Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO2(111) catalysts: An in situ study of C–C and O–H bond scission

Liu, Zongyuan; Duchon, Tomas; Wang, Huanru; Grinter, David C.; Waluyo, Iradwikanari; Zhou, Jing; Liu, Qiang; Jeong, Beomgyun; Crumlin, Ethan J.; Matolin, Vladimir; Stacchiola, Dario J.; Rodriguez, Jose A.; Senanayake, Sanjaya D.

doi:10.1039/c6cp01212d

Title: Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO₂(111) catalysts: An in situ study of C–C and O–H bond scission

Abstract

In situinvestigation of the surface chemistry of ethanol steam reforming & metal-oxide interactions over Ni–CeOx(111).

Authors:

Liu, Zongyuan ^[1]; Duchon, Tomas ^[2]; Wang, Huanru ^[3]; Grinter, David C. ^[3]; Waluyo, Iradwikanari ^[3]; Zhou, Jing ^[4]; Liu, Qiang ^[5]; Jeong, Beomgyun ^[5]; Crumlin, Ethan J. ^[5]; Matolin, Vladimir ^[2]; Stacchiola, Dario J. ^[3]; Rodriguez, Jose A. ^[1]; Senanayake, Sanjaya D. ^[3]

Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ.,Stony Brook, NY (United States)
Charles Univ. in Prague (Czech Republic)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Univ. of Wyoming, Laramie, WY (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Publication Date:: Thu Mar 31 00:00:00 EDT 2016

Research Org.:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1333206

Alternate Identifier(s):: OSTI ID: 1378777

Report Number(s):: BNL-113212-2016-JA
Journal ID: ISSN 1463-9076; PPCPFQ; R&D Project: CO040; KC0302010

Grant/Contract Number:: SC0012704; AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Physical Chemistry Chemical Physics. PCCP

Additional Journal Information:: Journal Volume: 18; Journal Issue: 25; Journal ID: ISSN 1463-9076

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Liu, Zongyuan, Duchon, Tomas, Wang, Huanru, Grinter, David C., Waluyo, Iradwikanari, Zhou, Jing, Liu, Qiang, Jeong, Beomgyun, Crumlin, Ethan J., Matolin, Vladimir, Stacchiola, Dario J., Rodriguez, Jose A., and Senanayake, Sanjaya D. Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO2(111) catalysts: An in situ study of C–C and O–H bond scission.  United States: N. p., 2016. 
Web.  doi:10.1039/c6cp01212d.

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                    Liu, Zongyuan, Duchon, Tomas, Wang, Huanru, Grinter, David C., Waluyo, Iradwikanari, Zhou, Jing, Liu, Qiang, Jeong, Beomgyun, Crumlin, Ethan J., Matolin, Vladimir, Stacchiola, Dario J., Rodriguez, Jose A., & Senanayake, Sanjaya D. Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO2(111) catalysts: An in situ study of C–C and O–H bond scission.  United States.  https://doi.org/10.1039/c6cp01212d

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                    Liu, Zongyuan, Duchon, Tomas, Wang, Huanru, Grinter, David C., Waluyo, Iradwikanari, Zhou, Jing, Liu, Qiang, Jeong, Beomgyun, Crumlin, Ethan J., Matolin, Vladimir, Stacchiola, Dario J., Rodriguez, Jose A., and Senanayake, Sanjaya D. Thu .  
"Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO2(111) catalysts: An in situ study of C–C and O–H bond scission".  United States.  https://doi.org/10.1039/c6cp01212d.  https://www.osti.gov/servlets/purl/1333206.

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@article{osti_1333206,

  title        = {Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO2(111) catalysts: An in situ study of C–C and O–H bond scission},

  author       = {Liu, Zongyuan and Duchon, Tomas and Wang, Huanru and Grinter, David C. and Waluyo, Iradwikanari and Zhou, Jing and Liu, Qiang and Jeong, Beomgyun and Crumlin, Ethan J. and Matolin, Vladimir and Stacchiola, Dario J. and Rodriguez, Jose A. and Senanayake, Sanjaya D.},

  abstractNote = {In situinvestigation of the surface chemistry of ethanol steam reforming & metal-oxide interactions over Ni–CeOx(111).},

  doi          = {10.1039/c6cp01212d},

  journal      = {Physical Chemistry Chemical Physics. PCCP},

  number       = 25,

  volume       = 18,

  place        = {United States},

  year         = {Thu Mar 31 00:00:00 EDT 2016},

  month        = {Thu Mar 31 00:00:00 EDT 2016}

}

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Journal Article Carrasco, Javier ; Rodriguez, Jose A. ; Lopez-Duran, David ; ... - Angewandte Chemie (International Edition)

