Perrhenate incorporation into binary mixed sodalites: The role of anion size and implications for technetium-99 sequestration

Dickson, Johnbull O.; Harsh, James B.; Lukens, Wayne W.; Pierce, Eric M.

doi:10.1016/j.chemgeo.2014.12.009

Title: Perrhenate incorporation into binary mixed sodalites: The role of anion size and implications for technetium-99 sequestration

Authors:

Dickson, Johnbull O. ^[1]; Harsh, James B. ^[1]; Lukens, Wayne W. ^[2]; Pierce, Eric M. ^[3]

Washington State Univ., Pullman, WA (United States). Department of Crop and Soil Sciences
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division

Publication Date:: Sat Dec 20 00:00:00 EST 2014

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Biological and Environmental Research (BER); USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1327622

Alternate Identifier(s):: OSTI ID: 1246658; OSTI ID: 1374723

Report Number(s):: LBNL-181861
Journal ID: ISSN 0009-2541; KP1702030; ERKP796

Grant/Contract Number:: AC05-00OR22725; PS02-09ER65075; AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Chemical Geology

Additional Journal Information:: Journal Volume: 395; Journal ID: ISSN 0009-2541

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 54 ENVIRONMENTAL SCIENCES; Mixed-anion sodalites; Anion selectivity; Distribution coefficient; Perrhenate; Pertechnetate; technetium-99; Nuclear waste

Citation Formats


                    Dickson, Johnbull O., Harsh, James B., Lukens, Wayne W., and Pierce, Eric M. Perrhenate incorporation into binary mixed sodalites: The role of anion size and implications for technetium-99 sequestration.  United States: N. p., 2014. 
Web.  doi:10.1016/j.chemgeo.2014.12.009.

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                    Dickson, Johnbull O., Harsh, James B., Lukens, Wayne W., & Pierce, Eric M. Perrhenate incorporation into binary mixed sodalites: The role of anion size and implications for technetium-99 sequestration.  United States.  https://doi.org/10.1016/j.chemgeo.2014.12.009

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                    Dickson, Johnbull O., Harsh, James B., Lukens, Wayne W., and Pierce, Eric M. Sat .  
"Perrhenate incorporation into binary mixed sodalites: The role of anion size and implications for technetium-99 sequestration".  United States.  https://doi.org/10.1016/j.chemgeo.2014.12.009.  https://www.osti.gov/servlets/purl/1327622.

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@article{osti_1327622,

  title        = {Perrhenate incorporation into binary mixed sodalites: The role of anion size and implications for technetium-99 sequestration},

  author       = {Dickson, Johnbull O. and Harsh, James B. and Lukens, Wayne W. and Pierce, Eric M.},

  abstractNote = {},

  doi          = {10.1016/j.chemgeo.2014.12.009},

  journal      = {Chemical Geology},

  number       = ,

  volume       = 395,

  place        = {United States},

  year         = {Sat Dec 20 00:00:00 EST 2014},

  month        = {Sat Dec 20 00:00:00 EST 2014}

}

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https://doi.org/10.1016/j.chemgeo.2014.12.009

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Cited by: 34 works

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Works referenced in this record:

Hydration and Extraction of Oxyanions
journal, January 2002

Abramov, A. A.; Dzhigirkhanov, M. S. -A.; Iofa, B. Z.
Radiochemistry, Vol. 44, Issue 3, p. 270-273
DOI: 10.1023/A:1020306823710

Synthesis and structures of M8[ALSiO4]6·(XO4)2, M = Na, Li, K; X = Cl, Mn Sodalites
journal, November 1994

Brenchley, Matthew E.; Weller, Mark T.
Zeolites, Vol. 14, Issue 8
DOI: 10.1016/0144-2449(94)90125-2

29Si MAS NMR investigations on the crystallization of nitrite-sodalite
journal, May 1996

