Strain tuning and strong enhancement of ionic conductivity in SrZrO3-RE2O3 (RE = Sm, Eu, Gd, Dy, and Er) nanocomposite films
Abstract
Fast ion transport channels at interfaces in thin films have attracted great attention due to a range of potential applications for energy materials and devices, for, solid oxide fuel cells, sensors, and memories. Here, it is shown that in vertical nanocomposite heteroepitaxial films of SrZrO3–RE2O3 (RE = Sm, Eu, Gd, Dy, and Er) the ionic conductivity of the composite can be tuned and strongly enhanced using embedded, stiff, and vertical nanopillars of RE2O3. With increasing lattice constant of RE2O3 from Er2O3 to Sm2O3, it is found that the tensile strain in the SrZrO3 increases proportionately, and the ionic conductivity of the composite increases accordingly, by an order of magnitude. Lastly, the results here conclusively show, for the first time, that strain in films can be effectively used to tune the ionic conductivity of the materials.
- Authors:
-
- Univ. of Cambridge, Cambridge (United Kingdom)
- Texas A & M Univ., College Station, TX (United States)
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Publication Date:
- Research Org.:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1329686
- Report Number(s):
- LA-UR-15-23679
Journal ID: ISSN 1616-301X
- Grant/Contract Number:
- AC52-06NA25396
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 25; Journal Issue: 27; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; material science; thin films; nanocomposite; ionic; strain; ion transport
Citation Formats
Lee, Shinbuhm, Zhang, Wenrui, Khatkhatay, Fauzia, Jia, Quanxi, Wang, Haiyan, and MacManus-Driscoll, Judith L. Strain tuning and strong enhancement of ionic conductivity in SrZrO3-RE2O3 (RE = Sm, Eu, Gd, Dy, and Er) nanocomposite films. United States: N. p., 2015.
Web. doi:10.1002/adfm.201404420.
Lee, Shinbuhm, Zhang, Wenrui, Khatkhatay, Fauzia, Jia, Quanxi, Wang, Haiyan, & MacManus-Driscoll, Judith L. Strain tuning and strong enhancement of ionic conductivity in SrZrO3-RE2O3 (RE = Sm, Eu, Gd, Dy, and Er) nanocomposite films. United States. https://doi.org/10.1002/adfm.201404420
Lee, Shinbuhm, Zhang, Wenrui, Khatkhatay, Fauzia, Jia, Quanxi, Wang, Haiyan, and MacManus-Driscoll, Judith L. Fri .
"Strain tuning and strong enhancement of ionic conductivity in SrZrO3-RE2O3 (RE = Sm, Eu, Gd, Dy, and Er) nanocomposite films". United States. https://doi.org/10.1002/adfm.201404420. https://www.osti.gov/servlets/purl/1329686.
@article{osti_1329686,
title = {Strain tuning and strong enhancement of ionic conductivity in SrZrO3-RE2O3 (RE = Sm, Eu, Gd, Dy, and Er) nanocomposite films},
author = {Lee, Shinbuhm and Zhang, Wenrui and Khatkhatay, Fauzia and Jia, Quanxi and Wang, Haiyan and MacManus-Driscoll, Judith L.},
abstractNote = {Fast ion transport channels at interfaces in thin films have attracted great attention due to a range of potential applications for energy materials and devices, for, solid oxide fuel cells, sensors, and memories. Here, it is shown that in vertical nanocomposite heteroepitaxial films of SrZrO3–RE2O3 (RE = Sm, Eu, Gd, Dy, and Er) the ionic conductivity of the composite can be tuned and strongly enhanced using embedded, stiff, and vertical nanopillars of RE2O3. With increasing lattice constant of RE2O3 from Er2O3 to Sm2O3, it is found that the tensile strain in the SrZrO3 increases proportionately, and the ionic conductivity of the composite increases accordingly, by an order of magnitude. Lastly, the results here conclusively show, for the first time, that strain in films can be effectively used to tune the ionic conductivity of the materials.},
doi = {10.1002/adfm.201404420},
journal = {Advanced Functional Materials},
number = 27,
volume = 25,
place = {United States},
year = {Fri Jun 05 00:00:00 EDT 2015},
month = {Fri Jun 05 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
Microstructure, vertical strain control and tunable functionalities in self-assembled, vertically aligned nanocomposite thin films
journal, May 2013
- Chen, Aiping; Bi, Zhenxing; Jia, Quanxi
- Acta Materialia, Vol. 61, Issue 8
“Stretching” the energy landscape of oxides—Effects on electrocatalysis and diffusion
journal, February 2014
- Yildiz, Bilge
- MRS Bulletin, Vol. 39, Issue 2
Strain control and spontaneous phase ordering in vertical nanocomposite heteroepitaxial thin films
journal, March 2008
- MacManus-Driscoll, Judith L.; Zerrer, Patrick; Wang, Haiyan
- Nature Materials, Vol. 7, Issue 4
Oxide interfaces with enhanced ion conductivity
journal, December 2013
- Leon, Carlos; Santamaria, Jacobo; Boukamp, Bernard A.
