A novel small-molecule compound of lithium iodine and 3-hydroxypropionitride as a solid-state electrolyte for lithium–air batteries
Abstract
A novel small-molecule compound of lithium iodine and 3-hydroxypropionitrile (HPN) has been successfully synthesized. Our combined experimental and theoretical studies indicated that LiIHPN is a Li-ion conductor, which is utterly different from the I–-anion conductor of LiI(HPN)2 reported previously. Solid-state lithium–air batteries based on LiIHPN as the electrolyte exhibit a reversible discharge capacity of more than 2100 mAh g–1 with a cyclic performance over 10 cycles. Lastly, our findings provide a new way to design solid-state electrolytes toward high-performance lithium–air batteries.
- Authors:
-
- Fudan Univ., Shanghai (People's Republic of China)
- Shanghai Univ., Shanghai (People's Republic of China)
- Fudan Univ., Shanghai (China)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1326753
- Report Number(s):
- BNL-112647-2016-JA
Journal ID: ISSN 0020-1669; R&D Project: MA453MAEA; VT1201000
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganic Chemistry
- Additional Journal Information:
- Journal Volume: 55; Journal Issue: 13; Journal ID: ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; solid-state electrolyte; small molecule; lithium-air battery
Citation Formats
Liu, Fang -Chao, Shadike, Zulipiya, Wang, Xiao -Fang, Shi, Si -Qi, Zhou, Yong -Ning, Chen, Guo -Ying, Yang, Xiao -Qing, Weng, Lin -Hong, Zhao, Jing -Tai, and Fu, Zheng -Wen. A novel small-molecule compound of lithium iodine and 3-hydroxypropionitride as a solid-state electrolyte for lithium–air batteries. United States: N. p., 2016.
Web. doi:10.1021/acs.inorgchem.6b00564.
Liu, Fang -Chao, Shadike, Zulipiya, Wang, Xiao -Fang, Shi, Si -Qi, Zhou, Yong -Ning, Chen, Guo -Ying, Yang, Xiao -Qing, Weng, Lin -Hong, Zhao, Jing -Tai, & Fu, Zheng -Wen. A novel small-molecule compound of lithium iodine and 3-hydroxypropionitride as a solid-state electrolyte for lithium–air batteries. United States. https://doi.org/10.1021/acs.inorgchem.6b00564
Liu, Fang -Chao, Shadike, Zulipiya, Wang, Xiao -Fang, Shi, Si -Qi, Zhou, Yong -Ning, Chen, Guo -Ying, Yang, Xiao -Qing, Weng, Lin -Hong, Zhao, Jing -Tai, and Fu, Zheng -Wen. Thu .
"A novel small-molecule compound of lithium iodine and 3-hydroxypropionitride as a solid-state electrolyte for lithium–air batteries". United States. https://doi.org/10.1021/acs.inorgchem.6b00564. https://www.osti.gov/servlets/purl/1326753.
@article{osti_1326753,
title = {A novel small-molecule compound of lithium iodine and 3-hydroxypropionitride as a solid-state electrolyte for lithium–air batteries},
author = {Liu, Fang -Chao and Shadike, Zulipiya and Wang, Xiao -Fang and Shi, Si -Qi and Zhou, Yong -Ning and Chen, Guo -Ying and Yang, Xiao -Qing and Weng, Lin -Hong and Zhao, Jing -Tai and Fu, Zheng -Wen},
abstractNote = {A novel small-molecule compound of lithium iodine and 3-hydroxypropionitrile (HPN) has been successfully synthesized. Our combined experimental and theoretical studies indicated that LiIHPN is a Li-ion conductor, which is utterly different from the I–-anion conductor of LiI(HPN)2 reported previously. Solid-state lithium–air batteries based on LiIHPN as the electrolyte exhibit a reversible discharge capacity of more than 2100 mAh g–1 with a cyclic performance over 10 cycles. Lastly, our findings provide a new way to design solid-state electrolytes toward high-performance lithium–air batteries.},
doi = {10.1021/acs.inorgchem.6b00564},
journal = {Inorganic Chemistry},
number = 13,
volume = 55,
place = {United States},
year = {2016},
month = {6}
}
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