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Title: Understanding the interactions of CO2 with doped and undoped SrTiO3

Abstract

SrTiO3 and doped SrTiO3 have a wide range of applications in different fields. For example, Rh-doped SrTiO3 has been shown to have photocatalytic activity for both hydrogen production and CO2 conversion. In this study, both undoped and Rh-doped SrTiO3 were synthesized by hydrothermal and polymerizable complex methods. Different characterizations techniques including X-ray photoelectron spectroscopy (XPS), XRD, Raman, and UV/Vis spectroscopy were utilized to establish correlations between the preparation methods and the electronic/structural properties of Rh-doped SrTiO3. The presence of dopants and oxygen vacancies substantially influenced the CO2 interactions with the surface, as revealed by the in situ infrared spectroscopic study. As a result, the presence of distinctly different adsorption sites was correlated to oxygen vacancies and oxidation states of Ti and Rh.

Authors:
ORCiD logo [1];  [1];  [1];  [2];  [1];  [1]
  1. Stony Brook Univ., Stony Brook, NY (United States)
  2. Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1333196
Alternate Identifier(s):
OSTI ID: 1400982
Report Number(s):
BNL-113182-2016-JA
Journal ID: ISSN 1864-5631; R&D Project: CO007; KC0301050
Grant/Contract Number:  
SC00112704
Resource Type:
Accepted Manuscript
Journal Name:
ChemSusChem
Additional Journal Information:
Journal Volume: 9; Journal Issue: 14; Journal ID: ISSN 1864-5631
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; SrTiO3; Rh doped SrTiO3; surface modification; electronic structure modification; catalysis

Citation Formats

Wu, Qiyuan, Cen, Jiajie, Goodman, Kenneth R., White, Michael G., Ramakrishnan, Girish, and Orlov, Alexander. Understanding the interactions of CO2 with doped and undoped SrTiO3. United States: N. p., 2016. Web. https://doi.org/10.1002/cssc.201600498.
Wu, Qiyuan, Cen, Jiajie, Goodman, Kenneth R., White, Michael G., Ramakrishnan, Girish, & Orlov, Alexander. Understanding the interactions of CO2 with doped and undoped SrTiO3. United States. https://doi.org/10.1002/cssc.201600498
Wu, Qiyuan, Cen, Jiajie, Goodman, Kenneth R., White, Michael G., Ramakrishnan, Girish, and Orlov, Alexander. Fri . "Understanding the interactions of CO2 with doped and undoped SrTiO3". United States. https://doi.org/10.1002/cssc.201600498. https://www.osti.gov/servlets/purl/1333196.
@article{osti_1333196,
title = {Understanding the interactions of CO2 with doped and undoped SrTiO3},
author = {Wu, Qiyuan and Cen, Jiajie and Goodman, Kenneth R. and White, Michael G. and Ramakrishnan, Girish and Orlov, Alexander},
abstractNote = {SrTiO3 and doped SrTiO3 have a wide range of applications in different fields. For example, Rh-doped SrTiO3 has been shown to have photocatalytic activity for both hydrogen production and CO2 conversion. In this study, both undoped and Rh-doped SrTiO3 were synthesized by hydrothermal and polymerizable complex methods. Different characterizations techniques including X-ray photoelectron spectroscopy (XPS), XRD, Raman, and UV/Vis spectroscopy were utilized to establish correlations between the preparation methods and the electronic/structural properties of Rh-doped SrTiO3. The presence of dopants and oxygen vacancies substantially influenced the CO2 interactions with the surface, as revealed by the in situ infrared spectroscopic study. As a result, the presence of distinctly different adsorption sites was correlated to oxygen vacancies and oxidation states of Ti and Rh.},
doi = {10.1002/cssc.201600498},
journal = {ChemSusChem},
number = 14,
volume = 9,
place = {United States},
year = {2016},
month = {6}
}

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Works referenced in this record:

Fabrication and characterization of Ba1−xKxBiO3/Nb-doped SrTiO3 all-oxide-type Schottky junctions
journal, May 1997

  • Suzuki, Seiji; Yamamoto, Tetsuya; Suzuki, Hiroshi
  • Journal of Applied Physics, Vol. 81, Issue 10
  • DOI: 10.1063/1.365242

