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Title: Liquid-like ionic conduction in solid lithium and sodium monocarba- closo-decaborates near or at room temperature

Abstract

Both LiCB 9H 10 and NaCB 9H 10 exhibit liquid-like cationic conductivities (≥0.03 S cm –1) in their disordered hexagonal phases near or at room temperature. Furthermore, these unprecedented conductivities and favorable stabilities enabled by the large pseudoaromatic polyhedral anions render these materials in their pristine or further modified forms as promising solid electrolytes in next-generation, power devices.

Authors:
 [1];  [2];  [3];  [4];  [3];  [4];  [5];  [5];  [5];  [5];  [2];  [2];  [3]
  1. Univ. of Maryland, College Park, MD (United States); National Institute of Standards and Technology, Gaithersburg, MD (United States)
  2. Tohoku Univ., Sendai (Japan)
  3. National Institute of Standards and Technology, Gaithersburg, MD (United States)
  4. Sandia National Lab. (SNL-CA), Livermore, CA (United States)
  5. Ural Branch of the Russian Academy of Sciences, Ekaterinburg (Russia)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1329624
Report Number(s):
SAND-2016-10125J
Journal ID: ISSN 1614-6832; 648152
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 6; Journal Issue: 8; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

Tang, Wan Si, Matsuo, Motoaki, Wu, Hui, Stavila, Vitalie, Zhou, Wei, Talin, Albert Alec, Soloninin, Alexei V., Skoryunov, Roman V., Babanova, Olga A., Skripov, Alexander V., Unemoto, Atsushi, Orimo, Shin -Ichi, and Udovic, Terrence J. Liquid-like ionic conduction in solid lithium and sodium monocarba-closo-decaborates near or at room temperature. United States: N. p., 2016. Web. doi:10.1002/aenm.201502237.
Tang, Wan Si, Matsuo, Motoaki, Wu, Hui, Stavila, Vitalie, Zhou, Wei, Talin, Albert Alec, Soloninin, Alexei V., Skoryunov, Roman V., Babanova, Olga A., Skripov, Alexander V., Unemoto, Atsushi, Orimo, Shin -Ichi, & Udovic, Terrence J. Liquid-like ionic conduction in solid lithium and sodium monocarba-closo-decaborates near or at room temperature. United States. doi:10.1002/aenm.201502237.
Tang, Wan Si, Matsuo, Motoaki, Wu, Hui, Stavila, Vitalie, Zhou, Wei, Talin, Albert Alec, Soloninin, Alexei V., Skoryunov, Roman V., Babanova, Olga A., Skripov, Alexander V., Unemoto, Atsushi, Orimo, Shin -Ichi, and Udovic, Terrence J. Fri . "Liquid-like ionic conduction in solid lithium and sodium monocarba-closo-decaborates near or at room temperature". United States. doi:10.1002/aenm.201502237. https://www.osti.gov/servlets/purl/1329624.
@article{osti_1329624,
title = {Liquid-like ionic conduction in solid lithium and sodium monocarba-closo-decaborates near or at room temperature},
author = {Tang, Wan Si and Matsuo, Motoaki and Wu, Hui and Stavila, Vitalie and Zhou, Wei and Talin, Albert Alec and Soloninin, Alexei V. and Skoryunov, Roman V. and Babanova, Olga A. and Skripov, Alexander V. and Unemoto, Atsushi and Orimo, Shin -Ichi and Udovic, Terrence J.},
abstractNote = {Both LiCB9H10 and NaCB9H10 exhibit liquid-like cationic conductivities (≥0.03 S cm–1) in their disordered hexagonal phases near or at room temperature. Furthermore, these unprecedented conductivities and favorable stabilities enabled by the large pseudoaromatic polyhedral anions render these materials in their pristine or further modified forms as promising solid electrolytes in next-generation, power devices.},
doi = {10.1002/aenm.201502237},
journal = {Advanced Energy Materials},
number = 8,
volume = 6,
place = {United States},
year = {2016},
month = {2}
}

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Cited by: 25 works
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