DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Bifunctional Catalysts for Upgrading of Biomass-Derived Oxygenates: A Review

Journal Article · · ACS Catalysis
 [1];  [2];  [1]
  1. Department of Chemical and Biological Engineering, University of Colorado—Boulder, UCB 596, Boulder, Colorado 80309, United States
  2. National Bioenergy Center, National Renewable Energy Laboratory, 15013 Denver West Pikeway, Golden, Colorado 80401, United States

Not Available

Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Bioenergy Technologies Office (BETO)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1326118
Journal Information:
ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 8 Vol. 6; ISSN 2155-5435
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (186)

Highly Selective Catalytic Conversion of Phenolic Bio-Oil to Alkanes journal May 2009
Multifunctional Heterogeneous Catalysts: SBA-15-Containing Primary Amines and Sulfonic Acids journal September 2006
Low-Temperature ABC-Type Atomic Layer Deposition: Synthesis of Highly Uniform Ultrafine Supported Metal Nanoparticles journal March 2010
Chemoselective Hydrogenolysis of Tetrahydropyran-2-methanol to 1,6-Hexanediol over Rhenium-Modified Carbon-Supported Rhodium Catalysts journal April 2010
X-ray Absorption Spectroscopy of Bimetallic Pt-Re Catalysts for Hydrogenolysis of Glycerol to Propanediols journal July 2010
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis journal June 2010
Hydrodeoxygenation of Guaiacol over Carbon-Supported Metal Catalysts journal July 2013
Carbon Nanofiber Supported Transition-Metal Carbide Catalysts for the Hydrodeoxygenation of Guaiacol journal July 2013
Enhancing Heterogeneous Catalysis through Cooperative Hybrid Organic–Inorganic Interfaces journal May 2006
Size-Specific Chemistry on Bimetallic Surfaces: A Combined Experimental and Theoretical Study journal October 2007
Correlating Benzene Hydrogenation Activity with Binding Energies of Hydrogen and Benzene on Co-Based Bimetallic Catalysts journal August 2009
Hydrogenolysis of 1,2-Propanediol for the Production of Biopropanols from Glycerol journal May 2010
Production of Biobutanediols by the Hydrogenolysis of Erythritol journal August 2012
Selective Hydrodeoxygenation of Biomass-Derived Oxygenates to Unsaturated Hydrocarbons using Molybdenum Carbide Catalysts journal April 2013
Ketonization of Carboxylic Acids by Decarboxylation: Mechanism and Scope journal March 2005
Role of Re Species and Acid Cocatalyst on Ir-ReO x /SiO 2 in the C-O Hydrogenolysis of Biomass-Derived Substrates : Hydrogenolysis of Biomass-Derived Substrates journal August 2014
Isobutanol and Methanol Synthesis on Copper Catalysts Supported on Modified Magnesium Oxide journal October 1997
Mono and Bifunctional Pathways of CO2/CH4Reforming over Pt and Rh Based Catalysts journal May 1998
Reaction Paths in the Hydrogenolysis of Acetic Acid to Ethanol over Pd(111), Re(0001), and PdRe Alloys journal July 2002
Mesoporous catalytic membranes: Synthetic control of pore size and wall composition journal August 2005
Novel, uniform nanostructured catalytic membranes journal October 2006
Hydrogenolysis of Glycerol to Propanediols Over Highly Active Ru–Re Bimetallic Catalysts journal April 2009
Condensation/Hydrogenation of Biomass-Derived Oxygenates in Water/Oil Emulsions Stabilized by Nanohybrid Catalysts journal February 2012
The Synergy of the Support Acid Function and the Metal Function in the Catalytic Hydrodeoxygenation of m-Cresol journal March 2012
Evaluation of Silica-Supported Metal and Metal Phosphide Nanoparticle Catalysts for the Hydrodeoxygenation of Guaiacol Under Ex Situ Catalytic Fast Pyrolysis Conditions journal September 2015
Adsorption of Bases on γ-Al2O3 journal May 1972
Structure and properties of molybdenum sulfide: Correlation of O2 chemisorption with hydrodesulfurization activity*1 journal June 1980
Influence of ensemble size on CO chemisorption and catalytic n-hexane conversion by Au-Pt(111) bimetallic single-crystal surfaces journal May 1983
The interaction of formic acid with transition metal surfaces, studied in ultrahigh vacuum journal May 1994
Reactions of carboxylic acids on the Pd(111)-(2 × 2)O surface: multiple roles of surface oxygen atoms journal October 1991
The adsorption and decomposition of formaldehyde and formic acid on the clean and modified Fe (100) surface journal February 1996
Vinyl substituent effects on the reactions of higher oxygenates on Pd(111) journal November 1992
Kinetic studies of upgrading pine pyrolytic oil by hydrotreatment journal July 1988
Preparation and catalytic properties of transition metal carbides and nitrides journal June 1992
Hydrogenation of phenol over supported platinum and palladium catalysts journal March 1993
