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Title: CO2 hydrogenation over oxide-supported PtCo catalysts: The role of the oxide support in determining the product selectivity

Abstract

By simply changing the oxide support, the selectivity of a metal–oxide catalysts can be tuned. For the CO2 hydrogenation over PtCo bimetallic catalysts supported on different reducible oxides (CeO2, ZrO2, and TiO2), replacing a TiO2 support by CeO2 or ZrO2 selectively strengthens the binding of C,O-bound and O-bound species at the PtCo–oxide interface, leading to a different product selectivity. Lastly, these results reveal mechanistic insights into how the catalytic performance of metal–oxide catalysts can be fine-tuned.

Authors:
 [1];  [2];  [1];  [1];  [3];  [2];  [1];  [4]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States)
  2. Columbia Univ., New York, NY (United States)
  3. Chinese Academy of Science, Dalian (China)
  4. Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1333197
Alternate Identifier(s):
OSTI ID: 1401667
Report Number(s):
BNL-113193-2016-JA
Journal ID: ISSN 1433-7851; R&D Project: CO035; KC0302010
Grant/Contract Number:  
SC00112704; AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition); Journal Volume: 55; Journal Issue: 28; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Kattel, Shyam, Yu, Weiting, Yang, Xiaofang, Yan, Binhang, Huang, Yanqiang, Wan, Weiming, Liu, Ping, and Chen, Jingguang G. CO2 hydrogenation over oxide-supported PtCo catalysts: The role of the oxide support in determining the product selectivity. United States: N. p., 2016. Web. doi:10.1002/anie.201601661.
Kattel, Shyam, Yu, Weiting, Yang, Xiaofang, Yan, Binhang, Huang, Yanqiang, Wan, Weiming, Liu, Ping, & Chen, Jingguang G. CO2 hydrogenation over oxide-supported PtCo catalysts: The role of the oxide support in determining the product selectivity. United States. doi:10.1002/anie.201601661.
Kattel, Shyam, Yu, Weiting, Yang, Xiaofang, Yan, Binhang, Huang, Yanqiang, Wan, Weiming, Liu, Ping, and Chen, Jingguang G. Mon . "CO2 hydrogenation over oxide-supported PtCo catalysts: The role of the oxide support in determining the product selectivity". United States. doi:10.1002/anie.201601661. https://www.osti.gov/servlets/purl/1333197.
@article{osti_1333197,
title = {CO2 hydrogenation over oxide-supported PtCo catalysts: The role of the oxide support in determining the product selectivity},
author = {Kattel, Shyam and Yu, Weiting and Yang, Xiaofang and Yan, Binhang and Huang, Yanqiang and Wan, Weiming and Liu, Ping and Chen, Jingguang G.},
abstractNote = {By simply changing the oxide support, the selectivity of a metal–oxide catalysts can be tuned. For the CO2 hydrogenation over PtCo bimetallic catalysts supported on different reducible oxides (CeO2, ZrO2, and TiO2), replacing a TiO2 support by CeO2 or ZrO2 selectively strengthens the binding of C,O-bound and O-bound species at the PtCo–oxide interface, leading to a different product selectivity. Lastly, these results reveal mechanistic insights into how the catalytic performance of metal–oxide catalysts can be fine-tuned.},
doi = {10.1002/anie.201601661},
journal = {Angewandte Chemie (International Edition)},
number = 28,
volume = 55,
place = {United States},
year = {2016},
month = {5}
}

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    Works referencing / citing this record:

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