Quantum Coherence and Temperature Dependence of the Anomalous State of Nanoconfined Water in Carbon Nanotubes
Abstract
X-ray Compton scattering measurements of the electron momentum distribution in water confined in both single-walled and double-walled carbon nanotubes (SWNT and DWNT), as a function of temperature and confinement size are presented here together with earlier measurements of the proton momentum distribution in the same systems using neutron Compton scattering. These studies provide a coherent picture of an anomalous state of water that exists because of nanoconfinement. This state cannot be described by the weakly interacting molecule picture. It has unique transport properties for both protons and water molecules. Furthermore, we suggest that knowledge of the excitation spectrum of this state is needed to understand the enhanced flow of water in cylinders with diameters on the order of 20 Å.
- Authors:
-
- Physics Department, University of Houston, Houston, Texas 77204, United States
- Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, United States
- Japan Synchrotron Radiation Research Institute (JASRI)/SPring-8, Sayo-cho, Hyogo 679-5198, Japan
- Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Michigan, Ann Arbor, MI (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1330471
- Alternate Identifier(s):
- OSTI ID: 1330556; OSTI ID: 1334167
- Grant/Contract Number:
- FG02-08ER46486; AC05-00OR22725
- Resource Type:
- Published Article
- Journal Name:
- Journal of Physical Chemistry Letters
- Additional Journal Information:
- Journal Name: Journal of Physical Chemistry Letters Journal Volume: 7 Journal Issue: 22; Journal ID: ISSN 1948-7185
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Reiter, George F., Deb, Aniruddha, Sakurai, Y., Itou, M., and Kolesnikov, A. I. Quantum Coherence and Temperature Dependence of the Anomalous State of Nanoconfined Water in Carbon Nanotubes. United States: N. p., 2016.
Web. doi:10.1021/acs.jpclett.6b02057.
Reiter, George F., Deb, Aniruddha, Sakurai, Y., Itou, M., & Kolesnikov, A. I. Quantum Coherence and Temperature Dependence of the Anomalous State of Nanoconfined Water in Carbon Nanotubes. United States. https://doi.org/10.1021/acs.jpclett.6b02057
Reiter, George F., Deb, Aniruddha, Sakurai, Y., Itou, M., and Kolesnikov, A. I. Sun .
"Quantum Coherence and Temperature Dependence of the Anomalous State of Nanoconfined Water in Carbon Nanotubes". United States. https://doi.org/10.1021/acs.jpclett.6b02057.
@article{osti_1330471,
title = {Quantum Coherence and Temperature Dependence of the Anomalous State of Nanoconfined Water in Carbon Nanotubes},
author = {Reiter, George F. and Deb, Aniruddha and Sakurai, Y. and Itou, M. and Kolesnikov, A. I.},
abstractNote = {X-ray Compton scattering measurements of the electron momentum distribution in water confined in both single-walled and double-walled carbon nanotubes (SWNT and DWNT), as a function of temperature and confinement size are presented here together with earlier measurements of the proton momentum distribution in the same systems using neutron Compton scattering. These studies provide a coherent picture of an anomalous state of water that exists because of nanoconfinement. This state cannot be described by the weakly interacting molecule picture. It has unique transport properties for both protons and water molecules. Furthermore, we suggest that knowledge of the excitation spectrum of this state is needed to understand the enhanced flow of water in cylinders with diameters on the order of 20 Å.},
doi = {10.1021/acs.jpclett.6b02057},
journal = {Journal of Physical Chemistry Letters},
number = 22,
volume = 7,
place = {United States},
year = {Sun Oct 30 00:00:00 EDT 2016},
month = {Sun Oct 30 00:00:00 EDT 2016}
}
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https://doi.org/10.1021/acs.jpclett.6b02057
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Cited by: 17 works
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