DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: TMPZnN(SiMe3)2, [TMPZn(μ-O Pr)]2 and TMPZn[OCMe2C(O)OEt]. Their role in the ring-opening of rac-lactide and ε-caprolactone where TMP = 1,5,9-trimesityldipyrromethene

Authors:
ORCiD logo; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1326412
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Organometallic Chemistry
Additional Journal Information:
Journal Name: Journal of Organometallic Chemistry Journal Volume: 812 Journal Issue: C; Journal ID: ISSN 0022-328X
Publisher:
Elsevier
Country of Publication:
Netherlands
Language:
English

Citation Formats

Balasanthiran, Vagulejan, Chisholm, Malcolm H., Choojun, Kittisak, Durr, Christopher B., and Wambua, Pasco M. TMPZnN(SiMe3)2, [TMPZn(μ-O Pr)]2 and TMPZn[OCMe2C(O)OEt]. Their role in the ring-opening of rac-lactide and ε-caprolactone where TMP = 1,5,9-trimesityldipyrromethene. Netherlands: N. p., 2016. Web. doi:10.1016/j.jorganchem.2016.01.001.
Balasanthiran, Vagulejan, Chisholm, Malcolm H., Choojun, Kittisak, Durr, Christopher B., & Wambua, Pasco M. TMPZnN(SiMe3)2, [TMPZn(μ-O Pr)]2 and TMPZn[OCMe2C(O)OEt]. Their role in the ring-opening of rac-lactide and ε-caprolactone where TMP = 1,5,9-trimesityldipyrromethene. Netherlands. https://doi.org/10.1016/j.jorganchem.2016.01.001
Balasanthiran, Vagulejan, Chisholm, Malcolm H., Choojun, Kittisak, Durr, Christopher B., and Wambua, Pasco M. Wed . "TMPZnN(SiMe3)2, [TMPZn(μ-O Pr)]2 and TMPZn[OCMe2C(O)OEt]. Their role in the ring-opening of rac-lactide and ε-caprolactone where TMP = 1,5,9-trimesityldipyrromethene". Netherlands. https://doi.org/10.1016/j.jorganchem.2016.01.001.
@article{osti_1326412,
title = {TMPZnN(SiMe3)2, [TMPZn(μ-O Pr)]2 and TMPZn[OCMe2C(O)OEt]. Their role in the ring-opening of rac-lactide and ε-caprolactone where TMP = 1,5,9-trimesityldipyrromethene},
author = {Balasanthiran, Vagulejan and Chisholm, Malcolm H. and Choojun, Kittisak and Durr, Christopher B. and Wambua, Pasco M.},
abstractNote = {},
doi = {10.1016/j.jorganchem.2016.01.001},
journal = {Journal of Organometallic Chemistry},
number = C,
volume = 812,
place = {Netherlands},
year = {Wed Jun 01 00:00:00 EDT 2016},
month = {Wed Jun 01 00:00:00 EDT 2016}
}

Journal Article:
Free Publicly Available Full Text

Citation Metrics:
Cited by: 7 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Structure and reactivity of mono- and dinuclear diiminate zinc alkyl complexes
journal, October 2003


Carbonhydrogen-transition metal bonds
journal, July 1983


BDI∗MgX(L) where X = Bu and O Bu and L = THF, py and DMAP. The rates of kinetic exchange of L where BDI∗= CH{C( Bu)N-2,6- Pr2C6H3}2
journal, January 2016


Evolution of lowest singlet and triplet excited states with number of thienyl rings in platinum poly-ynes
journal, March 1999

  • Chawdhury, N.; Köhler, A.; Friend, R. H.
  • The Journal of Chemical Physics, Vol. 110, Issue 10
  • DOI: 10.1063/1.478382

Structure validation in chemical crystallography
journal, January 2009

  • Spek, Anthony L.
  • Acta Crystallographica Section D Biological Crystallography, Vol. 65, Issue 2, p. 148-155
  • DOI: 10.1107/S090744490804362X

Synthesis and Photovoltaic Properties of New Metalloporphyrin-Containing Polyplatinyne Polymers
journal, July 2011

  • Zhan, Hongmei; Lamare, Simon; Ng, Annie
  • Macromolecules, Vol. 44, Issue 13
  • DOI: 10.1021/ma2006206

Mercury alkynyls as versatile templates for new organometallic materials and polymers
journal, September 2007


WinGX suite for small-molecule single-crystal crystallography
journal, August 1999


A short history of SHELX
journal, December 2007

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
  • DOI: 10.1107/S0108767307043930

Catalytic Activity of a Series of Zn(II) Phenoxides for the Copolymerization of Epoxides and Carbon Dioxide
journal, January 1999

  • Darensbourg, Donald J.; Holtcamp, Matthew W.; Struck, Ginette E.
  • Journal of the American Chemical Society, Vol. 121, Issue 1
  • DOI: 10.1021/ja9826284

Metal-Size Influence in Iso-Selective Lactide Polymerization
journal, July 2014

  • Bakewell, Clare; White, Andrew J. P.; Long, Nicholas J.
  • Angewandte Chemie International Edition, Vol. 53, Issue 35
  • DOI: 10.1002/anie.201403643

Organometallic acetylides of PtII, AuI and HgII as new generation optical power limiting materials
journal, January 2011

  • Zhou, Gui-Jiang; Wong, Wai-Yeung
  • Chemical Society Reviews, Vol. 40, Issue 5
  • DOI: 10.1039/c0cs00094a

Spatial extent of the singlet and triplet excitons in transition metal‐containing poly‐ynes
journal, September 1996

  • Beljonne, D.; Wittmann, H. F.; Köhler, A.
  • The Journal of Chemical Physics, Vol. 105, Issue 9
  • DOI: 10.1063/1.472207