Buhl, Josef-Christian; Reich, Dirk; Mundus, Carsten
Reaction Kinetics & Catalysis Letters, Vol. 58, Issue 1
DOI: 10.1007/BF02071099

Anion Separation with Metal–Organic Frameworks
journal, April 2007

Custelcean, Radu; Moyer, Bruce A.
European Journal of Inorganic Chemistry, Vol. 2007, Issue 10
DOI: 10.1002/ejic.200700018

Chemistry of Technetium and Rhenium Species during Low-Level Radioactive Waste Vitrification
journal, January 1996

Darab, John G.; Smith, Peter A.
Chemistry of Materials, Vol. 8, Issue 5
DOI: 10.1021/cm950418+

Mineral formation during simulated leaks of Hanford waste tanks
journal, August 2006

Deng, Youjun; Harsh, James B.; Flury, Markus
Applied Geochemistry, Vol. 21, Issue 8
DOI: 10.1016/j.apgeochem.2006.05.002

Competitive Incorporation of Perrhenate and Nitrate into Sodalite
journal, October 2014

Dickson, Johnbull O.; Harsh, James B.; Flury, Markus
Environmental Science & Technology, Vol. 48, Issue 21
DOI: 10.1021/es503156v

Nuclear waste forms for actinides
journal, March 1999

Ewing, R. C.
Proceedings of the National Academy of Sciences, Vol. 96, Issue 7
DOI: 10.1073/pnas.96.7.3432

The Nuclear Fuel Cycle: A Role for Mineralogy and Geochemistry
journal, December 2006

Ewing, R. C.
Elements, Vol. 2, Issue 6
DOI: 10.2113/gselements.2.6.331

Synthesis and crystal structure of carbonate cancrinite Na8[AlSiO4]6CO3(H2O)3.4, grown under low-temperature hydrothermal conditions
journal, September 1999

Hackbarth, K.; Gesing, Th. M.; Fechtelkord, M.
Microporous and Mesoporous Materials, Vol. 30, Issue 2-3
DOI: 10.1016/S1387-1811(99)00046-3

The biogeochemistry of technetium: A review of the behavior of an artificial element in the natural environment
journal, October 2010

Icenhower, J. P.; Qafoku, N. P.; Zachara, J. M.
American Journal of Science, Vol. 310, Issue 8
DOI: 10.2475/08.2010.02

X-ray-absorption fine-structure standards: A comparison of experiment and theory
journal, September 1995

Li, G. G.; Bridges, F.; Booth, C. H.
Physical Review B, Vol. 52, Issue 9
DOI: 10.1103/PhysRevB.52.6332

Synthesis of nitrate sodalite: An in situ scanning calorimetric study
journal, April 2007

Liu, Qingyuan; Navrotsky, Alexandra
Geochimica et Cosmochimica Acta, Vol. 71, Issue 8
DOI: 10.1016/j.gca.2007.01.011

Evolution of Technetium Speciation in Reducing Grout
journal, October 2005

Lukens, Wayne W.; Bucher, Jerome J.; Shuh, David K.
Environmental Science & Technology, Vol. 39, Issue 20
DOI: 10.1021/es050155c

Dissimilar Behavior of Technetium and Rhenium in Borosilicate Waste Glass as Determined by X-ray Absorption Spectroscopy
journal, February 2007

Lukens, Wayne W.; McKeown, David A.; Buechele, Andrew C.
Chemistry of Materials, Vol. 19, Issue 3
DOI: 10.1021/cm0622001

The durability of iodide sodalite
journal, June 2014

Maddrell, Ewan; Gandy, Amy; Stennett, Martin
Journal of Nuclear Materials, Vol. 449, Issue 1-3
DOI: 10.1016/j.jnucmat.2014.03.016

Ionic radii in aqueous solutions
journal, December 1988

Marcus, Yizhak
Chemical Reviews, Vol. 88, Issue 8
DOI: 10.1021/cr00090a003

Thermodynamics of solvation of ions. Part 5.—Gibbs free energy of hydration at 298.15 K
journal, January 1991