Water dissociation is crucial in many catalytic reactions on oxide-supported transition-metal catalysts. Here, supported by experimental and density-functional theory results, we elucidate the effect of the support on O-H bond cleavage activity for nickel/ceria systems. Ambient-pressure O1s photoemission spectra at low Ni loadings on CeO₂(111) reveal a substantially larger amount of OH groups as compared to the bare support. Our computed activation energy barriers for water dissociation show an enhanced reactivity of Ni adatoms on CeO₂(111) compared with pyramidal Ni₄ particles with one Ni atom not in contact with the support, and extended Ni(111) surfaces. At the origin of thismore »« less
Cited by 181
https://doi.org/10.1002/anie.201410697

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Methanol steam reforming over Ni-CeO₂ model and powder catalysts: Pathways to high stability and selectivity for H₂/CO₂ production

Journal Article Liu, Zongyuan ; Yao, Siyu ; Johnston-Peck, Aaron ; ... - Catalysis Today

Here, nickel-ceria has been reported as a very good catalysts for the reforming of methane. Here, the methanol steam reforming reaction on both powder (Ni-CeO₂) and model (Ni-CeO_2-x(111)) catalysts was investigated. The active phase evolution and surface species transformation on powder catalysts were studied via in situ X-ray diffraction (XRD) and diffuse reflectance infrared transform spectroscopy (DRIFTS). Phase transitions of NiO → NiC → Ni and CeO₂ → CeO_2-x were observed during the reaction. The simultaneous production of H₂/CO₂ demonstrates that the active phase of the catalysts contains metallic Ni supported over partially reduced ceria. The DRIFTS experiments indicate thatmore »« less
Cited by 36
https://doi.org/10.1016/j.cattod.2017.08.041

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Title: Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO2(111) catalysts: An in situ study of C–C and O–H bond scission

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Citation Formats

Steam Reforming of Ethanol on Ni/CeO 2 : Reaction Pathway and Interaction between Ni and the CeO 2 Support journal, April 2013

CO 2 Adsorption As a Flat-Lying, Tridentate Carbonate on CeO 2 (100) journal, April 2014

The Unique Properties of the Oxide-Metal Interface: Reaction of Ethanol on an Inverse Model CeO x –Au(111) Catalyst journal, October 2014

Growth of Pt Nanoparticles on Reducible CeO 2 (111) Thin Films: Effect of Nanostructures and Redox Properties of Ceria journal, June 2010

Redox Pathways for HCOOH Decomposition over CeO 2 Surfaces journal, June 2008

Direct Work Function Measurement by Gas Phase Photoelectron Spectroscopy and Its Application on PbS Nanoparticles journal, November 2013

Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering journal, September 2006

CeO2-supported Pt/Ni catalyst for the renewable and clean H2 production via ethanol steam reforming journal, February 2014

The Nature of Water Nucleation Sites on TiO 2 (110) Surfaces Revealed by Ambient Pressure X-ray Photoelectron Spectroscopy journal, June 2007

Bond activation sequence observed in the chemisorption and surface reaction of ethanol on Ni(111) journal, May 1986

Characterization of surface processes at the Ni-based catalyst during the methanation of biomass-derived synthesis gas: X-ray photoelectron spectroscopy (XPS) journal, October 2007

H2 production for MC fuel cell by steam reforming of ethanol over MgO supported Pd, Rh, Ni and Co catalysts journal, October 2004

Reactivity and reaction intermediates for acetic acid adsorbed on CeO2(1 1 1) journal, September 2015

Low temperature catalytic steam reforming of ethanol. 1. The effect of the support on the activity and stability of Pt catalysts journal, April 2010

Water Dissociation on CeO 2 (100) and CeO 2 (111) Thin Films journal, August 2012

The Reactions of Ethanol over Au/CeO2 journal, April 2004

Bio-oil catalytic reforming without steam addition: Application to hydrogen production and studies on its mechanism journal, December 2013

Hydrogen production from ethanol steam reforming over cerium and nickel based oxyhydrides journal, December 2010

Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation journal, July 2015

Reduction Characteristics of Ceria under Ethanol Steam Reforming Conditions: Effect of the Particle Size journal, December 2013

Ethanol steam reforming over MgxNi1−xAl2O3 spinel oxide-supported Rh catalysts journal, July 2005

