Liquid-like ionic conduction in solid lithium and sodium monocarba-closo-decaborates near or at room temperature
Abstract
Both LiCB9H10 and NaCB9H10 exhibit liquid-like cationic conductivities (≥0.03 S cm–1) in their disordered hexagonal phases near or at room temperature. Furthermore, these unprecedented conductivities and favorable stabilities enabled by the large pseudoaromatic polyhedral anions render these materials in their pristine or further modified forms as promising solid electrolytes in next-generation, power devices.
- Authors:
-
- Univ. of Maryland, College Park, MD (United States); National Institute of Standards and Technology, Gaithersburg, MD (United States)
- Tohoku Univ., Sendai (Japan)
- National Institute of Standards and Technology, Gaithersburg, MD (United States)
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Ural Branch of the Russian Academy of Sciences, Ekaterinburg (Russia)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1329624
- Alternate Identifier(s):
- OSTI ID: 1401183
- Report Number(s):
- SAND-2016-10125J
Journal ID: ISSN 1614-6832; 648152
- Grant/Contract Number:
- AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 8; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Tang, Wan Si, Matsuo, Motoaki, Wu, Hui, Stavila, Vitalie, Zhou, Wei, Talin, Albert Alec, Soloninin, Alexei V., Skoryunov, Roman V., Babanova, Olga A., Skripov, Alexander V., Unemoto, Atsushi, Orimo, Shin -Ichi, and Udovic, Terrence J. Liquid-like ionic conduction in solid lithium and sodium monocarba-closo-decaborates near or at room temperature. United States: N. p., 2016.
Web. doi:10.1002/aenm.201502237.
Tang, Wan Si, Matsuo, Motoaki, Wu, Hui, Stavila, Vitalie, Zhou, Wei, Talin, Albert Alec, Soloninin, Alexei V., Skoryunov, Roman V., Babanova, Olga A., Skripov, Alexander V., Unemoto, Atsushi, Orimo, Shin -Ichi, & Udovic, Terrence J. Liquid-like ionic conduction in solid lithium and sodium monocarba-closo-decaborates near or at room temperature. United States. https://doi.org/10.1002/aenm.201502237
Tang, Wan Si, Matsuo, Motoaki, Wu, Hui, Stavila, Vitalie, Zhou, Wei, Talin, Albert Alec, Soloninin, Alexei V., Skoryunov, Roman V., Babanova, Olga A., Skripov, Alexander V., Unemoto, Atsushi, Orimo, Shin -Ichi, and Udovic, Terrence J. Fri .
"Liquid-like ionic conduction in solid lithium and sodium monocarba-closo-decaborates near or at room temperature". United States. https://doi.org/10.1002/aenm.201502237. https://www.osti.gov/servlets/purl/1329624.
@article{osti_1329624,
title = {Liquid-like ionic conduction in solid lithium and sodium monocarba-closo-decaborates near or at room temperature},
author = {Tang, Wan Si and Matsuo, Motoaki and Wu, Hui and Stavila, Vitalie and Zhou, Wei and Talin, Albert Alec and Soloninin, Alexei V. and Skoryunov, Roman V. and Babanova, Olga A. and Skripov, Alexander V. and Unemoto, Atsushi and Orimo, Shin -Ichi and Udovic, Terrence J.},
abstractNote = {Both LiCB9H10 and NaCB9H10 exhibit liquid-like cationic conductivities (≥0.03 S cm–1) in their disordered hexagonal phases near or at room temperature. Furthermore, these unprecedented conductivities and favorable stabilities enabled by the large pseudoaromatic polyhedral anions render these materials in their pristine or further modified forms as promising solid electrolytes in next-generation, power devices.},
doi = {10.1002/aenm.201502237},
journal = {Advanced Energy Materials},
number = 8,
volume = 6,
place = {United States},
year = {Fri Feb 05 00:00:00 EST 2016},
month = {Fri Feb 05 00:00:00 EST 2016}
}
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