Marcus, Yizhak
J. Chem. Soc., Faraday Trans., Vol. 87, Issue 18
DOI: 10.1039/FT9918702995

Synthesis and structure of perrhenate sodalite
journal, April 2006

Mattigod, Shas V.; Peter McGrail, B.; McCready, David E.
Microporous and Mesoporous Materials, Vol. 91, Issue 1-3
DOI: 10.1016/j.micromeso.2005.11.025

Experimental determination of the speciation, partitioning, and release of perrhenate as a chemical surrogate for pertechnetate from a sodalite-bearing multiphase ceramic waste form
journal, March 2014

Pierce, E. M.; Lukens, W. W.; Fitts, J. P.
Applied Geochemistry, Vol. 42
DOI: 10.1016/j.apgeochem.2013.12.017

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

Ravel, B.; Newville, M.
Journal of Synchrotron Radiation, Vol. 12, Issue 4
DOI: 10.1107/S0909049505012719

Class B sodalites: nonstoichiometric silver, sodium halosodalites
journal, October 1992

Stein, Andreas; Ozin, Geoffrey A.; Stucky, Galen D.
Journal of the American Chemical Society, Vol. 114, Issue 21
DOI: 10.1021/ja00047a021

A computer model for the cubic sodalite structure
journal, January 1978

Taylor, D.; Henderson, C. M. B.
Physics And Chemistry Of Minerals, Vol. 2, Issue 4
DOI: 10.1007/BF00307575

EXPGUI , a graphical user interface for GSAS
journal, April 2001

Toby, Brian H.
Journal of Applied Crystallography, Vol. 34, Issue 2
DOI: 10.1107/S0021889801002242

Mixed Halide Sodalite Solid Solution Systems. Hydrothermal Synthesis and Structural Characterization by Solid State NMR
journal, August 2003

Trill, Henning; Eckert, Hellmut; Srdanov, Vojislav I.
The Journal of Physical Chemistry B, Vol. 107, Issue 34
DOI: 10.1021/jp0224618

Perrhenate Uptake by Iron and Aluminum Oxyhydroxides: An Analogue for Pertechnetate Incorporation in Hanford Waste Tank Sludges
journal, March 2004

Wakoff, Bradley; Nagy, Kathryn L.
Environmental Science & Technology, Vol. 38, Issue 6
DOI: 10.1021/es0348795

Intracage reactions in sodalites
journal, January 1990

Weller, Mark T.; Wong, Gordon; Adamson, Cathy L.
Journal of the Chemical Society, Dalton Transactions, Issue 2
DOI: 10.1039/dt9900000593

Works referencing / citing this record:

Synthesis and characterization of iodosodalite
journal, March 2017

Chong, Saehwa; Peterson, Jacob; Nam, Junghune
Journal of the American Ceramic Society, Vol. 100, Issue 5
DOI: 10.1111/jace.14772

Perrhenate sodalite growth from alkali silicate melts by noble metal catalysis
journal, March 2019

Anenburg, Michael; Le Losq, Charles
SN Applied Sciences, Vol. 1, Issue 4
DOI: 10.1007/s42452-019-0414-7

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Immobilization and exchange of perrhenate in sodalite and cancrinite

Journal Article Dickson, Johnbull O. ; Harsh, James B. ; Flury, Markus ; ... - Microporous and Mesoporous Materials

