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Title: Bifunctional Catalysts for Upgrading of Biomass-Derived Oxygenates: A Review

Abstract

Deoxygenation is an important reaction in the conversion of biomass-derived oxygenates to fuels and chemicals. A key route for biomass refining involves the production of pyrolysis oil through rapid heating of the raw biomass feedstock. Pyrolysis oil as produced is highly oxygenated, so the feasibility of this approach depends in large part on the ability to selectively deoxygenate pyrolysis oil components to create a stream of high-value finished products. Identification of catalytic materials that are active and selective for deoxygenation of pyrolysis oil components has therefore represented a major research area. One catalyst is rarely capable of performing the different types of elementary reaction steps required to deoxygenate biomass-derived compounds. For this reason, considerable attention has been placed on bifunctional catalysts, where two different active materials are used to provide catalytic sites for diverse reaction steps. Here, we review recent trends in the development of catalysts, with a focus on catalysts for which a bifunctional effect has been proposed. We summarize recent studies of hydrodeoxygenation (HDO) of pyrolysis oil and model compounds for a range of materials, including supported metal and bimetallic catalysts as well as transition-metal oxides, sulfides, carbides, nitrides, and phosphides. Particular emphasis is placed on how catalystmore » structure can be related to performance via molecular-level mechanisms. Finally, these studies demonstrate the importance of catalyst bifunctionality, with each class of materials requiring hydrogenation and C-O scission sites to perform HDO at reasonable rates.« less

Authors:
 [1];  [2];  [1]
  1. Department of Chemical and Biological Engineering, University of Colorado—Boulder, UCB 596, Boulder, Colorado 80309, United States
  2. National Bioenergy Center, National Renewable Energy Laboratory, 15013 Denver West Pikeway, Golden, Colorado 80401, United States
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Bioenergy Technologies Office
OSTI Identifier:
1326118
Alternate Identifier(s):
OSTI ID: 1313615
Report Number(s):
NREL/JA-5100-67033
Journal ID: ISSN 2155-5435
Grant/Contract Number:  
AC36-08-GO28308; AC36-08GO28308
Resource Type:
Published Article
Journal Name:
ACS Catalysis
Additional Journal Information:
Journal Name: ACS Catalysis Journal Volume: 6 Journal Issue: 8; Journal ID: ISSN 2155-5435
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
09 BIOMASS FUELS; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; bifunctional; bimetallic; catalyst; hydrodeoxygenation; metal-metal oxide; tethered bifunctional catalysts

Citation Formats

Robinson, Allison M., Hensley, Jesse E., and Medlin, J. Will. Bifunctional Catalysts for Upgrading of Biomass-Derived Oxygenates: A Review. United States: N. p., 2016. Web. doi:10.1021/acscatal.6b00923.
Robinson, Allison M., Hensley, Jesse E., & Medlin, J. Will. Bifunctional Catalysts for Upgrading of Biomass-Derived Oxygenates: A Review. United States. https://doi.org/10.1021/acscatal.6b00923
Robinson, Allison M., Hensley, Jesse E., and Medlin, J. Will. Wed . "Bifunctional Catalysts for Upgrading of Biomass-Derived Oxygenates: A Review". United States. https://doi.org/10.1021/acscatal.6b00923.
@article{osti_1326118,
title = {Bifunctional Catalysts for Upgrading of Biomass-Derived Oxygenates: A Review},
author = {Robinson, Allison M. and Hensley, Jesse E. and Medlin, J. Will},
abstractNote = {Deoxygenation is an important reaction in the conversion of biomass-derived oxygenates to fuels and chemicals. A key route for biomass refining involves the production of pyrolysis oil through rapid heating of the raw biomass feedstock. Pyrolysis oil as produced is highly oxygenated, so the feasibility of this approach depends in large part on the ability to selectively deoxygenate pyrolysis oil components to create a stream of high-value finished products. Identification of catalytic materials that are active and selective for deoxygenation of pyrolysis oil components has therefore represented a major research area. One catalyst is rarely capable of performing the different types of elementary reaction steps required to deoxygenate biomass-derived compounds. For this reason, considerable attention has been placed on bifunctional catalysts, where two different active materials are used to provide catalytic sites for diverse reaction steps. Here, we review recent trends in the development of catalysts, with a focus on catalysts for which a bifunctional effect has been proposed. We summarize recent studies of hydrodeoxygenation (HDO) of pyrolysis oil and model compounds for a range of materials, including supported metal and bimetallic catalysts as well as transition-metal oxides, sulfides, carbides, nitrides, and phosphides. Particular emphasis is placed on how catalyst structure can be related to performance via molecular-level mechanisms. Finally, these studies demonstrate the importance of catalyst bifunctionality, with each class of materials requiring hydrogenation and C-O scission sites to perform HDO at reasonable rates.},
doi = {10.1021/acscatal.6b00923},
journal = {ACS Catalysis},
number = 8,
volume = 6,
place = {United States},
year = {2016},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acscatal.6b00923

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Cited by: 34 works
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