Towards stable and commercially available perovskite solar cells

Park, Nam-Gyu; Grätzel, Michael; Miyasaka, Tsutomu; Zhu, Kai; Emery, Keith

doi:10.1038/nenergy.2016.152

Title: Towards stable and commercially available perovskite solar cells

Journal Article · 16 October 2016 · Nature Energy

DOI: https://doi.org/10.1038/nenergy.2016.152 · OSTI ID:1329525

Park, Nam-Gyu ^[1]; Grätzel, Michael ^[2]; Miyasaka, Tsutomu ^[3]; Zhu, Kai ^[4]; Emery, Keith ^[4]

Sungkyunkwan Univ., Suwon (Republic of Korea). School of Chemical Engineering
Ecole Polytechnique Federale Lausanne (Switzlerland). Inst. of Chemical Sciences and Engineering
Toin Univ. of Yokohama (Japan)
National Renewable Energy Lab. (NREL), Golden, CO (United States)

Solar cells employing a halide perovskite with an organic cation now show power conversion efficiency of up to 22%. But, these cells are facing issues towards commercialization, such as the need to achieve long-term stability and the development of a manufacturing method for the reproducible fabrication of high-performance devices. We propose a strategy to obtain stable and commercially viable perovskite solar cells. A reproducible manufacturing method is suggested, as well as routes to manage grain boundaries and interfacial charge transport. Electroluminescence is regarded as a metric to gauge theoretical efficiency. We highlight how optimizing the design of device architectures is important not only for achieving high efficiency but also for hysteresis-free and stable performance. Here, we argue that reliable device characterization is needed to ensure the advance of this technology towards practical applications. We believe that perovskite-based devices can be competitive with silicon solar modules, and discuss issues related to the safe management of toxic material.

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Research Organization:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Office (EE-4S)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1329525

Report Number(s):: NREL/JA-5900-66413

Journal Information:: Nature Energy, Journal Name: Nature Energy Journal Issue: 11 Vol. 1; ISSN 2058-7546

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Synergic Interface Optimization with Green Solvent Engineering in Mixed Perovskite Solar Cells Bu, Tongle; Wu, Lan; Liu, Xueping Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201700576	journal	July 2017
Efficient and Hysteresis-Free Perovskite Solar Cells Based on a Solution Processable Polar Fullerene Electron Transport Layer Wang, Ying-Chiao; Li, Xiaodong; Zhu, Liping Advanced Energy Materials, Vol. 7, Issue 21 https://doi.org/10.1002/aenm.201701144	journal	August 2017
The Importance of Pendant Groups on Triphenylamine-Based Hole Transport Materials for Obtaining Perovskite Solar Cells with over 20% Efficiency Zhang, Jinbao; Xu, Bo; Yang, Li Advanced Energy Materials, Vol. 8, Issue 2 https://doi.org/10.1002/aenm.201701209	journal	September 2017
Carbon Nanoparticles in High-Performance Perovskite Solar Cells Yavari, Mozhgan; Mazloum-Ardakani, Mohammad; Gholipour, Somayeh Advanced Energy Materials, Vol. 8, Issue 12 https://doi.org/10.1002/aenm.201702719	journal	January 2018
Low-Temperature Solution-Processed CuCrO ₂ Hole-Transporting Layer for Efficient and Photostable Perovskite Solar Cells Zhang, Hua; Wang, Huan; Zhu, Hongmei Advanced Energy Materials, Vol. 8, Issue 13 https://doi.org/10.1002/aenm.201702762	journal	January 2018
A New Perspective on the Role of A-Site Cations in Perovskite Solar Cells Myung, Chang Woo; Yun, Jeonghun; Lee, Geunsik Advanced Energy Materials, Vol. 8, Issue 14 https://doi.org/10.1002/aenm.201702898	journal	January 2018
Room-Temperature Vapor Deposition of Cobalt Nitride Nanofilms for Mesoscopic and Perovskite Solar Cells Kang, Jin Soo; Kim, Jae-Yup; Yoon, Jungjin Advanced Energy Materials, Vol. 8, Issue 13 https://doi.org/10.1002/aenm.201703114	journal	January 2018
Roll-to-Roll Slot Die Coated Perovskite for Efficient Flexible Solar Cells Galagan, Yulia; Di Giacomo, Francesco; Gorter, Harrie Advanced Energy Materials, Vol. 8, Issue 32 https://doi.org/10.1002/aenm.201801935	journal	October 2018
Excitation Density Dependent Photoluminescence Quenching and Charge Transfer Efficiencies in Hybrid Perovskite/Organic Semiconductor Bilayers Kim, Jinhyun; Godin, Robert; Dimitrov, Stoichko D. Advanced Energy Materials, Vol. 8, Issue 35 https://doi.org/10.1002/aenm.201802474	journal	October 2018
Fusing Nanowires into Thin Films: Fabrication of Graded‐Heterojunction Perovskite Solar Cells with Enhanced Performance Zhang, Yi; Yang, Hanjun; Chen, Min Advanced Energy Materials, Vol. 9, Issue 22 https://doi.org/10.1002/aenm.201900243	journal	May 2019
