Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands
Abstract
In a Cp*Ir complex with a bidentate pyridyl-imidazoline ligand achieved the evolution of 1.02 m3 of H2/CO2 gases by formic acid dehydrogenation without any additives or adjustments in the solution system. Furthermore, the pyridyl-imidazoline moieties provided the optimum pH to be 1.7, resulting in high activity and stability even at very acidic conditions.
- Authors:
-
- National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan)
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
- National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan); CREST, Kawaguchi (Japan). Japan Science and Technology Agency
- CREST, Kawaguchi (Japan). Japan Science and Technology Agency; National Inst. of Advanced Industrial Science and Technology (AIST), Koriyama (Japan). Renewable Energy Research Center
- National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan); CREST, Kawaguchi (Japan). Japan Science and Technology Agency; National Inst. of Advanced Industrial Science and Technology (AIST), Koriyama (Japan). Renewable Energy Research Center
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1335388
- Report Number(s):
- BNL-111792-2016-JA
Journal ID: ISSN 2044-4753; CSTAGD; R&D Project: CO026; KC0304030
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Catalysis Science and Technology
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 4; Journal ID: ISSN 2044-4753
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Onishi, Naoya, Ertem, Mehmed Z., Xu, Shaoan, Tsurusaki, Akihiro, Manaka, Yuichi, Muckerman, James T., Fujita, Etsuko, and Himeda, Yuichiro. Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands. United States: N. p., 2016.
Web. doi:10.1039/c5cy01865j.
Onishi, Naoya, Ertem, Mehmed Z., Xu, Shaoan, Tsurusaki, Akihiro, Manaka, Yuichi, Muckerman, James T., Fujita, Etsuko, & Himeda, Yuichiro. Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands. United States. https://doi.org/10.1039/c5cy01865j
Onishi, Naoya, Ertem, Mehmed Z., Xu, Shaoan, Tsurusaki, Akihiro, Manaka, Yuichi, Muckerman, James T., Fujita, Etsuko, and Himeda, Yuichiro. Thu .
"Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands". United States. https://doi.org/10.1039/c5cy01865j. https://www.osti.gov/servlets/purl/1335388.
@article{osti_1335388,
title = {Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands},
author = {Onishi, Naoya and Ertem, Mehmed Z. and Xu, Shaoan and Tsurusaki, Akihiro and Manaka, Yuichi and Muckerman, James T. and Fujita, Etsuko and Himeda, Yuichiro},
abstractNote = {In a Cp*Ir complex with a bidentate pyridyl-imidazoline ligand achieved the evolution of 1.02 m3 of H2/CO2 gases by formic acid dehydrogenation without any additives or adjustments in the solution system. Furthermore, the pyridyl-imidazoline moieties provided the optimum pH to be 1.7, resulting in high activity and stability even at very acidic conditions.},
doi = {10.1039/c5cy01865j},
journal = {Catalysis Science and Technology},
number = 4,
volume = 6,
place = {United States},
year = {Thu Nov 10 00:00:00 EST 2016},
month = {Thu Nov 10 00:00:00 EST 2016}
}
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