Infrared reflection-absorption spectroscopy of adsorbed molecules journal, January 1983

Long-Term Passivation of Strongly Interacting Metals with Single-Layer Graphene journal, November 2015

Highly Efficient and Stable CeNiHZOY Nano-Oxyhydride Catalyst for H2 Production from Ethanol at Room Temperature journal, August 2011

Voltammetric and XPS investigations of nickel hydroxide electrochemically dispersed on gold surface electrodes journal, February 1999

Adsorption and Reaction of C 1 −C 3 Alcohols over CeO X (111) Thin Films journal, July 2010

Use of biofuels to produce hydrogen (reformation processes) journal, January 2008

Metal-catalysed steam reforming of ethanol in the production of hydrogen for fuel cell applications journal, November 2002

Water–Gas Shift and CO Methanation Reactions over Ni–CeO2(111) Catalysts journal, January 2011

Acetaldehyde Adsorption and Reaction on CeO 2 (100) Thin Films journal, July 2013

Catalyst deactivation and regeneration in low temperature ethanol steam reforming with Rh/CeO2–ZrO2 catalysts journal, August 2006

Influence of Hydroxyls on Pd Atom Mobility and Clustering on Rutile TiO 2 (011)-2 × 1 journal, May 2014

A Study of the Reactions of Ethanol on CeO2 and Pd/CeO2 by Steady State Reactions, Temperature Programmed Desorption, and In Situ FT-IR journal, September 1999

Efficient Production of Hydrogen over Supported Cobalt Catalysts from Ethanol Steam Reforming journal, July 2002

Decomposition of Acetic Acid on Model Pt/CeO 2 Catalysts: The Effect of Surface Crowding journal, June 2015

Carbon monoxide and carbon dioxide adsorption on cerium oxide studied by Fourier-transform infrared spectroscopy. Part 1.—Formation of carbonate species on dehydroxylated CeO2, at room temperature journal, January 1989

Carbon formation and its influence on ethanol steam reforming over Ni/Al2O3 catalysts journal, May 2007

Interaction of CO with OH on Au(111): HCOO, CO 3 , and HOCO as Key Intermediates in the Water-Gas Shift Reaction journal, October 2009

Production of hydrogen for fuel cells by steam reforming of ethanol over supported noble metal catalysts journal, July 2003

Interactions of Ni Nanoparticles with Reducible CeO 2 (111) Thin Films journal, April 2012

High Activity of Ce1−xNixO2−y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal-Oxide Interactions journal, November 2010

Production of Hydrogen from Ethanol: Review of Reaction Mechanism and Catalyst Deactivation journal, April 2012

Steam reforming of bio-ethanol for the production of hydrogen over ceria-supported Co, Ir and Ni catalysts journal, June 2006

Adsorption and reaction of methanol on thin-film cerium oxide journal, April 2006

Theoretical Studies of the Adsorption of CO and C on Ni(111) and Ni/CeO 2 (111): Evidence of a Strong Metal–Support Interaction journal, April 2013

Hydrogen production by ethanol steam reforming on nickel catalysts: Effect of support modification by CeO 2 and La 2 O 3 journal, May 2015

Electron spectroscopy of single crystal and polycrystalline cerium oxide surfaces journal, July 1998

Ordered Phases of Reduced Ceria As Epitaxial Films on Cu(111) journal, December 2013

Superior performance of Ni–W–Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants journal, January 2015

Formation of metastable phases of Ni-C journal, September 1992

Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy journal, April 2013

Near-Ambient-Pressure X-ray Photoelectron Spectroscopy Study of Methane-Induced Carbon Deposition on Clean and Copper-Modified Polycrystalline Nickel Materials journal, November 2015

Ethanol decomposition on Ni(111): observation of ethoxy formation by IRAS and other methods journal, October 1991

New ambient pressure photoemission endstation at Advanced Light Source beamline 9.3.2 journal, May 2010

In Situ and Theoretical Studies for the Dissociation of Water on an Active Ni/CeO 2 Catalyst: Importance of Strong Metal-Support Interactions for the Cleavage of O-H Bonds journal, February 2015

Ordered cerium oxide thin films grown on Ru(0001) and Ni(111) journal, June 1999

Intermediates Arising from the Water–Gas Shift Reaction over Cu Surfaces: From UHV to Near Atmospheric Pressures journal, March 2015

Corrosion protection properties of cerium layers formed on tinplate journal, March 2004

Differential pulse voltammetric determination of the carcinogenic diamine 4,4′-oxydianiline by electrochemical preconcentration on a MoS2 based sensor journal, November 2019