Influence of Grain Size on Phase Transitions in Halide Perovskite Films Stavrakas, Camille; Zelewski, Szymon J.; Frohna, Kyle Advanced Energy Materials, Vol. 9, Issue 35 https://doi.org/10.1002/aenm.201901883	journal	August 2019
Processing‐Performance Evolution of Perovskite Solar Cells: From Large Grain Polycrystalline Films to Single Crystals Haque, Md Azimul; Troughton, Joel; Baran, Derya Advanced Energy Materials, Vol. 10, Issue 13 https://doi.org/10.1002/aenm.201902762	journal	April 2020
Wide‐Bandgap Perovskite/Gallium Arsenide Tandem Solar Cells Li, Zijia; Kim, Tae Hak; Han, Sung Yong Advanced Energy Materials, Vol. 10, Issue 6 https://doi.org/10.1002/aenm.201903085	journal	December 2019
Electron‐Beam‐Related Studies of Halide Perovskites: Challenges and Opportunities Ran, Junhui; Dyck, Ondrej; Wang, Xiaozheng Advanced Energy Materials, Vol. 10, Issue 26 https://doi.org/10.1002/aenm.201903191	journal	February 2020
Development of Dopant‐Free Organic Hole Transporting Materials for Perovskite Solar Cells Pham, Hong Duc; Yang, Terry Chien‐Jen; Jain, Sagar M. Advanced Energy Materials, Vol. 10, Issue 13 https://doi.org/10.1002/aenm.201903326	journal	April 2020
A Purified, Solvent‐Intercalated Precursor Complex for Wide‐Process‐Window Fabrication of Efficient Perovskite Solar Cells and Modules Ozaki, Masashi; Shimazaki, Ai; Jung, Mina Angewandte Chemie, Vol. 131, Issue 28 https://doi.org/10.1002/ange.201902235	journal	May 2019
A Scalable Methylamine Gas Healing Strategy for High‐Efficiency Inorganic Perovskite Solar Cells Shao, Zhipeng; Wang, Zaiwei; Li, Zhipeng Angewandte Chemie International Edition, Vol. 58, Issue 17 https://doi.org/10.1002/anie.201814024	journal	March 2019
A Purified, Solvent‐Intercalated Precursor Complex for Wide‐Process‐Window Fabrication of Efficient Perovskite Solar Cells and Modules Ozaki, Masashi; Shimazaki, Ai; Jung, Mina Angewandte Chemie International Edition, Vol. 58, Issue 28 https://doi.org/10.1002/anie.201902235	journal	July 2019
Bandgap Optimization of Perovskite Semiconductors for Photovoltaic Applications Xiao, Zewen; Zhou, Yuanyuan; Hosono, Hideo Chemistry - A European Journal, Vol. 24, Issue 10 https://doi.org/10.1002/chem.201705031	journal	January 2018
Femtosecond Charge-Injection Dynamics at Hybrid Perovskite Interfaces Grancini, Giulia; Viola, Daniele; Lee, Yonghui ChemPhysChem, Vol. 18, Issue 17 https://doi.org/10.1002/cphc.201700492	journal	July 2017
An Old Dog with New Tricks - Additions to the Cesium Lithium Chloride System: Cs ₃ Li ₂ Cl ₅ and the Hydrated Cs ₃ LiCl ₄ ·4H ₂ O : An Old Dog with New Tricks - Additions to the Cesium Lithium Chloride System: Cs Ortner, Teresa S.; Scheifers, Jan P.; Flores, Justin European Journal of Inorganic Chemistry, Vol. 2019, Issue 30 https://doi.org/10.1002/ejic.201900774	journal	August 2019
Ag/In lead‐free double perovskites Liu, Fang; Marongiu, Daniela; Pau, Riccardo EcoMat, Vol. 2, Issue 1 https://doi.org/10.1002/eom2.12017	journal	February 2020
Potential Substitutes for Replacement of Lead in Perovskite Solar Cells: A Review Kour, Ravinder; Arya, Sandeep; Verma, Sonali Global Challenges, Vol. 3, Issue 11 https://doi.org/10.1002/gch2.201900050	journal	July 2019
Memristors with organic‐inorganic halide perovskites Zhao, Xiaoning; Xu, Haiyang; Wang, Zhongqiang InfoMat https://doi.org/10.1002/inf2.12012	journal	May 2019
Interfacial Passivation of the p-Doped Hole-Transporting Layer Using General Insulating Polymers for High-Performance Inverted Perovskite Solar Cells Zhang, Fan; Song, Jun; Hu, Rui Small, Vol. 14, Issue 19 https://doi.org/10.1002/smll.201704007	journal	April 2018
General Nondestructive Passivation by 4‐Fluoroaniline for Perovskite Solar Cells with Improved Performance and Stability Zhao, Shenghe; Xie, Jiangsheng; Cheng, Guanghui Small, Vol. 14, Issue 50 https://doi.org/10.1002/smll.201803350	journal	October 2018
Benchmarking Chemical Stability of Arbitrarily Mixed 3D Hybrid Halide Perovskites for Solar Cell Applications García‐Fernández, Alberto; Juarez‐Perez, Emilio J.; Castro‐García, Socorro Small Methods, Vol. 2, Issue 10 https://doi.org/10.1002/smtd.201800242	journal	August 2018
Efficient Semitransparent CsPbI ₃ Quantum Dots Photovoltaics Using a Graphene Electrode Tavakoli, Mohammad Mahdi; Nasilowski, Michel; Zhao, Jiayuan Small Methods, Vol. 3, Issue 12 https://doi.org/10.1002/smtd.201900449	journal	August 2019
Inorganic Perovskite Solar Cells: A Rapidly Growing Field Chen, Haining; Xiang, Sisi; Li, Weiping Solar RRL, Vol. 2, Issue 2 https://doi.org/10.1002/solr.201700188	journal	January 2018
Performance Enhancement of Perovskite Solar Cells Induced by Lead Acetate as an Additive Tang, Guanqi; You, Peng; Tai, Qidong Solar RRL, Vol. 2, Issue 6 https://doi.org/10.1002/solr.201800066	journal	April 2018
