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Title: Selective adsorption of sulfur dioxide in a robust metal-organic framework material

Here, selective adsorption of SO 2 is realized in a porous metal–organic framework material, and in-depth structural and spectroscopic investigations using X-rays, infrared, and neutrons define the underlying interactions that cause SO 2 to bind more strongly than CO 2 and N 2.
Authors:
 [1] ;  [2] ;  [3] ;  [1] ;  [4] ;  [5] ;  [4] ;  [5] ;  [5] ;  [5] ;  [5] ;  [6] ;  [7] ;  [8] ;  [8] ;  [9] ;  [4] ;  [2] ;  [1] ;  [1]
  1. Univ. of Manchester, Manchester (United Kingdom)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Cardiff Univ., Cardiff (United Kingdom)
  4. Univ. of Nottingham, Nottingham (United Kingdom)
  5. Diamond Light Source, Harwell Science Campus, Oxfordshire (United Kingdom)
  6. Peking Univ., Beijing (China)
  7. STFC Rutherford Appleton Lab., Oxfordshire (United Kingdom)
  8. Hiden Isochema, Warrington (United Kingdom)
  9. European Synchrotron Radiation Facility, Grenoble (France)
Publication Date:
Grant/Contract Number:
AC05-00OR22725; LDRD 7739
Type:
Published Article
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 28; Journal Issue: 39; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE
OSTI Identifier:
1331221
Alternate Identifier(s):
OSTI ID: 1331222; OSTI ID: 1342698

Savage, Mathew, Cheng, Yongqiang, Easun, Timothy L., Eyley, Jennifer E., Argent, Stephen P., Warren, Mark R., Lewis, William, Murray, Claire, Tang, Chiu C., Frogley, Mark D., Cinque, Gianfelice, Sun, Junliang, Rudic, Svemir, Murden, Richard T., Benham, Michael J., Fitch, Andrew N., Blake, Alexander J., Ramirez-Cuesta, Anibal J., Yang, Sihai, and Schroder, Martin. Selective adsorption of sulfur dioxide in a robust metal-organic framework material. United States: N. p., Web. doi:10.1002/adma.201602338.
Savage, Mathew, Cheng, Yongqiang, Easun, Timothy L., Eyley, Jennifer E., Argent, Stephen P., Warren, Mark R., Lewis, William, Murray, Claire, Tang, Chiu C., Frogley, Mark D., Cinque, Gianfelice, Sun, Junliang, Rudic, Svemir, Murden, Richard T., Benham, Michael J., Fitch, Andrew N., Blake, Alexander J., Ramirez-Cuesta, Anibal J., Yang, Sihai, & Schroder, Martin. Selective adsorption of sulfur dioxide in a robust metal-organic framework material. United States. doi:10.1002/adma.201602338.
Savage, Mathew, Cheng, Yongqiang, Easun, Timothy L., Eyley, Jennifer E., Argent, Stephen P., Warren, Mark R., Lewis, William, Murray, Claire, Tang, Chiu C., Frogley, Mark D., Cinque, Gianfelice, Sun, Junliang, Rudic, Svemir, Murden, Richard T., Benham, Michael J., Fitch, Andrew N., Blake, Alexander J., Ramirez-Cuesta, Anibal J., Yang, Sihai, and Schroder, Martin. 2016. "Selective adsorption of sulfur dioxide in a robust metal-organic framework material". United States. doi:10.1002/adma.201602338.
@article{osti_1331221,
title = {Selective adsorption of sulfur dioxide in a robust metal-organic framework material},
author = {Savage, Mathew and Cheng, Yongqiang and Easun, Timothy L. and Eyley, Jennifer E. and Argent, Stephen P. and Warren, Mark R. and Lewis, William and Murray, Claire and Tang, Chiu C. and Frogley, Mark D. and Cinque, Gianfelice and Sun, Junliang and Rudic, Svemir and Murden, Richard T. and Benham, Michael J. and Fitch, Andrew N. and Blake, Alexander J. and Ramirez-Cuesta, Anibal J. and Yang, Sihai and Schroder, Martin},
abstractNote = {Here, selective adsorption of SO2 is realized in a porous metal–organic framework material, and in-depth structural and spectroscopic investigations using X-rays, infrared, and neutrons define the underlying interactions that cause SO2 to bind more strongly than CO2 and N2.},
doi = {10.1002/adma.201602338},
journal = {Advanced Materials},
number = 39,
volume = 28,
place = {United States},
year = {2016},
month = {8}
}

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