Activity and deactivation of Fe-MFI catalysts for benzene hydroxylation to phenol by N2O journal March 2003
Catalyst support effects: gas-phase hydrogenation of phenol over palladium journal October 2003
Effect of nickel on the surface acidity of γ-alumina and alumina-supported nickel—molybdenum hydrotreating catalysts journal May 1989
Hydrogenation active sites of unsupported molybdenum sulfide catalysts for hydroprocessing heavy oils journal February 2001
A survey of the mechanism in catalytic isomerization of alkanes journal June 2003
Deoxygenation of benzoic acid on metal oxides journal October 2001
Catalytic hydrodeoxygenation journal June 2000
Fast pyrolysis processes for biomass journal March 2000
Supported metal cluster catalysts journal December 2000
Oxygenate reaction pathways on transition metal surfaces journal May 1998
Condensation reactions of propanal over CexZr1−xO2 mixed oxide catalysts journal September 2010
Hydrodeoxygenation of guaiacol as model compound for pyrolysis oil on transition metal phosphide hydroprocessing catalysts journal January 2011
A review of catalytic upgrading of bio-oil to engine fuels journal November 2011
Guaiacol transformation over unsupported molybdenum-based nitride catalysts journal January 2012
Solid acid co-catalyst for the hydrogenolysis of glycerol to 1,3-propanediol over Ir-ReOx/SiO2 journal August 2012
Hydrodeoxygenation of guaiacol over carbon-supported molybdenum nitride catalysts: Effects of nitriding methods and support properties journal October 2012
Effects of support identity and metal dispersion in supported ruthenium hydrodeoxygenation catalysts journal May 2014
Activity and stability of low-content gold–cerium oxide catalysts for the water–gas shift reaction journal March 2005
Modification of Rh/SiO2 catalyst for the hydrogenolysis of glycerol in water journal February 2010
Highly dispersed Pt nanoparticle catalyst prepared by atomic layer deposition journal June 2010
Hydrodeoxygenation of 2-ethylphenol as a model compound of bio-crude over sulfided Mo-based catalysts: Promoting effect and reaction mechanism journal August 2010
Hydrodeoxygenation of guaiacol with CoMo catalysts. Part I: Promoting effect of cobalt on HDO selectivity and activity journal January 2011
Reaction mechanism of the glycerol hydrogenolysis to 1,3-propanediol over Ir–ReOx/SiO2 catalyst journal June 2011
Gas-phase hydrodeoxygenation of guaiacol over Fe/SiO2 catalyst journal April 2012
Evaluating strategies for catalytic upgrading of pyrolysis oil in liquid phase journal February 2014
Deoxygenation of methyl laurate as a model compound to hydrocarbons on transition metal phosphide catalysts journal January 2014
Demethoxylation of guaiacol and methoxybenzenes over carbon-supported Ru–Mn catalyst journal March 2016
Review of fast pyrolysis of biomass and product upgrading journal March 2012
A review of catalytic hydrodeoxygenation of lignin-derived phenols from biomass pyrolysis journal November 2012
Catalytic roles of metals and supports on hydrodeoxygenation of lignin monomer guaiacol journal January 2012
Hydrodeoxygenation of p-cresol on unsupported Ni–W–Mo–S catalysts prepared by one step hydrothermal method journal November 2014
An overview of dehydration, aldol-condensation and hydrogenation processes for production of liquid alkanes from biomass-derived carbohydrates journal May 2007
Transition metal phosphide hydroprocessing catalysts: A review journal May 2009
Comparison of H2 production from ethanol and ethylene glycol on M/Pt(111) (M=Ni, Fe, Ti) bimetallic surfaces journal September 2009
Zeolite-Beta-supported platinum catalysts for hydrogenation/hydrodeoxygenation of pyrolysis oil model compounds journal April 2013
Heterogeneous catalysis with metal nitrides journal July 2013
Vapor phase hydrodeoxygenation and hydrogenation of m -cresol on silica supported Ni, Pd and Pt catalysts journal October 2015
Overview of fuel properties of biomass fast pyrolysis oils journal May 2009
Selective cyclohexanol production from the renewable lignin derived phenolic chemicals catalyzed by Ni/MgO journal November 2015
Catalytic upgrading of biomass fast pyrolysis vapors with titania and zirconia/titania based catalysts journal August 2010
Amorphous unsupported Ni–Mo sulfide prepared by one step hydrothermal method for phenol hydrodeoxygenation journal January 2012
Bifunctional nature of a SiO2-supported Ni2P catalyst for hydrotreating: EXAFS and FTIR studies journal April 2006
Gas-phase conversion of glycerol to synthesis gas over carbon-supported platinum and platinum–rhenium catalysts journal April 2007
The effect of acid–base pairing on catalysis: An efficient acid–base functionalized catalyst for aldol condensation journal April 2007
Correlating hydrogenation activity with binding energies of hydrogen and cyclohexene on M/Pt(111) (M = Fe, Co, Ni, Cu) bimetallic surfaces journal July 2008