Highly alkaline nuclear tank wastes containing key anionic contaminants have leaked into the subsurface at the U.S. Department of Energy's Hanford Site. Laboratory studies showed that when simulated caustic tank wastes contact subsurface sediments, mineral dissolution and precipitation result in feldspathoid formation. Feldspathoids are environmentally important for waste management and disposal purposes because of their purported potential to sequester contaminants of interest (e.g., ⁹⁹TcO₄^-, ¹³⁷Cs⁺, ⁹⁰Sr²⁺) into their structure. In this paper, we investigated the incorporation of perrhenate (ReO₄^-), a surrogate for TcO₄^-, in the presence of competing anions (X) including OH^-, NO₂^-, NO₃^- and Cl^- on feldspathoid formation andmore »« less
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Treatment and immobilization of technetium-99 (⁹⁹Tc) contained in reprocessed nuclear waste and present in contaminated subsurface systems represents a major environmental challenge. One potential approach to managing this highly mobile and long-lived radionuclide is immobilization into micro- and meso-porous crystalline solids, specifically sodalite. We synthesized and characterized the structure of perrhenate sodalite, Na₈[AlSiO₄]₆(ReO₄)₂, and the structure of a mixed guest perrhenate/pertechnetate sodalite, Na₈[AlSiO₄]₆(ReO₄)_2-x(TcO₄)_x. Perrhenate was used as a chemical analogue for pertechnetate. Bulk analyses of each solid confirm a cubic sodalite-type structure (Pmore »« less
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Nuclear waste storage tanks at the Hanford site in southeastern Washington have released highly alkaline solutions, containing radioactive and other contaminants, into subsurface sediments. When this waste reacts with subsurface sediments, feldspathoid minerals (sodalite, cancrinite) can form, sequestering pertechnetate (⁹⁹TcO₄^–) and other ions. This study investigates the potential for incorporation of perrhenate (ReO₄^–), a chemical surrogate for ⁹⁹TcO₄^–, into mixed perrhenate/nitrate (ReO₄^–/NO₃^–) sodalite. Mixed-anion sodalites were hydrothermally synthesized in the laboratory from zeolite A in sodium hydroxide, nitrate, and perrhenate solutions at 90 °C for 24 h. The resulting solids were characterized by bulk chemical analysis, X-ray diffraction, scanning electronmore »« less
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DOI: 10.25505/fiz.icsd.cc1y3tpk
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CSD 1791140: Experimental Crystal Structure Determination
dataset, January 2015

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CSD 1791138: Experimental Crystal Structure Determination
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Title: Perrhenate incorporation into binary mixed sodalites: The role of anion size and implications for technetium-99 sequestration

Citation Formats

Hydration and Extraction of Oxyanions journal, January 2002

Synthesis and structures of M8[ALSiO4]6·(XO4)2, M = Na, Li, K; X = Cl, Mn Sodalites journal, November 1994

29Si MAS NMR investigations on the crystallization of nitrite-sodalite journal, May 1996

Anion Separation with Metal–Organic Frameworks journal, April 2007

Chemistry of Technetium and Rhenium Species during Low-Level Radioactive Waste Vitrification journal, January 1996

Mineral formation during simulated leaks of Hanford waste tanks journal, August 2006

Competitive Incorporation of Perrhenate and Nitrate into Sodalite journal, October 2014

Nuclear waste forms for actinides journal, March 1999

The Nuclear Fuel Cycle: A Role for Mineralogy and Geochemistry journal, December 2006

Synthesis and crystal structure of carbonate cancrinite Na8[AlSiO4]6CO3(H2O)3.4, grown under low-temperature hydrothermal conditions journal, September 1999

The biogeochemistry of technetium: A review of the behavior of an artificial element in the natural environment journal, October 2010

X-ray-absorption fine-structure standards: A comparison of experiment and theory journal, September 1995

Synthesis of nitrate sodalite: An in situ scanning calorimetric study journal, April 2007

Evolution of Technetium Speciation in Reducing Grout journal, October 2005

Dissimilar Behavior of Technetium and Rhenium in Borosilicate Waste Glass as Determined by X-ray Absorption Spectroscopy journal, February 2007

The durability of iodide sodalite journal, June 2014

Ionic radii in aqueous solutions journal, December 1988

Thermodynamics of solvation of ions. Part 5.—Gibbs free energy of hydration at 298.15 K journal, January 1991

