DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Determination of the mechanism and extent of surface degradation in Ni-based cathode materials after repeated electrochemical cycling

Authors:
 [1]; ORCiD logo [1];  [1]; ORCiD logo [2];  [3];  [1]
  1. Center for Energy Convergence, Korea Institute of Science and Technology (KIST), Seoul 02792, South Korea
  2. Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, USA
  3. Carbon Composite Materials Research Centre, Institute of Advanced Composite Materials, KIST, Wanju-gun 55324, South Korea
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1328533
Alternate Identifier(s):
OSTI ID: 1420461
Grant/Contract Number:  
SC0012704
Resource Type:
Published Article
Journal Name:
APL Materials
Additional Journal Information:
Journal Name: APL Materials Journal Volume: 4 Journal Issue: 9; Journal ID: ISSN 2166-532X
Publisher:
American Institute of Physics
Country of Publication:
United States
Language:
English

Citation Formats

Hwang, Sooyeon, Kim, Se Young, Chung, Kyung Yoon, Stach, Eric A., Kim, Seung Min, and Chang, Wonyoung. Determination of the mechanism and extent of surface degradation in Ni-based cathode materials after repeated electrochemical cycling. United States: N. p., 2016. Web. doi:10.1063/1.4963723.
Hwang, Sooyeon, Kim, Se Young, Chung, Kyung Yoon, Stach, Eric A., Kim, Seung Min, & Chang, Wonyoung. Determination of the mechanism and extent of surface degradation in Ni-based cathode materials after repeated electrochemical cycling. United States. https://doi.org/10.1063/1.4963723
Hwang, Sooyeon, Kim, Se Young, Chung, Kyung Yoon, Stach, Eric A., Kim, Seung Min, and Chang, Wonyoung. Tue . "Determination of the mechanism and extent of surface degradation in Ni-based cathode materials after repeated electrochemical cycling". United States. https://doi.org/10.1063/1.4963723.
@article{osti_1328533,
title = {Determination of the mechanism and extent of surface degradation in Ni-based cathode materials after repeated electrochemical cycling},
author = {Hwang, Sooyeon and Kim, Se Young and Chung, Kyung Yoon and Stach, Eric A. and Kim, Seung Min and Chang, Wonyoung},
abstractNote = {},
doi = {10.1063/1.4963723},
journal = {APL Materials},
number = 9,
volume = 4,
place = {United States},
year = {Tue Sep 27 00:00:00 EDT 2016},
month = {Tue Sep 27 00:00:00 EDT 2016}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1063/1.4963723

Citation Metrics:
Cited by: 18 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

An Electron Energy-Loss Spectrometry Study of Charge Compensation in LiNi 0.8 Co 0.2 O 2
journal, April 2003

  • Graetz, J.; Ahn, C. C.; Yazami, R.
  • The Journal of Physical Chemistry B, Vol. 107, Issue 13
  • DOI: 10.1021/jp026484y

Extraction of EELS white-line intensities of manganese compounds: Methods, accuracy, and valence sensitivity
journal, March 2006


Understanding local degradation of cycled Ni-rich cathode materials at high operating temperature for Li-ion batteries
journal, September 2014

  • Hwang, Sooyeon; Kim, Dong Hyun; Chung, Kyung Yoon
  • Applied Physics Letters, Vol. 105, Issue 10
  • DOI: 10.1063/1.4895336

Significant Improvement of Electrochemical Performance of AlF3-Coated Li[Ni0.8Co0.1Mn0.1]O2 Cathode Materials
journal, January 2007

  • Woo, S.-U.; Yoon, C. S.; Amine, K.
  • Journal of The Electrochemical Society, Vol. 154, Issue 11, p. A1005-A1009
  • DOI: 10.1149/1.2776160

Review—High-Capacity Li[Ni 1- x Co x /2 Mn x /2 ]O 2 ( x = 0.1, 0.05, 0) Cathodes for Next-Generation Li-Ion Battery
journal, January 2015

  • Yoon, Chong S.; Choi, Moon Ho; Lim, Byung-Beom
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0101514jes

Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries
journal, March 2014

  • Lin, Feng; Markus, Isaac M.; Nordlund, Dennis
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4529

Nickel-Rich Layered Microspheres Cathodes: Lithium/Nickel Disordering and Electrochemical Performance
journal, September 2014

  • Fu, Chaochao; Li, Guangshe; Luo, Dong
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 18
  • DOI: 10.1021/am5030726

EELS analysis of cation valence states and oxygen vacancies in magnetic oxides
journal, October 2000


Electronic Structure of Lithium Nickel Oxides by Electron Energy Loss Spectroscopy
journal, June 2005

  • Koyama, Yukinori; Mizoguchi, Teruyasu; Ikeno, Hidekazu
  • The Journal of Physical Chemistry B, Vol. 109, Issue 21
  • DOI: 10.1021/jp050486b

Capacity-Fading Mechanisms of LiNiO[sub 2]-Based Lithium-Ion Batteries
journal, January 2009

  • Muto, Shunsuke; Sasano, Yusuke; Tatsumi, Kazuyoshi
  • Journal of The Electrochemical Society, Vol. 156, Issue 5
  • DOI: 10.1149/1.3076137

Observation of anisotropic microstructural changes during cycling in LiNi0.5Co0.2Mn0.3O2 cathode material
journal, February 2015


3D Woven-Like Carbon Micropattern Decorated with Silicon Nanoparticles for Use in Lithium-Ion Batteries
journal, September 2015


White lines and d -band occupancy for the 3 d transition-metal oxides and lithium transition-metal oxides
journal, June 2004


Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study
journal, January 2011

  • Xu, Bo; Fell, Christopher R.; Chi, Miaofang
  • Energy & Environmental Science, Vol. 4, Issue 6
  • DOI: 10.1039/c1ee01131f

Understanding the Degradation Mechanisms of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Material in Lithium Ion Batteries
journal, August 2013

  • Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun
  • Advanced Energy Materials, Vol. 4, Issue 1
  • DOI: 10.1002/aenm.201300787

Balancing stability and specific energy in Li-rich cathodes for lithium ion batteries: a case study of a novel Li–Mn–Ni–Co oxide
journal, January 2015

  • Li, Qi; Li, Guangshe; Fu, Chaochao
  • Journal of Materials Chemistry A, Vol. 3, Issue 19
  • DOI: 10.1039/C5TA00929D

Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011


Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries
journal, January 1998

  • Arora, Pankaj; White, Ralph E.; Doyle, Marc
  • Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667
  • DOI: 10.1149/1.1838857

Nanoscale Phase Separation, Cation Ordering, and Surface Chemistry in Pristine Li 1.2 Ni 0.2 Mn 0.6 O 2 for Li-Ion Batteries
journal, May 2013

  • Gu, Meng; Genc, Arda; Belharouak, Ilias
  • Chemistry of Materials, Vol. 25, Issue 11
  • DOI: 10.1021/cm4009392

Correlation between dissolution behavior and electrochemical cycling performance for LiNi1/3Co1/3Mn1/3O2-based cells
journal, June 2012


First Evidence of Manganese–Nickel Segregation and Densification upon Cycling in Li-Rich Layered Oxides for Lithium Batteries
journal, July 2013

  • Boulineau, Adrien; Simonin, Loïc; Colin, Jean-François
  • Nano Letters, Vol. 13, Issue 8
  • DOI: 10.1021/nl4019275