Low temperature hydrogenation of benzene and cyclohexene: A comparative study between γ-Al2O3 supported PtCo and PtNi bimetallic catalysts journal October 2008
The role of rhenium in the conversion of glycerol to synthesis gas over carbon supported platinum–rhenium catalysts journal November 2008
Catalytic coupling of carboxylic acids by ketonization as a processing step in biomass conversion journal August 2009
Synthesis and characterization of Au–Pd/SiO2 bimetallic catalysts prepared by electroless deposition journal April 2010
Correlating extent of Pt–Ni bond formation with low-temperature hydrogenation of benzene and 1,3-butadiene over supported Pt/Ni bimetallic catalysts journal May 2010
Hydrodeoxygenation pathways catalyzed by MoS2 and NiMoS active phases: A DFT study journal April 2011
Aqueous-phase hydrodeoxygenation of bio-derived phenols to cycloalkanes journal May 2011
Mechanism of the hydrogenolysis of ethers over silica-supported rhodium catalyst modified with rhenium oxide journal June 2011
Deoxygenation mechanisms on Ni-promoted MoS2 bulk catalysts: A combined experimental and theoretical study journal February 2012
Correlation of Pt–Re surface properties with reaction pathways for the aqueous-phase reforming of glycerol journal March 2012
Bio-oil hydrodeoxygenation: Adsorption of phenolic compounds on sulfided (Co)Mo catalysts journal January 2013
Synthesis of supported Ni catalysts by atomic layer deposition journal July 2013
Carbon-supported bimetallic Pd–Fe catalysts for vapor-phase hydrodeoxygenation of guaiacol journal October 2013
Tuning acid–base cooperativity to create next generation silica-supported organocatalysts journal December 2013
Kinetics and mechanism of m-cresol hydrodeoxygenation on a Pt/SiO2 catalyst journal August 2014
A novel bifunctional electrocatalyst for unitized regenerative fuel cell journal January 2010
Preparation of Pt/Irx(IrO2)10−x bifunctional oxygen catalyst for unitized regenerative fuel cell journal July 2012
Selective conversion of m-cresol to toluene over bimetallic Ni–Fe catalysts journal July 2014
Combustion and gasification rates of lignocellulosic chars journal April 2009
Monolayer bimetallic surfaces: Experimental and theoretical studies of trends in electronic and chemical properties journal May 2008
Different Product Distributions and Mechanistic Aspects of the Hydrodeoxygenation of m-Cresol over Platinum and Ruthenium Catalysts journal September 2015
Experimental and Theoretical Insights into the Hydrogen-Efficient Direct Hydrodeoxygenation Mechanism of Phenol over Ru/TiO 2 journal October 2015
Role of the Support and Reaction Conditions on the Vapor-Phase Deoxygenation of m -Cresol over Pt/C and Pt/TiO 2 Catalysts journal March 2016
Enhanced Hydrodeoxygenation of m -Cresol over Bimetallic Pt–Mo Catalysts through an Oxophilic Metal-Induced Tautomerization Pathway journal June 2016
Cooperative Catalysis with Acid–Base Bifunctional Mesoporous Silica: Impact of Grafting and Co-condensation Synthesis Methods on Material Structure and Catalytic Properties journal June 2012
Catalytic asymmetric synthesis by means of secondary interaction between chiral ligands and substrates journal July 1992
Surface Chemistry of Transition Metal Carbides journal January 2005
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering journal September 2006
Structure and Surface Chemistry of Gold-Based Model Catalysts journal April 2011
Adsorption and Reaction of Furfural and Furfuryl Alcohol on Pd(111): Unique Reaction Pathways for Multifunctional Reagents journal August 2011
Ketonization of Carboxylic Acids: Mechanisms, Catalysts, and Implications for Biomass Conversion journal October 2013
Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m -Cresol journal August 2014
Hydrodeoxygenation of Anisole over Silica-Supported Ni 2 P, MoP, and NiMoP Catalysts journal March 2011
Catalytic Conversion of Guaiacol Catalyzed by Platinum Supported on Alumina: Reaction Network Including Hydrodeoxygenation Reactions journal August 2011
Hydrodeoxygenation of Guaiacol, A Surrogate of Lignin Pyrolysis Vapors, Over Iron Based Catalysts: Kinetics and Modeling of the Lignin to Aromatics Integrated Process journal January 2013
Pyrolysis of Wood and Bark in an Auger Reactor: Physical Properties and Chemical Analysis of the Produced Bio-oils journal January 2008
Catalytic Activities of NiMo Carbide Supported on SiO2 for the Hydrodeoxygenation of Ethyl Benzoate, Acetone, and Acetaldehyde journal March 2010
Hydrotreatment Activities of Supported Molybdenum Nitrides and Carbides journal May 1997
Hydrotreatment of Fast Pyrolysis Oil Using Heterogeneous Noble-Metal Catalysts
  • Wildschut, Jelle; Mahfud, Farchad H.; Venderbosch, Robbie H.
