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Title: Thermal stability study of a new guanidine suppressor for the next-generation caustic-side solvent extraction process

Abstract

Cesium stripping performance of thermally stressed solvent degrades slowly over time in batch tests of the Next Generation Caustic-Side Solvent Extraction (NGS) process. NGS is currently used at pilot scale at the Savannah River Site for the selective removal of cesium from high-level salt waste. Recently a new guanidine, N,N',N" -tris(3,7-dimethyloctyl)guanidine (TiDG), was chosen for use as the suppressor, a lipophilic organic base needed for stripping, and the present study was undertaken to address the question of its stability. The NGS process solvent was evaluated for a period of three months under a variety of temperature and storage conditions. The performance of the solvent was tested at 30-day increments using a standard extraction, scrub, strip, and extraction (ES 2S 3E) sequence. Lastly, the results provide insight on the effects of storage and process conditions, the stripping behavior of TiDG, and the stability of the new solvent composition.

Authors:
 [1];  [1];  [2];  [2]
  1. Tennessee Technological Univ., Cookeville, TN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Environmental Management (EM)
OSTI Identifier:
1332066
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Separation Science and Technology
Additional Journal Information:
Journal Volume: 51; Journal Issue: 7; Journal ID: ISSN 0149-6395
Publisher:
Taylor & Francis
Country of Publication:
United States
Language:
English
Subject:
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; 36 MATERIALS SCIENCE

Citation Formats

Hill, Talon G., Ensor, Dale D., Delmau, Lætitia Helene, and Moyer, Bruce A. Thermal stability study of a new guanidine suppressor for the next-generation caustic-side solvent extraction process. United States: N. p., 2016. Web. doi:10.1080/01496395.2016.1143509.
Hill, Talon G., Ensor, Dale D., Delmau, Lætitia Helene, & Moyer, Bruce A. Thermal stability study of a new guanidine suppressor for the next-generation caustic-side solvent extraction process. United States. doi:10.1080/01496395.2016.1143509.
Hill, Talon G., Ensor, Dale D., Delmau, Lætitia Helene, and Moyer, Bruce A. Sat . "Thermal stability study of a new guanidine suppressor for the next-generation caustic-side solvent extraction process". United States. doi:10.1080/01496395.2016.1143509. https://www.osti.gov/servlets/purl/1332066.
@article{osti_1332066,
title = {Thermal stability study of a new guanidine suppressor for the next-generation caustic-side solvent extraction process},
author = {Hill, Talon G. and Ensor, Dale D. and Delmau, Lætitia Helene and Moyer, Bruce A.},
abstractNote = {Cesium stripping performance of thermally stressed solvent degrades slowly over time in batch tests of the Next Generation Caustic-Side Solvent Extraction (NGS) process. NGS is currently used at pilot scale at the Savannah River Site for the selective removal of cesium from high-level salt waste. Recently a new guanidine, N,N',N" -tris(3,7-dimethyloctyl)guanidine (TiDG), was chosen for use as the suppressor, a lipophilic organic base needed for stripping, and the present study was undertaken to address the question of its stability. The NGS process solvent was evaluated for a period of three months under a variety of temperature and storage conditions. The performance of the solvent was tested at 30-day increments using a standard extraction, scrub, strip, and extraction (ES2S3E) sequence. Lastly, the results provide insight on the effects of storage and process conditions, the stripping behavior of TiDG, and the stability of the new solvent composition.},
doi = {10.1080/01496395.2016.1143509},
journal = {Separation Science and Technology},
number = 7,
volume = 51,
place = {United States},
year = {2016},
month = {2}
}

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