection study of the new magnetic superconductor Mo3Sb7: evidence of gap anisotropy
journal, April 2007

The Crystal Structure of Mo3Sb7.
journal, January 1966

Structural transition in the normal state of the superconductor Mo3Sb7
journal, May 2009

Low‐temperature and high-pressure apparatus developed at ISSP, University of Tokyo
journal, January 2004

Spin Fluctuations and Superconductivity in ${Mo}_{3} {Sb}_{7}$
journal, July 2007

Fragile structural transition in ${Mo}_{3} {Sb}_{7}$
journal, August 2015

Energy gap and upper critical field of the new magnetic superconductor Mo ₃ Sb ₇ found by the Andreev reflection method
journal, April 2006

Evidence for a spin pseudogap in the normal state of superconducting Mo ₃ Sb ₇
journal, October 2009

Conventional $s$ -wave pairing in the presence of spin fluctuations in superconducting ${Mo}_{3} {Sb}_{7}$ from specific heat measurements
journal, March 2008

High temperature thermoelectric properties of Mo ₃ Sb _{7− x} Te _x (0.0 ≤ x ≤ 1.8)
journal, December 2009

The Challenge of Unconventional Superconductivity
journal, April 2011

Integrated-fin gasket for palm cubic-anvil high pressure apparatus
journal, September 2014

First-principles comparison of the cubic and tetragonal phases of
journal, March 2011

Comment on “Muon-spin-rotation study of the superconducting properties of ${Mo}_{3} {Sb}_{7}$ ”
journal, July 2010

Spin Fluctuations in Itinerant Electron Magnetism
book, January 1985

Partial Gapping of the Fermi Surface and Superconductivity in ${Eu}_{x} {Mo}_{6} S_{8}$
journal, April 1982

Theoretical model of superconductivity and the martensitic transformation in $A 15$ compounds
journal, September 1976

Single crystal growth and superconductivity of Mo3Sb7
journal, August 2002

Frustration-Induced Valence Bond Crystal and Its Melting in ${Mo}_{3} {Sb}_{7}$
journal, September 2008

Competitive Coexistence of Superconductivity with Antiferromagnetism in ${CeRhIn}_{5}$
journal, July 2006

Critical fields, Pauli paramagnetic limiting, and material parameters of ${Nb}_{3}$ Sn and $V_{3}$ Si
journal, May 1979

New T3B7 Compounds
journal, January 1966

Transition Temperature of Strong-Coupled Superconductors
journal, March 1968