Interface Engineering in n‐i‐p Metal Halide Perovskite Solar Cells Yang, Zhi; Dou, Jinjuan; Wang, Minqiang Solar RRL, Vol. 2, Issue 12 https://doi.org/10.1002/solr.201800177	journal	September 2018
Cu ₂ ZnSnS ₄ Quantum Dots as Hole Transport Material for Enhanced Charge Extraction and Stability in All‐Inorganic CsPbBr ₃ Perovskite Solar Cells Zhou, Zheng‐Ji; Deng, Yue‐Qing; Zhang, Pan‐Pan Solar RRL, Vol. 3, Issue 4 https://doi.org/10.1002/solr.201800354	journal	February 2019
Discrete SnO ₂ Nanoparticle‐Modified Poly(3,4‐Ethylenedioxythiophene):Poly(Styrenesulfonate) for Efficient Perovskite Solar Cells Jia, Pengcheng; Bi, Wentao; Huang, Xin Solar RRL, Vol. 3, Issue 10 https://doi.org/10.1002/solr.201900162	journal	July 2019
Impact of Linking Topology on the Properties of Carbazole‐Based Hole‐Transport Materials and their Application in Solid‐State Mesoscopic Solar Cells Wang, Linqin; Sheibani, Esmaeil; Guo, Yu Solar RRL, Vol. 3, Issue 9 https://doi.org/10.1002/solr.201900196	journal	May 2019
Molecular Engineering of the Fullerene‐Based Electron Transport Layer Materials for Improving Ambient Stability of Perovskite Solar Cells Elnaggar, Mohamed; Elshobaki, Moneim; Mumyatov, Alexander Solar RRL, Vol. 3, Issue 9 https://doi.org/10.1002/solr.201900223	journal	May 2019
Application of a Tetra‐TPD‐Type Hole‐Transporting Material Fused by a Tröger's Base Core in Perovskite Solar Cells Braukyla, Titas; Xia, Rui; Malinauskas, Tadas Solar RRL, Vol. 3, Issue 9 https://doi.org/10.1002/solr.201900224	journal	May 2019
High Efficiency (16.37%) of Cesium Bromide—Passivated All‐Inorganic CsPbI ₂ Br Perovskite Solar Cells Zhang, Yuqing; Wu, Cuncun; Wang, Duo Solar RRL, Vol. 3, Issue 11 https://doi.org/10.1002/solr.201900254	journal	August 2019
Strategies Toward Extending the Near‐Infrared Photovoltaic Response of Perovskite Solar Cells Bai, Yiming; Lang, Kun; Zhao, Chunyan Solar RRL, Vol. 4, Issue 2 https://doi.org/10.1002/solr.201900280	journal	August 2019
A Review on Energy Band‐Gap Engineering for Perovskite Photovoltaics Hu, Zhaosheng; Lin, Zhenhua; Su, Jie Solar RRL, Vol. 3, Issue 12 https://doi.org/10.1002/solr.201900304	journal	September 2019
Toward a New Energy Era: Self‐Driven Integrated Systems Based on Perovskite Solar Cells Qiu, Jian; Shen, Yue; Li, Bixin Solar RRL, Vol. 3, Issue 11 https://doi.org/10.1002/solr.201900320	journal	September 2019
Interface Engineering of Cubic Zinc Metatitanate as an Excellent Electron Transport Material for Stable Perovskite Solar Cells Han, Faming; Wu, Lina; Huang, Xiaofeng Solar RRL, Vol. 4, Issue 4 https://doi.org/10.1002/solr.201900533	journal	April 2020
Discrete SnO ₂ Nanoparticle‐Modified Poly(3,4‐Ethylenedioxythiophene):Poly(Styrenesulfonate) for Efficient Perovskite Solar Cells Jia, Pengcheng; Bi, Wentao; Huang, Xin Solar RRL, Vol. 3, Issue 10 https://doi.org/10.1002/solr.201970103	journal	October 2019
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Advances in Polymer-Based Photovoltaic Cells: Review of Pioneering Materials, Design, and Device Physics Tiwari, Sanjay; Tiwari, Tanya; Carter, Sue A. Handbook of Ecomaterials https://doi.org/10.1007/978-3-319-48281-1_59-1	book	December 2017
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Perovskite Materials in Photovoltaics Wang, Wei; Shao, Zongping Revolution of Perovskite https://doi.org/10.1007/978-981-15-1267-4_7	book	January 2020
Composition-Dependent Degradation of Hybrid and Inorganic Lead Perovskites in Ambient Conditions Calisi, Nicola; Caporali, Stefano; Milanesi, Alessio Topics in Catalysis, Vol. 61, Issue 9-11 https://doi.org/10.1007/s11244-018-0922-5	journal	April 2018
Synergy of ammonium chloride and moisture on perovskite crystallization for efficient printable mesoscopic solar cells Rong, Yaoguang; Hou, Xiaomeng; Hu, Yue Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14555	journal	February 2017
11% efficiency solid-state dye-sensitized solar cells with copper(II/I) hole transport materials Cao, Yiming; Saygili, Yasemin; Ummadisingu, Amita Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15390	journal	June 2017
In-situ cross-linking strategy for efficient and operationally stable methylammoniun lead iodide solar cells Li, Xiaodong; Zhang, Wenxiao; Wang, Ying-Chiao Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06204-2	journal	September 2018
Tailoring vertical phase distribution of quasi-two-dimensional perovskite films via surface modification of hole-transporting layer Liu, Tiefeng; Jiang, Youyu; Qin, Minchao Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08843-5	journal	February 2019
Impacts of alkaline on the defects property and crystallization kinetics in perovskite solar cells Chen, Yihua; Li, Nengxu; Wang, Ligang Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09093-1	journal	March 2019