Synthesis and structure of perrhenate sodalite journal, April 2006

Experimental determination of the speciation, partitioning, and release of perrhenate as a chemical surrogate for pertechnetate from a sodalite-bearing multiphase ceramic waste form journal, March 2014

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal, June 2005

Class B sodalites: nonstoichiometric silver, sodium halosodalites journal, October 1992

A computer model for the cubic sodalite structure journal, January 1978

EXPGUI , a graphical user interface for GSAS journal, April 2001

Mixed Halide Sodalite Solid Solution Systems. Hydrothermal Synthesis and Structural Characterization by Solid State NMR journal, August 2003

Perrhenate Uptake by Iron and Aluminum Oxyhydroxides: An Analogue for Pertechnetate Incorporation in Hanford Waste Tank Sludges journal, March 2004

Intracage reactions in sodalites journal, January 1990

Synthesis and characterization of iodosodalite journal, March 2017

Perrhenate sodalite growth from alkali silicate melts by noble metal catalysis journal, March 2019

Hydration and Extraction of Oxyanions
journal, January 2002

Synthesis and structures of M8[ALSiO4]6·(XO4)2, M = Na, Li, K; X = Cl, Mn Sodalites
journal, November 1994

29Si MAS NMR investigations on the crystallization of nitrite-sodalite
journal, May 1996

Anion Separation with Metal–Organic Frameworks
journal, April 2007

Chemistry of Technetium and Rhenium Species during Low-Level Radioactive Waste Vitrification
journal, January 1996

Mineral formation during simulated leaks of Hanford waste tanks
journal, August 2006

Competitive Incorporation of Perrhenate and Nitrate into Sodalite
journal, October 2014

Nuclear waste forms for actinides
journal, March 1999

The Nuclear Fuel Cycle: A Role for Mineralogy and Geochemistry
journal, December 2006

Synthesis and crystal structure of carbonate cancrinite Na8[AlSiO4]6CO3(H2O)3.4, grown under low-temperature hydrothermal conditions
journal, September 1999

The biogeochemistry of technetium: A review of the behavior of an artificial element in the natural environment
journal, October 2010

X-ray-absorption fine-structure standards: A comparison of experiment and theory
journal, September 1995

Synthesis of nitrate sodalite: An in situ scanning calorimetric study
journal, April 2007

Evolution of Technetium Speciation in Reducing Grout
journal, October 2005

Dissimilar Behavior of Technetium and Rhenium in Borosilicate Waste Glass as Determined by X-ray Absorption Spectroscopy
journal, February 2007

The durability of iodide sodalite
journal, June 2014

Ionic radii in aqueous solutions
journal, December 1988

Thermodynamics of solvation of ions. Part 5.—Gibbs free energy of hydration at 298.15 K
journal, January 1991

Synthesis and structure of perrhenate sodalite
journal, April 2006

Experimental determination of the speciation, partitioning, and release of perrhenate as a chemical surrogate for pertechnetate from a sodalite-bearing multiphase ceramic waste form
journal, March 2014

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

Class B sodalites: nonstoichiometric silver, sodium halosodalites
journal, October 1992

A computer model for the cubic sodalite structure
journal, January 1978

EXPGUI , a graphical user interface for GSAS
journal, April 2001

Mixed Halide Sodalite Solid Solution Systems. Hydrothermal Synthesis and Structural Characterization by Solid State NMR
journal, August 2003

Perrhenate Uptake by Iron and Aluminum Oxyhydroxides: An Analogue for Pertechnetate Incorporation in Hanford Waste Tank Sludges
journal, March 2004

Intracage reactions in sodalites
journal, January 1990

Synthesis and characterization of iodosodalite
journal, March 2017

Perrhenate sodalite growth from alkali silicate melts by noble metal catalysis
journal, March 2019