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Title: “Rocking-Chair”-Type Metal Hybrid Supercapacitors

Abstract

Hybrid supercapacitors that follow a “rocking-chair”-type mechanism were developed by coupling divalent metal and activated carbon electrodes in nonaqueous electrolytes. Conventional supercapacitors require a large amount of electrolyte to provide a sufficient quantity of ions to the electrodes, due to their Daniell-type mechanism that depletes the ions from the electrolyte while charging. The alternative “rocking-chair”-type mechanism effectively enhances the energy density of supercapacitors by minimizing the necessary amount of electrolyte, because the ion is replenished from the metal anode while it is adsorbed to the cathode. Newly developed nonaqueous electrolytes for Mg and Zn electrochemistry, based on bis(trifluoromethylsulfonyl)imide (TFSI) salts, made the metal hybrid supercapacitors possible by enabling reversible deposition on the metal anodes and reversible adsorption on an activated carbon cathode. Factoring in gains through the cell design, the energy density of the metal hybrid supercapacitors is projected to be a factor of 7 higher than conventional devices thanks to both the “rocking-chair”-type mechanism that minimizes total electrolyte volume and the use of metal anodes, which have substantial merits in capacity and voltage. Self-discharge was also substantially alleviated compared to conventional supercapacitors. This concept offers a route to build supercapacitors that meet dual criteria of power and energy densitiesmore » with a simple cell design.« less

Authors:
 [1];  [2];  [1];  [3];  [4];  [5];  [5];  [2];  [1]
  1. Univ. of Illinois, Chicago, IL (United States). Dept. of Chemistry; Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR)
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR) and Chemical Sciences and Engineering Division
  3. Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR) ; Univ. of Illinois, Urbana-Champaign, IL (United States). Dept. of Chemistry
  4. Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR) and Materials Science Division; Univ. of Ljubljana (Slovenia)
  5. Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR) ; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technology Division
Publication Date:
Research Org.:
Univ. of Illinois, Chicago, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1330727
Alternate Identifier(s):
OSTI ID: 1334157; OSTI ID: 1340689; OSTI ID: 1474978
Grant/Contract Number:  
AC02-05CH11231; AC02-06CH11357
Resource Type:
Published Article
Journal Name:
ACS Applied Materials and Interfaces
Additional Journal Information:
Journal Volume: 8; Journal Issue: 45; Journal ID: ISSN 1944-8244
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; energy density; metal anodes; self-discharge; supercapacitors; volume of electrolyte; “rocking chair”-type mechanism; 25 ENERGY STORAGE

Citation Formats

Yoo, Hyun Deog, Han, Sang-Don, Bayliss, Ryan D., Gewirth, Andrew A., Genorio, Bostjan, Rajput, Nav Nidhi, Persson, Kristin A., Burrell, Anthony K., and Cabana, Jordi. “Rocking-Chair”-Type Metal Hybrid Supercapacitors. United States: N. p., 2016. Web. doi:10.1021/acsami.6b08367.
Yoo, Hyun Deog, Han, Sang-Don, Bayliss, Ryan D., Gewirth, Andrew A., Genorio, Bostjan, Rajput, Nav Nidhi, Persson, Kristin A., Burrell, Anthony K., & Cabana, Jordi. “Rocking-Chair”-Type Metal Hybrid Supercapacitors. United States. doi:10.1021/acsami.6b08367.
Yoo, Hyun Deog, Han, Sang-Don, Bayliss, Ryan D., Gewirth, Andrew A., Genorio, Bostjan, Rajput, Nav Nidhi, Persson, Kristin A., Burrell, Anthony K., and Cabana, Jordi. Mon . "“Rocking-Chair”-Type Metal Hybrid Supercapacitors". United States. doi:10.1021/acsami.6b08367.
@article{osti_1330727,
title = {“Rocking-Chair”-Type Metal Hybrid Supercapacitors},
author = {Yoo, Hyun Deog and Han, Sang-Don and Bayliss, Ryan D. and Gewirth, Andrew A. and Genorio, Bostjan and Rajput, Nav Nidhi and Persson, Kristin A. and Burrell, Anthony K. and Cabana, Jordi},
abstractNote = {Hybrid supercapacitors that follow a “rocking-chair”-type mechanism were developed by coupling divalent metal and activated carbon electrodes in nonaqueous electrolytes. Conventional supercapacitors require a large amount of electrolyte to provide a sufficient quantity of ions to the electrodes, due to their Daniell-type mechanism that depletes the ions from the electrolyte while charging. The alternative “rocking-chair”-type mechanism effectively enhances the energy density of supercapacitors by minimizing the necessary amount of electrolyte, because the ion is replenished from the metal anode while it is adsorbed to the cathode. Newly developed nonaqueous electrolytes for Mg and Zn electrochemistry, based on bis(trifluoromethylsulfonyl)imide (TFSI) salts, made the metal hybrid supercapacitors possible by enabling reversible deposition on the metal anodes and reversible adsorption on an activated carbon cathode. Factoring in gains through the cell design, the energy density of the metal hybrid supercapacitors is projected to be a factor of 7 higher than conventional devices thanks to both the “rocking-chair”-type mechanism that minimizes total electrolyte volume and the use of metal anodes, which have substantial merits in capacity and voltage. Self-discharge was also substantially alleviated compared to conventional supercapacitors. This concept offers a route to build supercapacitors that meet dual criteria of power and energy densities with a simple cell design.},
doi = {10.1021/acsami.6b08367},
journal = {ACS Applied Materials and Interfaces},
number = 45,
volume = 8,
place = {United States},
year = {2016},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1021/acsami.6b08367

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Cited by: 6 works
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