Structures and chemistry of the annealed SrTiO3(001) surface
journal, May 1994


Atomic force microscopy study of (001) SrTiO3 surfaces
journal, December 1996


Surfaces of reduced and oxidized SrTiO 3 from atomic force microscopy
journal, August 1999


Formation of micro-crystals on the (100) surface of SrTiO3 at elevated temperatures
journal, July 2000


THE DEFECT STRUCTUFE OF SrTi 1−x Fe x O 3−y ( x = 0–0.8) INVESTIGATED BY ELECTRICAL CONDUCTIVITY MEASUREMENTS AND ELECTRON ENERGY LOSS SPECTROSCOPY (EELS)
journal, June 1997


Photocatalytic Conversion of CO 2 into Renewable Hydrocarbon Fuels: State-of-the-Art Accomplishment, Challenges, and Prospects
journal, May 2014


Heterogeneous photocatalyst materials for water splitting
journal, January 2009

  • Kudo, Akihiko; Miseki, Yugo
  • Chem. Soc. Rev., Vol. 38, Issue 1
  • DOI: 10.1039/B800489G

Strontium titanate photoelectrodes. Efficient photoassisted electrolysis of water at zero applied potential
journal, May 1976

  • Wrighton, Mark S.; Ellis, Arthur B.; Wolczanski, Peter T.
  • Journal of the American Chemical Society, Vol. 98, Issue 10
  • DOI: 10.1021/ja00426a017

Mechanism of photocatalytic decomposition of water into H2 and O2 over NiO$z.sbnd;SrTiO3
journal, November 1986


Photocatalytic decomposition of water into hydrogen and oxygen over nickel(II) oxide-strontium titanate (SrTiO3) powder. 1. Structure of the catalysts
journal, January 1986

  • Domen, Kazunari; Kudo, Akihiko; Onishi, Takaharu
  • The Journal of Physical Chemistry, Vol. 90, Issue 2
  • DOI: 10.1021/j100274a018

Photocatalytic Activities of Noble Metal Ion Doped SrTiO 3 under Visible Light Irradiation
journal, July 2004

  • Konta, Ryoko; Ishii, Tatsuya; Kato, Hideki
  • The Journal of Physical Chemistry B, Vol. 108, Issue 26
  • DOI: 10.1021/jp049556p

Rh-Doped SrTiO 3 Photocatalyst Electrode Showing Cathodic Photocurrent for Water Splitting under Visible-Light Irradiation
journal, August 2011

  • Iwashina, Katsuya; Kudo, Akihiko
  • Journal of the American Chemical Society, Vol. 133, Issue 34
  • DOI: 10.1021/ja2050315

BiVO4–Ru/SrTiO3:Rh composite Z-scheme photocatalyst for solar water splitting
journal, January 2014

  • Jia, Qingxin; Iwase, Akihide; Kudo, Akihiko
  • Chemical Science, Vol. 5, Issue 4
  • DOI: 10.1039/c3sc52810c

Synthesis of highly active rhodium-doped SrTiO3 powders in Z-scheme systems for visible-light-driven photocatalytic overall water splitting
journal, January 2013

  • Kato, Hideki; Sasaki, Yasuyoshi; Shirakura, Nana
  • Journal of Materials Chemistry A, Vol. 1, Issue 39
  • DOI: 10.1039/c3ta12803b

Photocatalytic Activity of SrTiO 3 Codoped with Nitrogen and Lanthanum under Visible Light Illumination
journal, January 2004

  • Miyauchi, Masahiro; Takashio, Minoru; Tobimatsu, Hiroki
  • Langmuir, Vol. 20, Issue 1
  • DOI: 10.1021/la0353125

Atomic scale characterization of oxygen vacancy segregation at SrTiO3 grain boundaries
journal, December 2000

  • Klie, R. F.; Browning, N. D.
  • Applied Physics Letters, Vol. 77, Issue 23
  • DOI: 10.1063/1.1330572

Structural and Electrical Characterization of SrTiO 3 Thin Films Prepared by Metal Organic Chemical Vapor Deposition
journal, September 1993