A chemically inert bismuth interlayer enhances long-term stability of inverted perovskite solar cells Wu, Shaohang; Chen, Rui; Zhang, Shasha Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09167-0	journal	March 2019
Atomic-level passivation mechanism of ammonium salts enabling highly efficient perovskite solar cells Alharbi, Essa A.; Alyamani, Ahmed Y.; Kubicki, Dominik J. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10985-5	journal	July 2019
Carrier lifetime enhancement in halide perovskite via remote epitaxy Jiang, Jie; Sun, Xin; Chen, Xinchun Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12056-1	journal	September 2019
A fluorene-terminated hole-transporting material for highly efficient and stable perovskite solar cells Jeon, Nam Joong; Na, Hyejin; Jung, Eui Hyuk Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0200-6	journal	July 2018
Reduction of lead leakage from damaged lead halide perovskite solar modules using self-healing polymer-based encapsulation Jiang, Yan; Qiu, Longbin; Juarez-Perez, Emilio J. Nature Energy, Vol. 4, Issue 7 https://doi.org/10.1038/s41560-019-0406-2	journal	June 2019
On-device lead sequestration for perovskite solar cells Li, Xun; Zhang, Fei; He, Haiying Nature, Vol. 578, Issue 7796 https://doi.org/10.1038/s41586-020-2001-x	journal	February 2020
Hazard potential of perovskite solar cell technology for potential implementation of “safe-by-design” approach Bae, Su-Yong; Lee, Su Young; Kim, Ji-wan Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-018-37229-8	journal	March 2019
Light Intensity-dependent Variation in Defect Contributions to Charge Transport and Recombination in a Planar MAPbI3 Perovskite Solar Cell Ryu, Shinyoung; Nguyen, Duc Cuong; Ha, Na Young Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-56338-6	journal	December 2019
Optical determination of Shockley-Read-Hall and interface recombination currents in hybrid perovskites Sarritzu, Valerio; Sestu, Nicola; Marongiu, Daniela Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep44629	journal	March 2017
Do grain boundaries dominate non-radiative recombination in CH ₃ NH ₃ PbI ₃ perovskite thin films? Yang, Mengjin; Zeng, Yining; Li, Zhen Physical Chemistry Chemical Physics, Vol. 19, Issue 7 https://doi.org/10.1039/c6cp08770a	journal	January 2017
High-throughput and tunable synthesis of colloidal CsPbX ₃ perovskite nanocrystals in a heterogeneous system by microwave irradiation Long, Zi; Ren, Hong; Sun, Jianghui Chemical Communications, Vol. 53, Issue 71 https://doi.org/10.1039/c7cc04862a	journal	January 2017
Extrinsic ion migration in perovskite solar cells Li, Zhen; Xiao, Chuanxiao; Yang, Ye Energy & Environmental Science, Vol. 10, Issue 5 https://doi.org/10.1039/c7ee00358g	journal	January 2017
Reconsidering figures of merit for performance and stability of perovskite photovoltaics Khenkin, Mark V.; K. M., Anoop; Visoly-Fisher, Iris Energy & Environmental Science, Vol. 11, Issue 4 https://doi.org/10.1039/c7ee02956j	journal	January 2018
Selective growth of layered perovskites for stable and efficient photovoltaics Cho, Kyung Taek; Grancini, Giulia; Lee, Yonghui Energy & Environmental Science, Vol. 11, Issue 4 https://doi.org/10.1039/c7ee03513f	journal	January 2018
High-efficiency near-infrared enabled planar perovskite solar cells by embedding upconversion nanocrystals Meng, Fan-Li; Wu, Jiao-Jiao; Zhao, Er-Fei Nanoscale, Vol. 9, Issue 46 https://doi.org/10.1039/c7nr05416e	journal	January 2017
The synergistic effect of non-stoichiometry and Sb-doping on air-stable α-CsPbI ₃ for efficient carbon-based perovskite solar cells Xiang, Sisi; Li, Weiping; Wei, Ya Nanoscale, Vol. 10, Issue 21 https://doi.org/10.1039/c7nr09657g	journal	January 2018
Mixed cation hybrid lead halide perovskites with enhanced performance and stability Xu, Feng; Zhang, Taiyang; Li, Ge Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/c7ta00042a	journal	January 2017
A dimeric fullerene derivative for efficient inverted planar perovskite solar cells with improved stability Tian, Chengbo; Kochiss, Kevin; Castro, Edison Journal of Materials Chemistry A, Vol. 5, Issue 16 https://doi.org/10.1039/c7ta00362e	journal	January 2017
Methylamine lead bromide perovskite/protonated graphitic carbon nitride nanocomposites: interfacial charge carrier dynamics and photocatalysis Pu, Ying-Chih; Fan, Hsiao-Chuan; Liu, Tzu-Wei Journal of Materials Chemistry A, Vol. 5, Issue 48 https://doi.org/10.1039/c7ta08190a	journal	January 2017
Room-temperature processed films of colloidal carved rod-shaped nanocrystals of reduced tungsten oxide as interlayers for perovskite solar cells Masi, Sofia; Mastria, Rosanna; Scarfiello, Riccardo Physical Chemistry Chemical Physics, Vol. 20, Issue 16 https://doi.org/10.1039/c8cp00645h	journal	January 2018