  • Industrial & Engineering Chemistry Research, Vol. 48, Issue 23, p. 10324-10334 https://doi.org/10.1021/ie9006003
journal December 2009
Gas-Phase Hydrogenation/Hydrogenolysis of Phenol over Supported Nickel Catalysts journal April 2000
New Catalysts for Hydroprocessing: Transition Metal Carbides and Nitrides journal November 1995
The temperature and coverage dependences of adsorbed formic acid and its conversion to formate on platinum(111) journal February 1992
Asymmetric Reissert-type Reaction Promoted by Bifunctional Catalyst journal July 2000
Template-Assisted Self-Assembly:  A Practical Route to Complex Aggregates of Monodispersed Colloids with Well-Defined Sizes, Shapes, and Structures journal September 2001
Titania-Supported PdAu Bimetallic Catalysts Prepared from Dendrimer-Encapsulated Nanoparticle Precursors journal February 2005
Effect of Surface Composition on Electronic Structure, Stability, and Electrocatalytic Properties of Pt-Transition Metal Alloys:  Pt-Skin versus Pt-Skeleton Surfaces journal July 2006
Evolution of Structure and Chemistry of Bimetallic Nanoparticle Catalysts under Reaction Conditions journal June 2010
Biphasic Pd−Au Alloy Catalyst for Low-Temperature CO Oxidation journal August 2010
Platinum−Gold Nanoparticles: A Highly Active Bifunctional Electrocatalyst for Rechargeable Lithium−Air Batteries journal September 2010
Selective Hydrogenolysis of Polyols and Cyclic Ethers over Bifunctional Surface Sites on Rhodium–Rhenium Catalysts journal August 2011
Trapping Guests within a Nanoporous Metal–Organic Framework through Pressure-Induced Amorphization journal November 2011
Isolated Metal Active Site Concentration and Stability Control Catalytic CO 2 Reduction Selectivity journal February 2015
Modeling Ethanol Decomposition on Transition Metals: A Combined Application of Scaling and Brønsted−Evans−Polanyi Relations journal April 2009
CO Adsorption on Molybdenum Nitride's γ-Mo 2 N(100) Surface:  Formation of NCO Species? A Density Functional Study journal November 2000
Reforming of Oxygenates for H 2 Production:  Correlating Reactivity of Ethylene Glycol and Ethanol on Pt(111) and Ni/Pt(111) with Surface d-Band Center journal February 2006
Tungsten Monocarbide as Potential Replacement of Platinum for Methanol Electrooxidation journal October 2007
Bio-oils Hydrodeoxygenation: Adsorption of Phenolic Molecules on Oxidic Catalyst Supports journal August 2010
Stable Low-Valence ReO x Cluster Attached on Rh Metal Particles Formed by Hydrogen Reduction and Its Formation Mechanism journal January 2012
Adsorption Orientation-Induced Selectivity Control of Reactions of Benzyl Alcohol on Pd(111) journal June 2012
Structure of ReO x Clusters Attached on the Ir Metal Surface in Ir–ReO x /SiO 2 for the Hydrogenolysis Reaction journal October 2012
Promotion of Activity and Selectivity by Alkanethiol Monolayers for Pd-Catalyzed Benzyl Alcohol Hydrodeoxygenation journal October 2014
Platinum Nanoparticle Shape Effects on Benzene Hydrogenation Selectivity journal October 2007
Size-Dependent Subnanometer Pd Cluster (Pd 4 , Pd 6 , and Pd 17 ) Water Oxidation Electrocatalysis journal June 2013
Thermochemistry of Oxygen Transfer between Rhenium and Phosphine Complexes. A Density Functional Study journal November 1999
Effects of Alloying Pd and Au on the Hydrogenation of Ethylene: An ab initio-Based Dynamic Monte Carlo Study journal January 2002
Molecular imprinting of bulk, microporous silica journal January 2000
Size-dependent catalytic activity of supported metal clusters journal November 1994
Directing reaction pathways by catalyst active-site selection using self-assembled monolayers journal September 2013
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces journal February 2007
Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane journal February 2009
Hydrodeoxygenation of bio-derived phenols to hydrocarbons using RANEY® Ni and Nafion/SiO2 catalysts journal January 2010