  • Yamaguchi, Hiromu; Lesaicherre, Pierre-Yves; Sakuma, Toshiyuki
  • Japanese Journal of Applied Physics, Vol. 32, Issue Part 1, No. 9B
  • DOI: 10.1143/JJAP.32.4069

Atomic control and characterization of surface defect states of TiO2 terminated SrTiO3 single crystals
journal, August 2008

  • Kareev, M.; Prosandeev, S.; Liu, J.
  • Applied Physics Letters, Vol. 93, Issue 6
  • DOI: 10.1063/1.2971035

Theoretical Investigation of the Metal-Doped SrTiO 3 Photocatalysts for Water Splitting
journal, March 2012

  • Chen, Hsin-Chieh; Huang, Chao-Wei; Wu, Jeffrey C. S.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 14
  • DOI: 10.1021/jp300910e

Density Functional Characterization of the Electronic Structure and Optical Properties of N-Doped, La-Doped, and N/La-Codoped SrTiO 3
journal, July 2009

  • Wei, Wei; Dai, Ying; Guo, Meng
  • The Journal of Physical Chemistry C, Vol. 113, Issue 33
  • DOI: 10.1021/jp902567j

Elucidation of Rh-Induced In-Gap States of Rh:SrTiO 3 Visible-Light-Driven Photocatalyst by Soft X-ray Spectroscopy and First-Principles Calculations
journal, November 2012

  • Kawasaki, Seiji; Akagi, Kazuto; Nakatsuji, Kan
  • The Journal of Physical Chemistry C, Vol. 116, Issue 46
  • DOI: 10.1021/jp3082529

Temperature Dependence of the Raman Spectrum of SrTiO 3 and KTaO 3
journal, September 1967

  • Perry, C. H.; Fertel, Jeanne H.; McNelly, T. F.
  • The Journal of Chemical Physics, Vol. 47, Issue 5
  • DOI: 10.1063/1.1712142

First‐ and Second‐Order Raman Scattering of SrTiO 3
journal, April 1967

  • Schaufele, R. F.; Weber, M. J.
  • The Journal of Chemical Physics, Vol. 46, Issue 7
  • DOI: 10.1063/1.1841140

Raman Spectrum of Strontium Titanate
journal, March 1968

  • Nilsen, W. G.; Skinner, J. G.
  • The Journal of Chemical Physics, Vol. 48, Issue 5
  • DOI: 10.1063/1.1669418

Electric-Field-Induced Raman Scattering in SrTi O 3 and KTa O 3
journal, October 1968


Synthesis-Dependent First-Order Raman Scattering in SrTiO 3 Nanocubes at Room Temperature
journal, September 2008

  • Rabuffetti, Federico A.; Kim, Hack-Sung; Enterkin, James A.
  • Chemistry of Materials, Vol. 20, Issue 17
  • DOI: 10.1021/cm801192t

SrTiO 3 by XPS
journal, March 1992

  • Vasquez, Richard P.
  • Surface Science Spectra, Vol. 1, Issue 1
  • DOI: 10.1116/1.1247683

Ti 2p and Ti 3p X-ray photoelectron spectra for TiO2, SrTiO3 and BaTiO3
journal, January 1999

  • Oku, Masaoki; Wagatsuma, Kazuaki; Kohiki, Shigemi
  • Physical Chemistry Chemical Physics, Vol. 1, Issue 23
  • DOI: 10.1039/a907161j

The interaction of CO2 and CO with Fe-doped SrTiO3(100) surfaces
journal, June 2011

  • Voigts, F.; Argirusis, Chr.; Maus-Friedrichs, W.
  • Surface and Interface Analysis, Vol. 44, Issue 3
  • DOI: 10.1002/sia.3802

Adsorption and Reaction of CO and CO 2 on Oxidized and Reduced SrTiO 3 (100) Surfaces
journal, May 2005

  • Azad, Samina; Engelhard, Mark H.; Wang, Li-Qiong
  • The Journal of Physical Chemistry B, Vol. 109, Issue 20
  • DOI: 10.1021/jp045864b