New insights into the origin of hysteresis behavior in perovskite solar cells Li, Xin; Wang, Yichao; Tai, Meiqian Physical Chemistry Chemical Physics, Vol. 20, Issue 23 https://doi.org/10.1039/c8cp01432a	journal	January 2018
First-principles study of anion diffusion in lead-free halide double perovskites Lan, Chunfeng; Zhao, Shuai; Luo, Jingting Physical Chemistry Chemical Physics, Vol. 20, Issue 37 https://doi.org/10.1039/c8cp04150d	journal	January 2018
Imperfections and their passivation in halide perovskite solar cells Chen, Bo; Rudd, Peter N.; Yang, Shuang Chemical Society Reviews, Vol. 48, Issue 14 https://doi.org/10.1039/c8cs00853a	journal	January 2019
A non-equilibrium Ti ⁴⁺ doping strategy for an efficient hematite electron transport layer in perovskite solar cells Zhu, Weidong; Zhang, Qianni; Zhang, Chunfu Dalton Transactions, Vol. 47, Issue 18 https://doi.org/10.1039/c8dt00692j	journal	January 2018
Extending lead-free hybrid photovoltaic materials to new structures: thiazolium, aminothiazolium and imidazolium iodobismuthates Li, Tianyue; Wang, Qifei; Nichol, Gary S. Dalton Transactions, Vol. 47, Issue 20 https://doi.org/10.1039/c8dt00864g	journal	January 2018
Phosphomolybdic acid as an efficient hole injection material in perovskite optoelectronic devices Fallah Hamidabadi, Vahid; Momblona, Cristina; Pérez-Del-Rey, Daniel Dalton Transactions, Vol. 48, Issue 1 https://doi.org/10.1039/c8dt03680b	journal	January 2019
Improving the stability and performance of perovskite solar cells via off-the-shelf post-device ligand treatment Zhang, Hong; Ren, Xingang; Chen, Xiwen Energy & Environmental Science, Vol. 11, Issue 8 https://doi.org/10.1039/c8ee00580j	journal	January 2018
Nacre-inspired crystallization and elastic “brick-and-mortar” structure for a wearable perovskite solar module Hu, Xiaotian; Huang, Zengqi; Li, Fengyu Energy & Environmental Science, Vol. 12, Issue 3 https://doi.org/10.1039/c8ee01799a	journal	January 2019
Mixed phononic and non-phononic transport in hybrid lead halide perovskites: glass-crystal duality, dynamical disorder, and anharmonicity Zhu, Taishan; Ertekin, Elif Energy & Environmental Science, Vol. 12, Issue 1 https://doi.org/10.1039/c8ee02820f	journal	January 2019
Chemical stability and instability of inorganic halide perovskites Zhou, Yuanyuan; Zhao, Yixin Energy & Environmental Science, Vol. 12, Issue 5 https://doi.org/10.1039/c8ee03559h	journal	January 2019
MAPbI ₃ microneedle-arrays for perovskite photovoltaic application Mahmood, Khalid; Khalid, Arshi; Mehran, Muhammad Taqi Nanoscale Advances, Vol. 1, Issue 1 https://doi.org/10.1039/c8na00064f	journal	January 2019
High crystallization of a multiple cation perovskite absorber for low-temperature stable ZnO solar cells with high-efficiency of over 20% Dong, Xuemei; Chen, Dong; Zhou, Junshuai Nanoscale, Vol. 10, Issue 15 https://doi.org/10.1039/c8nr00152a	journal	January 2018
Stable, color-tunable 2D SCN-based perovskites: revealing the critical influence of an asymmetric pseudo-halide on constituent ions Li, Chia-Hsin; Tsai, Chang-Che; Liao, Ming-Yun Nanoscale, Vol. 11, Issue 6 https://doi.org/10.1039/c8nr08014c	journal	January 2019
Realizing a highly luminescent perovskite thin film by controlling the grain size and crystallinity through solvent vapour annealing Chin, Sang-Hyun; Choi, Jin Woo; Woo, Hee Chul Nanoscale, Vol. 11, Issue 13 https://doi.org/10.1039/c8nr09947b	journal	January 2019
All-inorganic lead-free perovskites for optoelectronic applications Wang, Xingtao; Zhang, Taiyang; Lou, Yongbing Materials Chemistry Frontiers, Vol. 3, Issue 3 https://doi.org/10.1039/c8qm00611c	journal	January 2019
Improved performance and stability of perovskite solar cells with bilayer electron-transporting layers Jiang, Tingting; Fu, Weifei RSC Advances, Vol. 8, Issue 11 https://doi.org/10.1039/c8ra00248g	journal	January 2018
A one-step laser process for rapid manufacture of mesoscopic perovskite solar cells prepared under high relative humidity Chen, Qian; Mokhtar, Muhamad Z.; Ke, Jack Chun-Ren Sustainable Energy & Fuels, Vol. 2, Issue 6 https://doi.org/10.1039/c8se00043c	journal	January 2018
Evaluation of multiple cation/anion perovskite solar cells through life cycle assessment Alberola-Borràs, Jaume-Adrià; Vidal, Rosario; Mora-Seró, Iván Sustainable Energy & Fuels, Vol. 2, Issue 7 https://doi.org/10.1039/c8se00053k	journal	January 2018
Growing high-quality CsPbBr ₃ by using porous CsPb ₂ Br ₅ as an intermediate: a promising light absorber in carbon-based perovskite solar cells Liu, Jiaming; Zhu, Liqun; Xiang, Sisi Sustainable Energy & Fuels, Vol. 3, Issue 1 https://doi.org/10.1039/c8se00442k	journal	January 2019