Growth and structure of ultrathin praseodymium oxide layers on ruthenium(0001) journal, January 2017

Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and methane and alcohol reforming journal, January 2017

Thermal reduction of ceria nanostructures on rhodium(111) and re-oxidation by CO 2 journal, January 2018

A mini review of in situ near-ambient pressure XPS studies on non-noble, late transition metal catalysts journal, January 2019

Effect of ZnO on acid–base properties and catalytic performances of ZnO/ZrO 2 –SiO 2 catalysts in 1,3-butadiene production from ethanol–water mixture journal, January 2019

Threshold catalytic onset of carbon formation on CeO 2 during CO 2 electrolysis: mechanism and inhibition journal, January 2019

New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water journal, October 2017

Title: Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO₂(111) catalysts: An in situ study of C–C and O–H bond scission

Steam Reforming of Ethanol on Ni/CeO ₂ : Reaction Pathway and Interaction between Ni and the CeO ₂ Support
journal, April 2013

CO ₂ Adsorption As a Flat-Lying, Tridentate Carbonate on CeO ₂ (100)
journal, April 2014

The Unique Properties of the Oxide-Metal Interface: Reaction of Ethanol on an Inverse Model CeO _x –Au(111) Catalyst
journal, October 2014

Growth of Pt Nanoparticles on Reducible CeO ₂ (111) Thin Films: Effect of Nanostructures and Redox Properties of Ceria
journal, June 2010

Redox Pathways for HCOOH Decomposition over CeO ₂ Surfaces
journal, June 2008

Direct Work Function Measurement by Gas Phase Photoelectron Spectroscopy and Its Application on PbS Nanoparticles
journal, November 2013

Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
journal, September 2006

CeO2-supported Pt/Ni catalyst for the renewable and clean H2 production via ethanol steam reforming
journal, February 2014

The Nature of Water Nucleation Sites on TiO ₂ (110) Surfaces Revealed by Ambient Pressure X-ray Photoelectron Spectroscopy
journal, June 2007

Bond activation sequence observed in the chemisorption and surface reaction of ethanol on Ni(111)
journal, May 1986

Characterization of surface processes at the Ni-based catalyst during the methanation of biomass-derived synthesis gas: X-ray photoelectron spectroscopy (XPS)
journal, October 2007

H2 production for MC fuel cell by steam reforming of ethanol over MgO supported Pd, Rh, Ni and Co catalysts
journal, October 2004

Reactivity and reaction intermediates for acetic acid adsorbed on CeO2(1 1 1)
journal, September 2015

Low temperature catalytic steam reforming of ethanol. 1. The effect of the support on the activity and stability of Pt catalysts
journal, April 2010

Water Dissociation on CeO ₂ (100) and CeO ₂ (111) Thin Films
journal, August 2012

The Reactions of Ethanol over Au/CeO2
journal, April 2004

Bio-oil catalytic reforming without steam addition: Application to hydrogen production and studies on its mechanism
journal, December 2013

Hydrogen production from ethanol steam reforming over cerium and nickel based oxyhydrides
journal, December 2010

Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO _x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation
journal, July 2015

Reduction Characteristics of Ceria under Ethanol Steam Reforming Conditions: Effect of the Particle Size
journal, December 2013

Ethanol steam reforming over MgxNi1−xAl2O3 spinel oxide-supported Rh catalysts
journal, July 2005

Infrared reflection-absorption spectroscopy of adsorbed molecules
journal, January 1983

Long-Term Passivation of Strongly Interacting Metals with Single-Layer Graphene
journal, November 2015

Highly Efficient and Stable CeNiHZOY Nano-Oxyhydride Catalyst for H2 Production from Ethanol at Room Temperature
journal, August 2011

Voltammetric and XPS investigations of nickel hydroxide electrochemically dispersed on gold surface electrodes
journal, February 1999

Adsorption and Reaction of C ₁ −C ₃ Alcohols over CeO _X (111) Thin Films
journal, July 2010

Use of biofuels to produce hydrogen (reformation processes)
journal, January 2008

Metal-catalysed steam reforming of ethanol in the production of hydrogen for fuel cell applications
journal, November 2002

Water–Gas Shift and CO Methanation Reactions over Ni–CeO2(111) Catalysts
journal, January 2011

Acetaldehyde Adsorption and Reaction on CeO ₂ (100) Thin Films
journal, July 2013

Catalyst deactivation and regeneration in low temperature ethanol steam reforming with Rh/CeO2–ZrO2 catalysts
journal, August 2006