- MRS Bulletin, Vol. 38, Issue 12
Self-Assembled Growth of BiFeO3–CoFe2O4 Nanostructures
journal, October 2006
- Zheng, H.; Straub, F.; Zhan, Q.
- Advanced Materials, Vol. 18, Issue 20
Elastic strain at interfaces and its influence on ionic conductivity in nanoscaled solid electrolyte thin films—theoretical considerations and experimental studies
journal, January 2009
- Schichtel, N.; Korte, C.; Hesse, D.
- Physical Chemistry Chemical Physics, Vol. 11, Issue 17
Study of structural, elastic, electronic and optical properties of seven SrZrO3 phases: First-principles calculations
journal, December 2012
- Liu, Qi-Jun; Liu, Zheng-Tang; Feng, Li-Ping
- Journal of Solid State Chemistry, Vol. 196
Thick lead-free ferroelectric films with high Curie temperatures through nanocomposite-induced strain
journal, July 2011
- Harrington, Sophie A.; Zhai, Junyi; Denev, Sava
- Nature Nanotechnology, Vol. 6, Issue 8
Protonic conduction in the single crystals of Y-doped SrZrO3
journal, September 1991
- Huang, H.; Ishigame, M.; Shin, S.
- Solid State Ionics, Vol. 47, Issue 3-4
Applicability of Gd-doped BaZrO3, SrZrO3, BaCeO3 and SrCeO3 proton conducting perovskites as electrolytes for solid oxide fuel cells
journal, April 2013
- Zając, Wojciech; Rusinek, Dariusz; Zheng, Kun
- Open Chemistry, Vol. 11, Issue 4
Electrochemical characterization and redox behavior of Nb-doped SrTiO3
journal, February 2009
- Blennow, Peter; Hansen, Kent K.; Wallenberg, L. Reine
- Solid State Ionics, Vol. 180, Issue 1
Vertically aligned nanocomposite electrolytes with superior out-of-plane ionic conductivity for solid oxide fuel cells
journal, November 2013
- Su, Qing; Yoon, Daeil; Chen, Aiping
- Journal of Power Sources, Vol. 242
Novel Electroforming-Free Nanoscaffold Memristor with Very High Uniformity, Tunability, and Density
journal, July 2014
- Lee, Shinbuhm; Sangle, Abhijeet; Lu, Ping
- Advanced Materials, Vol. 26, Issue 36
Electrical Modulation of the Local Conduction at Oxide Tubular Interfaces
journal, September 2013
- Hsieh, Ying-Hui; Strelcov, Evgheni; Liou, Jia-Ming
- ACS Nano, Vol. 7, Issue 10
On the influence of strain on ion transport: microstructure and ionic conductivity of nanoscale YSZ|Sc2O3 multilayers
journal, January 2010
- Schichtel, Nicole; Korte, Carsten; Hesse, Dietrich
- Physical Chemistry Chemical Physics, Vol. 12, Issue 43
Local Conduction at the BiFeO3-CoFe2O4 Tubular Oxide Interface
journal, July 2012
- Hsieh, Ying-Hui; Liou, Jia-Ming; Huang, Bo-Chao
- Advanced Materials, Vol. 24, Issue 33, p. 4564-4568
Colossal Ionic Conductivity at Interfaces of Epitaxial ZrO2:Y2O3/SrTiO3 Heterostructures
journal, August 2008
- Garcia-Barriocanal, J.; Rivera-Calzada, A.; Varela, M.
- Science, Vol. 321, Issue 5889
Protonic and oxygen-ion conduction in SrZrO3-based materials
journal, June 1995
- Labrincha, J. A.; Marques, F. M. B.; Frade, J. R.
- Journal of Materials Science, Vol. 30, Issue 11
Proton conducting ceramics and their applications
journal, July 1996
- Iwahara, Hiroyasu
- Solid State Ionics, Vol. 86-88
Extremely High Tunability and Low Loss in Nanoscaffold Ferroelectric Films
journal, July 2012
- Lee, OonJew; Harrington, Sophie A.; Kursumovic, Ahmed
- Nano Letters, Vol. 12, Issue 8
Self-Assembled Heteroepitaxial Oxide Nanocomposite Thin Film Structures: Designing Interface-Induced Functionality in Electronic Materials
journal, June 2010
- MacManus-Driscoll, Judith L.