A novel ball milling technique for room temperature processing of TiO ₂ nanoparticles employed as the electron transport layer in perovskite solar cells and modules Singh, Mriganka; Chiang, Chien-Hung; Boopathi, Karunakara Moorthy Journal of Materials Chemistry A, Vol. 6, Issue 16 https://doi.org/10.1039/c8ta00303c	journal	January 2018
Recent progressive efforts in perovskite solar cells toward commercialization Kim, Byeong Jo; Lee, Sangwook; Jung, Hyun Suk Journal of Materials Chemistry A, Vol. 6, Issue 26 https://doi.org/10.1039/c8ta02159g	journal	January 2018
Recent progress in 2D/quasi-2D layered metal halide perovskites for solar cells Yan, Jielin; Qiu, Weiming; Wu, Gang Journal of Materials Chemistry A, Vol. 6, Issue 24 https://doi.org/10.1039/c8ta02288g	journal	January 2018
Nb-doped amorphous titanium oxide compact layer for formamidinium-based high efficiency perovskite solar cells by low-temperature fabrication Numata, Youhei; Ishikawa, Ryo; Sanehira, Yoshitaka Journal of Materials Chemistry A, Vol. 6, Issue 20 https://doi.org/10.1039/c8ta02540a	journal	January 2018
Efficient and UV-stable perovskite solar cells enabled by side chain-engineered polymeric hole-transporting layers Tsai, Chang-Hung; Li, Nan; Lee, Chia-Chen Journal of Materials Chemistry A, Vol. 6, Issue 27 https://doi.org/10.1039/c8ta03608j	journal	January 2018
Narrow optical gap ferroelectric Bi ₂ ZnTiO ₆ thin films deposited by RF sputtering Figueiras, Fábio G.; Fernandes, J. Ramiro A.; Silva, J. P. B. Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c8ta09425j	journal	January 2019
Ab initio study of the dynamics of electron trapping and detrapping processes in the CH ₃ NH ₃ PbI ₃ perovskite Zhang, Linghai; Sit, Patrick H. -L. Journal of Materials Chemistry A, Vol. 7, Issue 5 https://doi.org/10.1039/c8ta09512d	journal	January 2019
Recent advances in the fabrication of graphene–ZnO heterojunctions for optoelectronic device applications Liang, Feng-Xia; Gao, Yang; Xie, Chao Journal of Materials Chemistry C, Vol. 6, Issue 15 https://doi.org/10.1039/c8tc00172c	journal	January 2018
Beyond efficiency: phenothiazine, a new commercially viable substituent for hole transport materials in perovskite solar cells Maciejczyk, Michal R.; Chen, Ruihao; Brown, Alasdair Journal of Materials Chemistry C, Vol. 7, Issue 28 https://doi.org/10.1039/c8tc05773g	journal	January 2019
Performance enhancement of AgBi ₂ I ₇ solar cells by modulating a solvent-mediated adduct and tuning remnant BiI ₃ in one-step crystallization Kulkarni, Ashish; Jena, Ajay K.; Ikegami, Masashi Chemical Communications, Vol. 55, Issue 28 https://doi.org/10.1039/c9cc00733d	journal	January 2019
Refractive index change dominates the transient absorption response of metal halide perovskite thin films in the near infrared Pasanen, Hannu P.; Vivo, Paola; Canil, Laura Physical Chemistry Chemical Physics, Vol. 21, Issue 27 https://doi.org/10.1039/c9cp02291k	journal	January 2019
Materials chemistry and engineering in metal halide perovskite lasers Dong, Haiyun; Zhang, Chunhuan; Liu, Xiaolong Chemical Society Reviews, Vol. 49, Issue 3 https://doi.org/10.1039/c9cs00598f	journal	January 2020
An interface stabilized perovskite solar cell with high stabilized efficiency and low voltage loss Yoo, Jason J.; Wieghold, Sarah; Sponseller, Melany C. Energy & Environmental Science, Vol. 12, Issue 7 https://doi.org/10.1039/c9ee00751b	journal	January 2019
Long-term ambient air-stable cubic CsPbBr ₃ perovskite quantum dots using molecular bromine Thapa, Surakcha; Bhardwaj, Karishma; Basel, Siddhant Nanoscale Advances, Vol. 1, Issue 9 https://doi.org/10.1039/c9na00486f	journal	January 2019
AgBiS ₂ as a low-cost and eco-friendly all-inorganic photovoltaic material: nanoscale morphology–property relationship Ju, Ming-Gang; Dai, Jun; Ma, Liang Nanoscale Advances, Vol. 2, Issue 2 https://doi.org/10.1039/c9na00505f	journal	January 2020
Ultrafast carrier dynamics of metal halide perovskite nanocrystals and perovskite-composites Mondal, Navendu; De, Apurba; Das, Somnath Nanoscale, Vol. 11, Issue 20 https://doi.org/10.1039/c9nr01745c	journal	January 2019
Solvothermal synthesis of Mn-doped CsPbCl ₃ perovskite nanocrystals with tunable morphology and their size-dependent optical properties Liu, Chang; Lin, Jing; Zhai, Wei RSC Advances, Vol. 9, Issue 67 https://doi.org/10.1039/c9ra08289a	journal	January 2019
Carrier-gas assisted vapor deposition for highly tunable morphology of halide perovskite thin films Clark, Catherine P.; Voigt, Bryan; Aydil, Eray S. Sustainable Energy & Fuels, Vol. 3, Issue 9 https://doi.org/10.1039/c9se00200f	journal	January 2019
A photo-crosslinkable bis-triarylamine side-chain polymer as a hole-transport material for stable perovskite solar cells Tremblay, Marie-Hélène; Schutt, Kelly; Zhang, Yadong Sustainable Energy & Fuels, Vol. 4, Issue 1 https://doi.org/10.1039/c9se00513g	journal	January 2020
