Influence of thermal treatment time on structural and physical properties of polyimide films at beginning of carbonization
Abstract
Poly(4,4'-oxydiphenylene-oxydiphthalimide) (POO) was thermally treated at 773 K for 1, 15 and 60 min under argon atmosphere resulting in free-standing films with intermingled characteristics between polymer and carbon-rich derivatives. Degradative thermal analysis performed by pyrolysis-gas chromatography/mass spectroscopy (Py-GC/MS) revealed CO2 among the major products of thermal decomposition which according to electron paramagnetic resonance (EPR) passed through a radical process. X-ray diffraction (XRD) revealed thermal treated samples with semicrystalline organization that was attributed to the development of lamellae structure. Moreover, Atomic force microscopy (AFM) showed an increase in the roughness of the samples that acquired pronounced roughcast-like surface. Hence, there was an enhancement of mechanical strength and dielectric permittivity. From the data collected a mechanism of thermal decomposition was proposed.
- Authors:
-
[1];
- Univ. de São Paulo (Brazil). Inst. de Química de São Carlos
- Univ. de Campinas, SP (Brazil). Inst. de Química
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Univ. de São Paulo (Brazil). Inst. de Fisica de São Carlos; Centro Universitário Central Paulista (UNICEP), São Carlos, SP (Brazil)
- Univ. de São Paulo (Brazil). Inst. de Fisica de São Carlos
- Univ. Federal do Paraná, PR (Brazil)
- Publication Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA); FAPESP; CNPq
- OSTI Identifier:
- 1873623
- Alternate Identifier(s):
- OSTI ID: 1326407; OSTI ID: 1836941
- Report Number(s):
- LLNL-JRNL-830094; LLNL-JRNL-791106
Journal ID: ISSN 0141-3910; 888393
- Grant/Contract Number:
- AC52-07NA27344; 2013/24948-3; 2016/10939-0; 302185/2017-8
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Polymer Degradation and Stability
- Additional Journal Information:
- Journal Volume: 129; Journal Issue: N/A; Journal ID: ISSN 0141-3910
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; Polyimide; Carbon-rich derivatives; Thermal degradation; Structural rearrangement
Citation Formats
Ferreira, Fábio A.S., Battirola, Liliane C., Lewicki, James P., Worsley, Marcus A., Pereira-da-Silva, Marcelo A., Amaral, Thiago, Lepienski, Carlos M., and Rodrigues-Filho, Ubirajara P. Influence of thermal treatment time on structural and physical properties of polyimide films at beginning of carbonization. United States: N. p., 2016.
Web. doi:10.1016/j.polymdegradstab.2016.05.001.
Ferreira, Fábio A.S., Battirola, Liliane C., Lewicki, James P., Worsley, Marcus A., Pereira-da-Silva, Marcelo A., Amaral, Thiago, Lepienski, Carlos M., & Rodrigues-Filho, Ubirajara P. Influence of thermal treatment time on structural and physical properties of polyimide films at beginning of carbonization. United States. https://doi.org/10.1016/j.polymdegradstab.2016.05.001
Ferreira, Fábio A.S., Battirola, Liliane C., Lewicki, James P., Worsley, Marcus A., Pereira-da-Silva, Marcelo A., Amaral, Thiago, Lepienski, Carlos M., and Rodrigues-Filho, Ubirajara P. Tue .
"Influence of thermal treatment time on structural and physical properties of polyimide films at beginning of carbonization". United States. https://doi.org/10.1016/j.polymdegradstab.2016.05.001. https://www.osti.gov/servlets/purl/1873623.
@article{osti_1873623,
title = {Influence of thermal treatment time on structural and physical properties of polyimide films at beginning of carbonization},
author = {Ferreira, Fábio A.S. and Battirola, Liliane C. and Lewicki, James P. and Worsley, Marcus A. and Pereira-da-Silva, Marcelo A. and Amaral, Thiago and Lepienski, Carlos M. and Rodrigues-Filho, Ubirajara P.},
abstractNote = {Poly(4,4'-oxydiphenylene-oxydiphthalimide) (POO) was thermally treated at 773 K for 1, 15 and 60 min under argon atmosphere resulting in free-standing films with intermingled characteristics between polymer and carbon-rich derivatives. Degradative thermal analysis performed by pyrolysis-gas chromatography/mass spectroscopy (Py-GC/MS) revealed CO2 among the major products of thermal decomposition which according to electron paramagnetic resonance (EPR) passed through a radical process. X-ray diffraction (XRD) revealed thermal treated samples with semicrystalline organization that was attributed to the development of lamellae structure. Moreover, Atomic force microscopy (AFM) showed an increase in the roughness of the samples that acquired pronounced roughcast-like surface. Hence, there was an enhancement of mechanical strength and dielectric permittivity. From the data collected a mechanism of thermal decomposition was proposed.},
doi = {10.1016/j.polymdegradstab.2016.05.001},
journal = {Polymer Degradation and Stability},
number = N/A,
volume = 129,
place = {United States},
year = {Tue May 31 00:00:00 EDT 2016},
month = {Tue May 31 00:00:00 EDT 2016}
}
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