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Title: Experimental and DFT Computational Study of β-Me and β-H Elimination Coupled with Proton Transfer: From Amides to Enamides in Cp* 2 MX (M = La, Ce)

Authors:
 [1];  [2];  [3];  [1]
  1. Department of Chemistry, University of California, Berkeley, California 94720-1460, United States
  2. Université Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, 43 Boulevard du 11 Novembre 1918, F-69622 Villeurbanne, France
  3. Institut Charles Gerhardt, CNRS UMR 5253, Université de Montpellier, Place E. Bataillon, F-34095 Montpellier, France
Publication Date:
Research Org.:
Univ. of California, Berkeley, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1330108
Alternate Identifier(s):
OSTI ID: 1339954
Grant/Contract Number:  
AC02- 05CH11231; AC02-05CH11231
Resource Type:
Published Article
Journal Name:
Organometallics
Additional Journal Information:
Journal Name: Organometallics Journal Volume: 36 Journal Issue: 1; Journal ID: ISSN 0276-7333
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Rozenel, Sergio S., Perrin, Lionel, Eisenstein, Odile, and Andersen, Richard A. Experimental and DFT Computational Study of β-Me and β-H Elimination Coupled with Proton Transfer: From Amides to Enamides in Cp* 2 MX (M = La, Ce). United States: N. p., 2016. Web. doi:10.1021/acs.organomet.6b00677.
Rozenel, Sergio S., Perrin, Lionel, Eisenstein, Odile, & Andersen, Richard A. Experimental and DFT Computational Study of β-Me and β-H Elimination Coupled with Proton Transfer: From Amides to Enamides in Cp* 2 MX (M = La, Ce). United States. doi:10.1021/acs.organomet.6b00677.
Rozenel, Sergio S., Perrin, Lionel, Eisenstein, Odile, and Andersen, Richard A. Wed . "Experimental and DFT Computational Study of β-Me and β-H Elimination Coupled with Proton Transfer: From Amides to Enamides in Cp* 2 MX (M = La, Ce)". United States. doi:10.1021/acs.organomet.6b00677.
@article{osti_1330108,
title = {Experimental and DFT Computational Study of β-Me and β-H Elimination Coupled with Proton Transfer: From Amides to Enamides in Cp* 2 MX (M = La, Ce)},
author = {Rozenel, Sergio S. and Perrin, Lionel and Eisenstein, Odile and Andersen, Richard A.},
abstractNote = {},
doi = {10.1021/acs.organomet.6b00677},
journal = {Organometallics},
number = 1,
volume = 36,
place = {United States},
year = {2016},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1021/acs.organomet.6b00677

Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

Figures / Tables:

Scheme 1 Scheme 1: β-Methyl Elimination from an f-Block Metal Alkyl Compound

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Works referencing / citing this record:

CCDC 1483809: Experimental Crystal Structure Determination: RAKHOD : bis(η5-pentamethylcyclopentadienyl)-(t-butyl(isopropyl)amino)-cerium
dataset, June 2016


CCDC 1483823: Experimental Crystal Structure Determination: RAKHUJ : bis(η5-pentamethylcyclopentadienyl)-(bis(trimethylsilyl)amino)-cerium
dataset, June 2016


CCDC 1483836: Experimental Crystal Structure Determination: RAKJIZ : bis(η5-pentamethylcyclopentadienyl)-(isopropyl(dimethylsilyl)amino)-cerium
dataset, June 2016


CCDC 1483848: Experimental Crystal Structure Determination: RAKKEW : bis(η5-pentamethylcyclopentadienyl)-(t-butyl(trimethylsilyl)amino)-cerium
dataset, June 2016


Pentamethylcyclopentadienyl-Supported Cerocene(III) Complexes: Pentamethylcyclopentadienyl-Supported Cerocene(III) Complexes
journal, February 2017

  • Schneider, David; Anwander, Reiner
  • European Journal of Inorganic Chemistry, Vol. 2017, Issue 8
  • DOI: 10.1002/ejic.201601404

Pentamethylcyclopentadienyl-Supported Cerocene(III) Complexes: Pentamethylcyclopentadienyl-Supported Cerocene(III) Complexes
journal, February 2017

  • Schneider, David; Anwander, Reiner
  • European Journal of Inorganic Chemistry, Vol. 2017, Issue 8
  • DOI: 10.1002/ejic.201601404