Hydrodeoxygenation and coupling of aqueous phenolics over bifunctional zeolite-supported metal catalysts journal January 2010
Tungsten carbides as selective deoxygenation catalysts: experimental and computational studies of converting C3 oxygenates to propene journal January 2014
Recent advances in heterogeneous catalysts for bio-oil upgrading via “ex situ catalytic fast pyrolysis”: catalyst development through the study of model compounds journal January 2014
A review and perspective of recent bio-oil hydrotreating research journal January 2014
Low-temperature water–gas shift reaction over gold deposited on TiO2 journal January 1997
Ligand and ensemble effects in adsorption on alloy surfaces journal January 2001
Cooperative catalysis by silica-supported organic functional groups journal January 2008
Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol journal January 2009
Nanostructured molybdenum carbides supported on carbon nanotubes as efficient catalysts for one-step hydrodeoxygenation and isomerization of vegetable oils journal January 2011
Bimetallic catalysts for upgrading of biomass to fuels and chemicals journal January 2012
Top ten fundamental challenges of biomass pyrolysis for biofuels journal January 2012
Bimetallic effects in the hydrodeoxygenation of meta-cresol on γ-Al2O3 supported Pt–Ni and Pt–Co catalysts journal January 2012
Single atom alloy surface analogs in Pd0.18Cu15 nanoparticles for selective hydrogenation reactions journal January 2013
Aqueous-phase hydrogenation and hydrodeoxygenation of biomass-derived oxygenates with bimetallic catalysts journal January 2014
Selective production of cyclohexanol and methanol from guaiacol over Ru catalyst combined with MgO journal January 2014
Modification of the surface electronic and chemical properties of Pt(111) by subsurface 3d transition metals journal June 2004
Catalytic Properties of Single Layers of Transition Metal Sulfide Catalytic Materials journal January 2006
Pathways for Carboxylic Acid Decomposition on Transition Metal Oxides journal August 1994
The identification and some properties of point defects and non-basal dislocations in molybdenite surfaces
  • Bahl, O. P.; Evans, E. L.; Thomas, J. M.
  • Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 306, Issue 1484, p. 53-65 https://doi.org/10.1098/rspa.1968.0137
journal July 1968
Coating Fine Nickel Particles with Al 2 O 3 Utilizing an Atomic Layer Deposition-Fluidized Bed Reactor (ALD-FBR) journal April 2004
The adsorption and decomposition of formic acid on Ni(111): The identification of formic anhydride by vibrational spectroscopy journal May 1989
The Role of Atomic Ensembles in the Reactivity of Bimetallic Electrocatalysts journal September 2001
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts journal August 2003
The Promotional Effect of Gold in Catalysis by Palladium-Gold journal October 2005
Solid Nanoparticles that Catalyze Biofuel Upgrade Reactions at the Water/Oil Interface journal December 2009
Break-Up of Stepped Platinum Catalyst Surfaces by High CO Coverage journal February 2010
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects journal April 2010
Alkali-Stabilized Pt-OHx Species Catalyze Low-Temperature Water-Gas Shift Reactions journal September 2010
Spectroscopic Observation of Dual Catalytic Sites During Oxidation of CO on a Au/TiO2 Catalyst journal August 2011
Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer Deposition journal March 2012
The critical role of water at the gold-titania interface in catalytic CO oxidation journal September 2014
Influence of the support on surface rearrangements of bimetallic nanoparticles in real catalysts journal October 2014
Platinum-Like Behavior of Tungsten Carbide in Surface Catalysis journal August 1973
Atomically Dispersed Supported Metal Catalysts journal July 2012
CRC Handbook of Chemistry and Physics book June 2014