Highly efficient and stable inverted perovskite solar cells using down-shifting quantum dots as a light management layer and moisture-assisted film growth Tavakoli, Mohammad Mahdi; Dastjerdi, Hadi Tavakoli; Prochowicz, Daniel Journal of Materials Chemistry A, Vol. 7, Issue 24 https://doi.org/10.1039/c9ta03131f	journal	January 2019
Lead-free low-dimensional tin halide perovskites with functional organic spacers: breaking the charge-transport bottleneck Ju, Ming-Gang; Dai, Jun; Ma, Liang Journal of Materials Chemistry A, Vol. 7, Issue 28 https://doi.org/10.1039/c9ta04486h	journal	January 2019
Structured crystallization for efficient all-inorganic perovskite solar cells with high phase stability Wang, Zhen; Baranwal, Ajay K.; Kamarudin, Muhammad Akmal Journal of Materials Chemistry A, Vol. 7, Issue 35 https://doi.org/10.1039/c9ta05556h	journal	January 2019
Potassium ions as a kinetic controller in ionic double layers for hysteresis-free perovskite solar cells Kim, Seul-Gi; Li, Cheng; Guerrero, Antonio Journal of Materials Chemistry A, Vol. 7, Issue 32 https://doi.org/10.1039/c9ta07595j	journal	January 2019
A thermally stable, barium-stabilized α-CsPbI ₃ perovskite for optoelectronic devices Kajal, Sandeep; Kim, Gi-Hwan; Myung, Chang Woo Journal of Materials Chemistry A, Vol. 7, Issue 38 https://doi.org/10.1039/c9ta07827d	journal	January 2019
Direct emission from quartet excited states triggered by upconversion phenomena in solid-phase synthesized fluorescent lead-free organic–inorganic hybrid compounds Jana, Atanu; Zhumagali, Shynggys; Ba, Qiankai Journal of Materials Chemistry A, Vol. 7, Issue 46 https://doi.org/10.1039/c9ta08268a	journal	January 2019
Morphology control towards a greener, non-halogenated solvent system processed CH ₃ NH ₃ PbI ₃ film for high performance perovskite solar cells Tan, Wan-Yi; Cheng, Peng-Peng; Zhang, Yong-Wen Journal of Materials Chemistry C, Vol. 7, Issue 20 https://doi.org/10.1039/c9tc00812h	journal	January 2019
A partially-planarised hole-transporting quart- p -phenylene for perovskite solar cells Mora-Fuentes, Juan P.; Cortizo-Lacalle, Diego; Collavini, Silvia Journal of Materials Chemistry C, Vol. 7, Issue 15 https://doi.org/10.1039/c9tc01076a	journal	January 2019
Skillfully deflecting the question: a small amount of piperazine-1,4-diium iodide radically enhances the thermal stability of CsPbI ₃ perovskite Wang, Hailiang; Xiang, Sisi; Li, Weiping Journal of Materials Chemistry C, Vol. 7, Issue 38 https://doi.org/10.1039/c9tc03576a	journal	January 2019
Sulfur-fused perylene diimide electron transport layers allow >400 h operational lifetime of methylammonium lead iodide photovoltaics Nakayama, Hidenori; Zheng, Yonghao; Schneider, Julia A. Journal of Materials Chemistry C, Vol. 7, Issue 36 https://doi.org/10.1039/c9tc03877a	journal	January 2019
Complexes of BiCl ₃ with hydrazone derived ligands: a Möbius-like discrete metal chelate versus a salt-like porous polymeric structure Akbari Afkhami, Farhad; Mahmoudi, Ghodrat; Miroslaw, Barbara New Journal of Chemistry, Vol. 44, Issue 22 https://doi.org/10.1039/d0nj00930j	journal	January 2020
Perspective: Theory and simulation of hybrid halide perovskites Whalley, Lucy D.; Frost, Jarvist M.; Jung, Young-Kwang The Journal of Chemical Physics, Vol. 146, Issue 22 https://doi.org/10.1063/1.4984964	journal	June 2017
Exploring wide bandgap metal oxides for perovskite solar cells Shin, S. S.; Lee, S. J.; Seok, S. I. APL Materials, Vol. 7, Issue 2 https://doi.org/10.1063/1.5055607	journal	February 2019
In situ investigation of light soaking in organolead halide perovskite films Zhong, Yu; Luna, Carlos Andres Melo; Hildner, Richard APL Materials, Vol. 7, Issue 4 https://doi.org/10.1063/1.5086125	journal	April 2019
Toward air-stable field-effect transistors with a tin iodide-based hybrid perovskite semiconductor Matsushima, Toshinori; Terakawa, Shinobu; Leyden, Matthew R. Journal of Applied Physics, Vol. 125, Issue 23 https://doi.org/10.1063/1.5097433	journal	June 2019
Large metal halide perovskite crystals for field-effect transistor applications Matsushima, Toshinori; Leyden, Matthew R.; Fujihara, Takashi Applied Physics Letters, Vol. 115, Issue 12 https://doi.org/10.1063/1.5116411	journal	September 2019
Pressure responses of halide perovskites with various compositions, dimensionalities, and morphologies Li, Mei; Liu, Tianbiao; Wang, Yonggang Matter and Radiation at Extremes, Vol. 5, Issue 1 https://doi.org/10.1063/1.5133653	journal	January 2020
Fabrications and Applications of ZnO Nanomaterials in Flexible Functional Devices-A Review Rong, Ping; Ren, Shuai; Yu, Qi Critical Reviews in Analytical Chemistry, Vol. 49, Issue 4 https://doi.org/10.1080/10408347.2018.1531691	journal	December 2018
