High-pressure Seebeck coefficients and thermoelectric behaviors of Bi and PbTe measured using a Paris-Edinburgh cell
Abstract
A new sample cell assembly design for the Paris-Edinburgh type large-volume press for simultaneous measurements of X-ray diffraction, electrical resistance, Seebeck coefficient and relative changes in the thermal conductance at high pressures has been developed. The feasibility of performing in situ measurements of the Seebeck coefficient and thermal measurements is demonstrated by observing well known solid–solid phase transitions of bismuth (Bi) up to 3 GPa and 450 K. A reversible polarity flip has been observed in the Seebeck coefficient across the Bi-I to Bi-II phase boundary. Also, successful Seebeck coefficient measurements have been performed for the classical high-temperature thermoelectric material PbTe under high pressure and temperature conditions. In addition, the relative change in the thermal conductivity was measured and a relative change in ZT, the dimensionless figure of merit, is described. Furthermore, this new capability enables pressure-induced structural changes to be directly correlated to electrical and thermal properties.
- Authors:
-
- Univ. of Nevada, Las Vegas, NV (United States)
- Carnegie Inst. of Washington, Argonne, IL (United States)
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Publication Date:
- Research Org.:
- Univ. of Nevada, Las Vegas, NV (United States); Carnegie Inst. of Science, Washington, DC (United States); Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA), Office of Defense Programs (DP)
- OSTI Identifier:
- 1332352
- Grant/Contract Number:
- NA0001982; NA0001974; NA0002006; FG02-99ER45775; AC02-06CH11357; AC52-06NA25396
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Synchrotron Radiation (Online)
- Additional Journal Information:
- Journal Name: Journal of Synchrotron Radiation (Online); Journal Volume: 23; Journal Issue: 6; Journal ID: ISSN 1600-5775
- Publisher:
- International Union of Crystallography
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; high pressure; Paris-Edinburgh press; Seebeck coefficient; thermal conductivity; thermoelectrics
Citation Formats
Baker, Jason, Kumar, Ravhi S., Park, Changyong, Kenney-Benson, Curtis, Cornelius, Andrew L., and Velisavljevic, Nenad. High-pressure Seebeck coefficients and thermoelectric behaviors of Bi and PbTe measured using a Paris-Edinburgh cell. United States: N. p., 2016.
Web. doi:10.1107/S1600577516014521.
Baker, Jason, Kumar, Ravhi S., Park, Changyong, Kenney-Benson, Curtis, Cornelius, Andrew L., & Velisavljevic, Nenad. High-pressure Seebeck coefficients and thermoelectric behaviors of Bi and PbTe measured using a Paris-Edinburgh cell. United States. https://doi.org/10.1107/S1600577516014521
Baker, Jason, Kumar, Ravhi S., Park, Changyong, Kenney-Benson, Curtis, Cornelius, Andrew L., and Velisavljevic, Nenad. Fri .
"High-pressure Seebeck coefficients and thermoelectric behaviors of Bi and PbTe measured using a Paris-Edinburgh cell". United States. https://doi.org/10.1107/S1600577516014521. https://www.osti.gov/servlets/purl/1332352.
@article{osti_1332352,
title = {High-pressure Seebeck coefficients and thermoelectric behaviors of Bi and PbTe measured using a Paris-Edinburgh cell},
author = {Baker, Jason and Kumar, Ravhi S. and Park, Changyong and Kenney-Benson, Curtis and Cornelius, Andrew L. and Velisavljevic, Nenad},
abstractNote = {A new sample cell assembly design for the Paris-Edinburgh type large-volume press for simultaneous measurements of X-ray diffraction, electrical resistance, Seebeck coefficient and relative changes in the thermal conductance at high pressures has been developed. The feasibility of performing in situ measurements of the Seebeck coefficient and thermal measurements is demonstrated by observing well known solid–solid phase transitions of bismuth (Bi) up to 3 GPa and 450 K. A reversible polarity flip has been observed in the Seebeck coefficient across the Bi-I to Bi-II phase boundary. Also, successful Seebeck coefficient measurements have been performed for the classical high-temperature thermoelectric material PbTe under high pressure and temperature conditions. In addition, the relative change in the thermal conductivity was measured and a relative change in ZT, the dimensionless figure of merit, is described. Furthermore, this new capability enables pressure-induced structural changes to be directly correlated to electrical and thermal properties.},
doi = {10.1107/S1600577516014521},
journal = {Journal of Synchrotron Radiation (Online)},
number = 6,
volume = 23,
place = {United States},
year = {Fri Jan 01 00:00:00 EST 2016},
month = {Fri Jan 01 00:00:00 EST 2016}
}
Web of Science
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Works referencing / citing this record:
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