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Title: Time-dependent local and average structural evolution of δ-phase 239Pu-Ga alloys

Abstract

Here, plutonium metal is a very unusual element, exhibiting six allotropes at ambient pressure, between room temperature and its melting point, a complicated phase diagram, and a complex electronic structure. Many phases of plutonium metal are unstable with changes in temperature, pressure, chemical additions, or time. This strongly affects structure and properties, and becomes of high importance, particularly when considering effects on structural integrity over long periods of time [1]. This paper presents a time-dependent neutron total scattering study of the local and average structure of naturally aging δ-phase239Pu-Ga alloys, together with preliminary results on neutron tomography characterization.

Authors:
 [1];  [2];  [2];  [3];  [1];  [1];  [1];  [1];  [1];  [1]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of California, Berkeley, CA (United States)
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1324570
Report Number(s):
LA-UR-16-22439
Journal ID: ISSN 2059-8521; applab
Grant/Contract Number:  
AC52-06NA25396
Resource Type:
Accepted Manuscript
Journal Name:
MRS Advances
Additional Journal Information:
Journal Name: MRS Advances; Journal ID: ISSN 2059-8521
Publisher:
Materials Research Society (MRS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Smith, Alice I., Page, Katharine L., Siewenie, Joan E., Losko, Adrian S., Vogel, Sven C., Gourdon, Olivier A., Richmond, Scott, Saleh, Tarik A., Ramos, Michael, and Schwartz, Daniel S. Time-dependent local and average structural evolution of δ-phase 239Pu-Ga alloys. United States: N. p., 2016. Web. doi:10.1557/adv.2016.541.
Smith, Alice I., Page, Katharine L., Siewenie, Joan E., Losko, Adrian S., Vogel, Sven C., Gourdon, Olivier A., Richmond, Scott, Saleh, Tarik A., Ramos, Michael, & Schwartz, Daniel S. Time-dependent local and average structural evolution of δ-phase 239Pu-Ga alloys. United States. doi:10.1557/adv.2016.541.
Smith, Alice I., Page, Katharine L., Siewenie, Joan E., Losko, Adrian S., Vogel, Sven C., Gourdon, Olivier A., Richmond, Scott, Saleh, Tarik A., Ramos, Michael, and Schwartz, Daniel S. Fri . "Time-dependent local and average structural evolution of δ-phase 239Pu-Ga alloys". United States. doi:10.1557/adv.2016.541. https://www.osti.gov/servlets/purl/1324570.
@article{osti_1324570,
title = {Time-dependent local and average structural evolution of δ-phase 239Pu-Ga alloys},
author = {Smith, Alice I. and Page, Katharine L. and Siewenie, Joan E. and Losko, Adrian S. and Vogel, Sven C. and Gourdon, Olivier A. and Richmond, Scott and Saleh, Tarik A. and Ramos, Michael and Schwartz, Daniel S.},
abstractNote = {Here, plutonium metal is a very unusual element, exhibiting six allotropes at ambient pressure, between room temperature and its melting point, a complicated phase diagram, and a complex electronic structure. Many phases of plutonium metal are unstable with changes in temperature, pressure, chemical additions, or time. This strongly affects structure and properties, and becomes of high importance, particularly when considering effects on structural integrity over long periods of time [1]. This paper presents a time-dependent neutron total scattering study of the local and average structure of naturally aging δ-phase239Pu-Ga alloys, together with preliminary results on neutron tomography characterization.},
doi = {10.1557/adv.2016.541},
journal = {MRS Advances},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {8}
}

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Works referenced in this record:

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