- Advanced Functional Materials, Vol. 20, Issue 13
Ionically Conducting Two-Dimensional Heterostructures
journal, June 2009
- Guo, Xiangxin; Maier, Joachim
- Advanced Materials, Vol. 21, Issue 25-26
A New Material for High-Temperature Lead-Free Actuators
journal, June 2013
- Kursumovic, Ahmed; Defay, Emmanuel; Lee, Oon Jew
- Advanced Functional Materials, Vol. 23, Issue 47
Fundamental questions relating to ion conduction in disordered solids
journal, March 2009
- Dyre, Jeppe C.; Maass, Philipp; Roling, Bernhard
- Reports on Progress in Physics, Vol. 72, Issue 4
Enhancement of Ionic Conductivity in Sm-Doped Ceria/Yttria-Stabilized Zirconia Heteroepitaxial Structures
journal, August 2010
- Sanna, Simone; Esposito, Vincenzo; Tebano, Antonello
- Small, Vol. 6, Issue 17
Origin of Colossal Ionic Conductivity in Oxide Multilayers: Interface Induced Sublattice Disorder
journal, March 2010
- Pennycook, Timothy J.; Beck, Matthew J.; Varga, Kalman
- Physical Review Letters, Vol. 104, Issue 11
Coherency strain and its effect on ionic conductivity and diffusion in solid electrolytes – an improved model for nanocrystalline thin films and a review of experimental data
journal, January 2014
- Korte, C.; Keppner, J.; Peters, A.
- Phys. Chem. Chem. Phys., Vol. 16, Issue 44
Activation Volume Tensor for Oxygen-Vacancy Migration in Strained Electrolytes
journal, May 2013
- Hinterberg, J.; Zacherle, T.; De Souza, R. A.
- Physical Review Letters, Vol. 110, Issue 20
Spontaneous Ordering, Strain Control, and Multifunctionality in Vertical Nanocomposite Heteroepitaxial Films
journal, August 2009
- Fouchet, A.
- IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control, Vol. 56, Issue 8
Nanoionics: ion transport and electrochemical storage in confined systems
journal, November 2005
- Maier, J.
- Nature Materials, Vol. 4, Issue 11, p. 805-815
Fundamental questions relating to ion conduction in disordered solids
text, January 2008
- Dyre, Jeppe C.; Maass, Philipp; Roling, Bernhard
- arXiv
Works referencing / citing this record:
Large polarization and dielectric response in epitaxial SrZrO 3 films
journal, January 2016
- Tian, Hao; Mao, Ai-Jie; Zhao, Hong Jian
- Physical Chemistry Chemical Physics, Vol. 18, Issue 11
Structural phases arising from reconstructive and isostructural transitions in high-melting-point oxides under hydrostatic pressure: A first-principles study
journal, January 2018
- Tian, Hao; Kuang, Xiao-Yu; Mao, Ai-Jie
- Physical Review B, Vol. 97, Issue 2
Metal Oxide Nanocomposites: A Perspective from Strain, Defect, and Interface
journal, October 2018
- Chen, Aiping; Su, Qing; Han, Hyungkyu
- Advanced Materials, Vol. 31, Issue 4
Strongly enhanced oxygen ion transport through samarium-doped CeO2 nanopillars in nanocomposite films
journal, October 2015
- Yang, Sang Mo; Lee, Shinbuhm; Jian, Jie
- Nature Communications, Vol. 6, Issue 1
The role of oxide interfaces in highly confined electronic and ionic conductors
journal, January 2019
- Christensen, Dennis V.; Chen, Yunzhong; Esposito, Vincenzo
- APL Materials, Vol. 7, Issue 1
Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain
journal, May 2017
- Balaji Gopal, Chirranjeevi; García-Melchor, Max; Lee, Sang Chul
- Nature Communications, Vol. 8, Issue 1
Determining interface structures in vertically aligned nanocomposite films
journal, June 2019
- Zhu, Bonan; Schusteritsch, Georg; Lu, Ping
- APL Materials, Vol. 7, Issue 6
Ordered Structures with Functional Units as a Paradigm of Material Design
journal, June 2019
- Chen, Kexin; Li, Liang
- Advanced Materials
Determining interface structures in vertically aligned nanocomposite films
text, January 2019
- Zhu, Bonan; Schusteritsch, Georg; Lu, P.
- Apollo - University of Cambridge Repository