Organometallic Photovoltaics: A New and Versatile Approach for Harvesting Solar Energy Using Conjugated Polymetallaynes
journal, September 2010

  • Wong, Wai-Yeung; Ho, Cheuk-Lam
  • Accounts of Chemical Research, Vol. 43, Issue 9
  • DOI: 10.1021/ar1000378

Synthesis and characterisation of new acetylide-functionalised oligothiophenes and their dinuclear platinum complexes
journal, January 1997

  • Lewis, Jack; Long, Nicholas J.; Raithby, Paul R.
  • Journal of the Chemical Society, Dalton Transactions, Issue 22
  • DOI: 10.1039/a704708h

Charge and energy transfers in functional metallophosphors and metallopolyynes
journal, May 2013


Single-site bismuth alkoxide catalysts for the ring-opening polymerization of lactide
journal, January 2013

  • Balasanthiran, Vagulejan; Chisholm, Malcolm H.; Durr, Christopher B.
  • Dalton Transactions, Vol. 42, Issue 31
  • DOI: 10.1039/c3dt50629k

Monomeric metal alkoxides and trialkyl siloxides: (BDI)Mg(OtBu)(THF ) and (BDI)Zn(OSiPh3)(THF ). Comments on single site catalysts for ring-opening polymerization of lactides †
journal, January 2001

  • Chisholm, Malcolm H.; Huffman, John C.; Phomphrai, Khamphee
  • Journal of the Chemical Society, Dalton Transactions, Issue 3
  • DOI: 10.1039/b008158m

Effect of Oligothienyl Chain Length on Tuning the Solar Cell Performance in Fluorene-Based Polyplatinynes
journal, September 2008

  • Liu, Li; Ho, Cheuk-Lam; Wong, Wai-Yeung
  • Advanced Functional Materials, Vol. 18, Issue 18
  • DOI: 10.1002/adfm.200800439

Phosphasalen Yttrium Complexes: Highly Active and Stereoselective Initiators for Lactide Polymerization
journal, January 2012

  • Cao, Thi-Phuong-Anh; Buchard, Antoine; Le Goff, Xavier F.
  • Inorganic Chemistry, Vol. 51, Issue 4
  • DOI: 10.1021/ic202015z

Synthesis, Redox and Optical Properties of Low-Bandgap Platinum(II) Polyynes with 9-Dicyanomethylene-Substituted Fluorene Acceptors
journal, March 2001


Stereocontrolled ring-opening polymerisation of lactide
journal, January 2010

  • Stanford, Matthew J.; Dove, Andrew P.
  • Chem. Soc. Rev., Vol. 39, Issue 2
  • DOI: 10.1039/B815104K

Metallated conjugated polymers as a new avenue towards high-efficiency polymer solar cells
journal, May 2007

  • Wong, Wai-Yeung; Wang, Xing-Zhu; He, Ze
  • Nature Materials, Vol. 6, Issue 7
  • DOI: 10.1038/nmat1909

In memory of Lord Jack Lewis
journal, January 2015

  • Johnson, Brian F. G.; Griffith, William. P.; Clark, Robin J. H.
  • Dalton Transactions, Vol. 44, Issue 9
  • DOI: 10.1039/C4DT90196G

Synthesis of cyclic polyesters: effects of alkoxy side chains in salicylaldiminato tin( ii ) complexes
journal, January 2015

  • Wongmahasirikun, Phonpimon; Prom-on, Paweenuch; Sangtrirutnugul, Preeyanuch
  • Dalton Transactions, Vol. 44, Issue 27
  • DOI: 10.1039/C5DT00139K

Ethyl 2-hydroxy-2-methylpropanoate derivatives of magnesium and zinc. The effect of chelation on the homo- and copolymerization of lactide and ε-caprolactone
journal, January 2014

  • Balasanthiran, Vagulejan; Chisholm, Malcolm H.; Choojun, Kittisak
  • Dalton Trans., Vol. 43, Issue 7
  • DOI: 10.1039/C3DT52553H

Controlled Polymerization of dl -Lactide and ε-Caprolactone by Structurally Well-Defined Alkoxo-Bridged Di- and Triyttrium(III) Complexes
journal, May 2000

  • Chamberlain, Bradley M.; Jazdzewski, Brian A.; Pink, Maren
  • Macromolecules, Vol. 33, Issue 11
  • DOI: 10.1021/ma0000834

Synthesis of new bis(acetylide)-substituted fluorene derivatives and their bimetallic and polymeric complexes
journal, April 1998


Synthesis, characterisation and properties of platinum(II) acetylide complexes of ferrocenylfluorene: novel soluble donor–acceptor heterometallic materials ‡
journal, January 1998

  • Wong, Wai-Yeung; Wong, Wai-Kwok; Raithby, Paul R.
  • Journal of the Chemical Society, Dalton Transactions, Issue 16
  • DOI: 10.1039/a803168a

Well-Defined Calcium Initiators for Lactide Polymerization
journal, October 2004

  • Chisholm, Malcolm H.; Gallucci, Judith C.; Phomphrai, Khamphee
  • Inorganic Chemistry, Vol. 43, Issue 21
  • DOI: 10.1021/ic0490730

Biocompatible Initiators for Lactide Polymerization
journal, January 2008


Polymerization of Lactide with Zinc and Magnesium β-Diiminate Complexes:  Stereocontrol and Mechanism
journal, April 2001

  • Chamberlain, Bradley M.; Cheng, Ming; Moore, David R.
  • Journal of the American Chemical Society, Vol. 123, Issue 14
  • DOI: 10.1021/ja003851f

Metallopolyyne Polymers as New Functional Materials for Photovoltaic and Solar Cell Applications
journal, January 2008