Photoemission and quantum chemical study of SrTiO 3 ( 001 ) surfaces and their interaction with CO 2
journal, November 2008


Oxygen incorporation into strontium titanate single crystals from CO2 dissociation
journal, January 2009

  • Argirusis, Chr.; Voigts, F.; Datta, P.
  • Physical Chemistry Chemical Physics, Vol. 11, Issue 17
  • DOI: 10.1039/b901401b

Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes
journal, January 2013

  • Kondratenko, Evgenii V.; Mul, Guido; Baltrusaitis, Jonas
  • Energy & Environmental Science, Vol. 6, Issue 11
  • DOI: 10.1039/c3ee41272e

Photocatalytic activity of hydrogen evolution over Rh doped SrTiO3 prepared by polymerizable complex method
journal, May 2013


Microstructural Evolution of γ-Alumina-Supported Rh upon Aging in Air
journal, August 1997

  • Weng-Sieh, Zara; Gronsky, Ronald; Bell, Alexis T.
  • Journal of Catalysis, Vol. 170, Issue 1
  • DOI: 10.1006/jcat.1997.1738

Epitaxial Rh-doped SrTiO 3 thin film photocathode for water splitting under visible light irradiation
journal, July 2012

  • Kawasaki, S.; Nakatsuji, K.; Yoshinobu, J.
  • Applied Physics Letters, Vol. 101, Issue 3
  • DOI: 10.1063/1.4738371

Self-doped SrTiO3−δ photocatalyst with enhanced activity for artificial photosynthesis under visible light
journal, January 2011

  • Xie, Kui; Umezawa, Naoto; Zhang, Ning
  • Energy & Environmental Science, Vol. 4, Issue 10
  • DOI: 10.1039/c1ee01594j

Dielectric, infrared, and Raman response of undoped SrTiO 3 ceramics: Evidence of polar grain boundaries
journal, October 2001


Raman spectroscopy of CaTiO 3 -based perovskite solid solutions
journal, February 2004

  • Zheng, H.; Reaney, I. M.; de Györgyfalva, G. D. C. Csete
  • Journal of Materials Research, Vol. 19, Issue 2
  • DOI: 10.1557/jmr.2004.19.2.488

A visible light responsive rhodium and antimony-codoped SrTiO 3 powdered photocatalyst loaded with an IrO 2 cocatalyst for solar water splitting
journal, January 2014

  • Asai, Rikako; Nemoto, Hiroaki; Jia, Qingxin
  • Chem. Commun., Vol. 50, Issue 19
  • DOI: 10.1039/C3CC49279F

Raman scattering and room temperature ferromagnetism in Co-doped SrTiO3 particles
journal, September 2011


Lattice dynamics and dielectric response of Mg-doped SrTiO3 ceramics in a wide frequency range
journal, February 2005

  • Tkach, A.; Vilarinho, P. M.; Kholkin, A. L.
  • Journal of Applied Physics, Vol. 97, Issue 4
  • DOI: 10.1063/1.1849822

Neutron inelastic scattering study of the lattice dynamics of strontium titanate: harmonic models
journal, October 1972


Observation of infrared active and silent modes in cubic crystals by hyper-Raman scattering
journal, March 1979


Soft Phonon Modes and the 110°K Phase Transition in SrTi O 3
journal, July 1968


Observation of Fano asymmetry in Raman spectra of SrTiO3 and CaxSr1−xTiO3 perovskite nanocubes
journal, November 2006

  • Banerjee, Sarbajit; Kim, Dae-In; Robinson, Richard D.
  • Applied Physics Letters, Vol. 89, Issue 22
  • DOI: 10.1063/1.2400095

Observation of the First-Order Raman Scattering in SrTiO 3 Thin Films
journal, May 1999


Temperature-dependent structural characterization of sol-gel deposited strontium titanate (SrTiO3) thin films using Raman spectroscopy
journal, January 2001

  • Gupta, S.; Katiyar, R. S.
  • Journal of Raman Spectroscopy, Vol. 32, Issue 10
  • DOI: 10.1002/jrs.752

Tetragonal SrTiO3 revisited: The effect of impurities on the Raman spectrum
journal, September 1979


