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Title: Selective separation of trivalent f-ions using 1,10-phenanthroline-2,9-dicarboxamide ligands in ionic liquids

Abstract

1,10-Phenanthroline-2,9-dicarboxamide complexants decorated with alkyl chains and imidazolium cations have been studied for extraction of trivalent f-ions into imidazolium ionic liquids. The dicationic complexants are shown to extract Am over Eu with separation factors > 50 and high extraction efficiencies. Lastly, the different size selectivities for lanthanide ions were observed for these two types of the complexants, highlighting the importance of the positive charge in controlling both extraction efficiencies and extraction selectivities.

Authors:
 [1];  [2];  [3];  [4];  [2]
+ Show Author Affiliations
  1. Univ. of Tennessee, Knoxville, TN (United States)
  2. Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1333009
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 45; Journal Issue: 29; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; lanthanides; minor actinides; nuclear separations; liquid-liquid extraction

Citation Formats

Dehaudt, Jeremy, Williams, Neil J., Shkrob, Ilya A., Luo, Huimin, and Dai, Sheng. Selective separation of trivalent f-ions using 1,10-phenanthroline-2,9-dicarboxamide ligands in ionic liquids. United States: N. p., 2016. Web. doi:10.1039/c6dt01800a.
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Dehaudt, Jeremy, Williams, Neil J., Shkrob, Ilya A., Luo, Huimin, & Dai, Sheng. Selective separation of trivalent f-ions using 1,10-phenanthroline-2,9-dicarboxamide ligands in ionic liquids. United States. https://doi.org/10.1039/c6dt01800a
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Dehaudt, Jeremy, Williams, Neil J., Shkrob, Ilya A., Luo, Huimin, and Dai, Sheng. Mon . "Selective separation of trivalent f-ions using 1,10-phenanthroline-2,9-dicarboxamide ligands in ionic liquids". United States. https://doi.org/10.1039/c6dt01800a. https://www.osti.gov/servlets/purl/1333009.
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@article{osti_1333009,
title = {Selective separation of trivalent f-ions using 1,10-phenanthroline-2,9-dicarboxamide ligands in ionic liquids},
author = {Dehaudt, Jeremy and Williams, Neil J. and Shkrob, Ilya A. and Luo, Huimin and Dai, Sheng},
abstractNote = {1,10-Phenanthroline-2,9-dicarboxamide complexants decorated with alkyl chains and imidazolium cations have been studied for extraction of trivalent f-ions into imidazolium ionic liquids. The dicationic complexants are shown to extract Am over Eu with separation factors > 50 and high extraction efficiencies. Lastly, the different size selectivities for lanthanide ions were observed for these two types of the complexants, highlighting the importance of the positive charge in controlling both extraction efficiencies and extraction selectivities.},
doi = {10.1039/c6dt01800a},
journal = {Dalton Transactions},
number = 29,
volume = 45,
place = {United States},
year = {Mon Jun 13 00:00:00 EDT 2016},
month = {Mon Jun 13 00:00:00 EDT 2016}
}
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Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/c6dt01800a
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Citation Metrics:
Cited by: 26 works
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Figures / Tables:

Fig. 1 Fig. 1: Chemical structures for 1,10-phenanthroline-2,9- dicarboxamide complexants 1 to 4.
All figures and tables (31 total)
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    Works referencing / citing this record:

    Efficient Separation of Light Lanthanides(III) by Using Bis‐Lactam Phenanthroline Ligands
    journal, March 2019

    • Healy, Mary R.; Ivanov, Alexander S.; Karslyan, Yana
    • Chemistry – A European Journal, Vol. 25, Issue 25
    • DOI: 10.1002/chem.201806443

    Ligands for f-element extraction used in the nuclear fuel cycle
    journal, January 2017

    • Leoncini, Andrea; Huskens, Jurriaan; Verboom, Willem
    • Chemical Society Reviews, Vol. 46, Issue 23
    • DOI: 10.1039/c7cs00574a

    The impact of alicyclic substituents on the extraction ability of new family of 1,10-phenanthroline-2,9-diamides
    journal, January 2020

    • Lemport, Pavel S.; Matveev, Petr I.; Yatsenko, Alexander V.
    • RSC Advances, Vol. 10, Issue 44
    • DOI: 10.1039/d0ra05182a

    Phenanthroline-based fluorescence sensors for Eu 3+ ion and subsequent enantioselective discriminating of malate
    journal, August 2018

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      Figures / Tables found in this record:

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