Influence of Hydroxyls on Pd Atom Mobility and Clustering on Rutile TiO ₂ (011)-2 × 1
journal, May 2014

A Study of the Reactions of Ethanol on CeO2 and Pd/CeO2 by Steady State Reactions, Temperature Programmed Desorption, and In Situ FT-IR
journal, September 1999

Efficient Production of Hydrogen over Supported Cobalt Catalysts from Ethanol Steam Reforming
journal, July 2002

Decomposition of Acetic Acid on Model Pt/CeO ₂ Catalysts: The Effect of Surface Crowding
journal, June 2015

Carbon monoxide and carbon dioxide adsorption on cerium oxide studied by Fourier-transform infrared spectroscopy. Part 1.—Formation of carbonate species on dehydroxylated CeO2, at room temperature
journal, January 1989

Carbon formation and its influence on ethanol steam reforming over Ni/Al2O3 catalysts
journal, May 2007

Interaction of CO with OH on Au(111): HCOO, CO ₃ , and HOCO as Key Intermediates in the Water-Gas Shift Reaction
journal, October 2009

Production of hydrogen for fuel cells by steam reforming of ethanol over supported noble metal catalysts
journal, July 2003

Interactions of Ni Nanoparticles with Reducible CeO ₂ (111) Thin Films
journal, April 2012

High Activity of Ce1−xNixO2−y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal-Oxide Interactions
journal, November 2010

Production of Hydrogen from Ethanol: Review of Reaction Mechanism and Catalyst Deactivation
journal, April 2012

Steam reforming of bio-ethanol for the production of hydrogen over ceria-supported Co, Ir and Ni catalysts
journal, June 2006

Adsorption and reaction of methanol on thin-film cerium oxide
journal, April 2006

Theoretical Studies of the Adsorption of CO and C on Ni(111) and Ni/CeO ₂ (111): Evidence of a Strong Metal–Support Interaction
journal, April 2013

Hydrogen production by ethanol steam reforming on nickel catalysts: Effect of support modification by CeO 2 and La 2 O 3
journal, May 2015

Electron spectroscopy of single crystal and polycrystalline cerium oxide surfaces
journal, July 1998

Ordered Phases of Reduced Ceria As Epitaxial Films on Cu(111)
journal, December 2013

Superior performance of Ni–W–Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants
journal, January 2015

Formation of metastable phases of Ni-C
journal, September 1992

Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, April 2013

Near-Ambient-Pressure X-ray Photoelectron Spectroscopy Study of Methane-Induced Carbon Deposition on Clean and Copper-Modified Polycrystalline Nickel Materials
journal, November 2015

Ethanol decomposition on Ni(111): observation of ethoxy formation by IRAS and other methods
journal, October 1991

New ambient pressure photoemission endstation at Advanced Light Source beamline 9.3.2
journal, May 2010

In Situ and Theoretical Studies for the Dissociation of Water on an Active Ni/CeO ₂ Catalyst: Importance of Strong Metal-Support Interactions for the Cleavage of O-H Bonds
journal, February 2015

Ordered cerium oxide thin films grown on Ru(0001) and Ni(111)
journal, June 1999

Intermediates Arising from the Water–Gas Shift Reaction over Cu Surfaces: From UHV to Near Atmospheric Pressures
journal, March 2015

Corrosion protection properties of cerium layers formed on tinplate
journal, March 2004

Differential pulse voltammetric determination of the carcinogenic diamine 4,4′-oxydianiline by electrochemical preconcentration on a MoS2 based sensor
journal, November 2019

Growth and structure of ultrathin praseodymium oxide layers on ruthenium(0001)
journal, January 2017

Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO ₂ hydrogenation, and methane and alcohol reforming
journal, January 2017

Thermal reduction of ceria nanostructures on rhodium(111) and re-oxidation by CO ₂
journal, January 2018

A mini review of in situ near-ambient pressure XPS studies on non-noble, late transition metal catalysts
journal, January 2019

Effect of ZnO on acid–base properties and catalytic performances of ZnO/ZrO ₂ –SiO ₂ catalysts in 1,3-butadiene production from ethanol–water mixture
journal, January 2019

Threshold catalytic onset of carbon formation on CeO ₂ during CO ₂ electrolysis: mechanism and inhibition
journal, January 2019

New Routes for Refinery of Biogenic Platform Chemicals Catalyzed by Cerium Oxide-supported Ruthenium Nanoparticles in Water
journal, October 2017