Ferroelectric microregions and Raman scattering in KTaO 3
journal, May 1986


Adsorption of small molecules at the cobalt-doped SrTiO3(001) surface: A first-principles investigation
journal, March 2015


Monitoring Solid Oxide CO 2 Capture Sorbents in Action
journal, October 2014

  • Keturakis, Christopher J.; Ni, Fan; Spicer, Michelle
  • ChemSusChem, Vol. 7, Issue 12
  • DOI: 10.1002/cssc.201402474

Adsorption and Reaction of CO 2 on the RuO 2 (110) Surface
journal, May 2002

  • Wang, Y.; Lafosse, A.; Jacobi, K.
  • The Journal of Physical Chemistry B, Vol. 106, Issue 21
  • DOI: 10.1021/jp025619x

Infrared Spectroscopic Study of the Carbon Dioxide Adsorption on the Surface of Ga 2 O 3 Polymorphs
journal, March 2006

  • Collins, Sebastián E.; Baltanás, Miguel A.; Bonivardi, Adrian L.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 11
  • DOI: 10.1021/jp055594c

Lewis Acido-Basic Interactions between CO 2 and MgO Surface: DFT and DRIFT Approaches
journal, March 2012

  • Cornu, Damien; Guesmi, Hazar; Krafft, Jean-Marc
  • The Journal of Physical Chemistry C, Vol. 116, Issue 11
  • DOI: 10.1021/jp211171t

Infrared spectroscopic study of carbon dioxide adsorption on the surface of cerium–gallium mixed oxides
journal, January 2012


In Situ FT-IR Spectroscopic Study of CO 2 and CO Adsorption on Y 2 O 3 , ZrO 2 , and Yttria-Stabilized ZrO 2
journal, August 2013

  • Köck, Eva-Maria; Kogler, Michaela; Bielz, Thomas
  • The Journal of Physical Chemistry C, Vol. 117, Issue 34
  • DOI: 10.1021/jp405625x

CO 2 Adsorption As a Flat-Lying, Tridentate Carbonate on CeO 2 (100)
journal, April 2014

  • Albrecht, Peter M.; Jiang, De-en; Mullins, David R.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 17
  • DOI: 10.1021/jp501201b

Effect of Dopants on the Adsorption of Carbon Dioxide on Ceria Surfaces
journal, September 2015


Tailoring Cu valence and oxygen vacancy in Cu/TiO2 catalysts for enhanced CO2 photoreduction efficiency
journal, May 2013


Spontaneous Dissociation of CO 2 to CO on Defective Surface of Cu(I)/TiO 2– x Nanoparticles at Room Temperature
journal, March 2012

  • Liu, Lianjun; Zhao, Cunyu; Li, Ying
  • The Journal of Physical Chemistry C, Vol. 116, Issue 14
  • DOI: 10.1021/jp300932b

Photo-enhanced hydrogenation of CO2 to mimic photosynthesis by CO co-feed in a novel twin reactor
journal, June 2015


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    Origin of Resistance Switching and Regulation of the Resistance Stability by the Interface State Density on the Pt/Nb:SrTiO 3 Interface
    journal, July 2019

    • Li, Guanghui; Yang, Ziyan; Zhang, Xinan
    • physica status solidi (a), Vol. 216, Issue 18
    • DOI: 10.1002/pssa.201900125

    Recent Progress in Photocatalytic CO 2 Reduction Over Perovskite Oxides
    journal, September 2017


    Revealing the role of the Rh valence state, La doping level and Ru cocatalyst in determining the H 2 evolution efficiency in doped SrTiO 3 photocatalysts
    journal, January 2019

    • Murthy, Dharmapura H. K.; Matsuzaki, Hiroyuki; Wang, Qian
    • Sustainable Energy & Fuels, Vol. 3, Issue 1
    • DOI: 10.1039/c8se00487k

    Electrical properties of Mo-doped SrTiO 3 prepared by solid state reaction method
    journal, September 2019


    Study on the Multi-level Resistance-Switching Memory and Memory-State-Dependent Photovoltage in Pt/Nd:SrTiO3 Junctions
    journal, January 2018