Interfacial crosslinked quasi-2D perovskite with boosted carrier transport and enhanced stability Zhang, Taiyang; Hui, Yong; Chen, Liang Journal of Physics D: Applied Physics, Vol. 51, Issue 40 https://doi.org/10.1088/1361-6463/aad7de	journal	August 2018
Roadmap on halide perovskite and related devices Jeong, Dong-Nyuk; Yang, June-Mo; Park, Nam-Gyu Nanotechnology, Vol. 31, Issue 15 https://doi.org/10.1088/1361-6528/ab59ed	journal	January 2020
Effect of PQT-12 interface layer on the performance of PCDTBT: PCBM bulk heterojunction solar cells Kumar, Amit; Ratan, Smrity; Jarwal, Deepak Kumar Materials Research Express, Vol. 6, Issue 11 https://doi.org/10.1088/2053-1591/ab4708	journal	September 2019
Graphene as charge transport layers in lead free perovskite solar cell Materials Research Express, Vol. 6, Issue 11, 115611 https://doi.org/10.1088/2053-1591/ab4b02	journal	October 2019
Advances in modelling and simulation of halide perovskites for solar cell applications Yu, Chol-Jun Journal of Physics: Energy, Vol. 1, Issue 2 https://doi.org/10.1088/2515-7655/aaf143	journal	January 2019
Inorganic–organic halide perovskites for new photovoltaic technology Li, Dongmei; Shi, Jiangjian; Xu, Yuzhuan National Science Review, Vol. 5, Issue 4 https://doi.org/10.1093/nsr/nwx100	journal	August 2017
DFT study of the electronic properties and the cubic to tetragonal phase transition in RbCaF 3 Ehsan, Sohaib; Tröster, Andreas; Tran, Fabien Physical Review Materials, Vol. 2, Issue 9 https://doi.org/10.1103/physrevmaterials.2.093610	journal	September 2018
Giant Rashba splitting in 2D organic-inorganic halide perovskites measured by transient spectroscopies Zhai, Yaxin; Baniya, Sangita; Zhang, Chuang Science Advances, Vol. 3, Issue 7 https://doi.org/10.1126/sciadv.1700704	journal	July 2017
Bication lead iodide 2D perovskite component to stabilize inorganic α-CsPbI ₃ perovskite phase for high-efficiency solar cells Zhang, Taiyang; Dar, M. Ibrahim; Li, Ge Science Advances, Vol. 3, Issue 9 https://doi.org/10.1126/sciadv.1700841	journal	September 2017
Defect-engineered epitaxial VO _2±δ in strain engineering of heterogeneous soft crystals Wang, Yiping; Sun, Xin; Chen, Zhizhong Science Advances, Vol. 4, Issue 5 https://doi.org/10.1126/sciadv.aar3679	journal	May 2018
High-efficiency large-area perovskite photovoltaic modules achieved via electrochemically assembled metal-filamentary nanoelectrodes Hong, Soonil; Lee, Jinho; Kang, Hongkyu Science Advances, Vol. 4, Issue 8 https://doi.org/10.1126/sciadv.aat3604	journal	August 2018
Efficient and stable solution-processed planar perovskite solar cells via contact passivation Tan, Hairen; Jain, Ankit; Voznyy, Oleksandr Science, Vol. 355, Issue 6326 https://doi.org/10.1126/science.aai9081	journal	February 2017
Challenges for commercializing perovskite solar cells Rong, Yaoguang; Hu, Yue; Mei, Anyi Science, Vol. 361, Issue 6408 https://doi.org/10.1126/science.aat8235	journal	September 2018
Carrier lifetimes of >1 μs in Sn-Pb perovskites enable efficient all-perovskite tandem solar cells Tong, Jinhui; Song, Zhaoning; Kim, Dong Hoe Science, Vol. 364, Issue 6439 https://doi.org/10.1126/science.aav7911	journal	April 2019
All-inorganic inverse perovskite solar cells using zinc oxide nanocolloids on spin coated perovskite layer Shibayama, Naoyuki; Kanda, Hiroyuki; Yusa, Shin-ichi Nano Convergence, Vol. 4, Issue 1 https://doi.org/10.1186/s40580-017-0113-2	journal	July 2017
Environment versus sustainable energy: The case of lead halide perovskite-based solar cells Babayigit, Aslihan; Boyen, Hans-Gerd; Conings, Bert MRS Energy & Sustainability, Vol. 5 https://doi.org/10.1557/mre.2017.17	journal	January 2018
Synergistic Effect of Elevated Device Temperature and Excess Charge Carriers on the Rapid Light-Induced Degradation of Perovskite Solar Cells Y., Liu,; J., Song,; J., Huang, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/zj42-ct77	text	January 2019
Atomic-level passivation mechanism of ammonium salts enabling highly efficient perovskite solar cells. Alharbi, Essa A.; Alyamani, Ahmed Y.; Kubicki, Dominik Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.43116	text	January 2019
Nanostructured Perovskite Solar Cells McDonald, Calum; Ni, Chengsheng; Maguire, Paul Nanomaterials, Vol. 9, Issue 10 https://doi.org/10.3390/nano9101481	journal	October 2019
Charge Transfer in Mixed-Phase TiO2 Photoelectrodes for Perovskite Solar Cells Nikolskaia, Anna; Vildanova, Marina; Kozlov, Sergey Sustainability, Vol. 12, Issue 3 https://doi.org/10.3390/su12030788	journal	January 2020
Performance Loss Analysis and Design Space Optimization of Perovskite Solar Cells Agarwal, Sumanshu; Nair, Pradeep R. arXiv https://doi.org/10.48550/arxiv.1803.04171	text	January 2018

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