Title: Revisiting formic acid decomposition on metallic powder catalysts: Exploding the HCOOH decomposition volcano curve

Journal Article · · Surface Science

Not Available

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI ID:
1324336
Journal Information:
Surface Science, Journal Name: Surface Science Journal Issue: C Vol. 650; ISSN 0039-6028
Publisher:
ElsevierCopyright Statement
Country of Publication:
Netherlands
Language:
English

References (28)

Selectivity Control in Gold-Mediated Esterification of Methanol journal May 2009
Linear free energy relationships for C1-oxygenate decomposition on transition metal surfaces journal January 1991
MBRS measurements of overlayer effects on surface lifetimes and reaction probabilities journal February 1980
Decomposition of formic acid on copper, nickel, and copper-nickel alloys II. Catalytic and temperature-programmed decomposition of formic acid on Cu/SiO2, Cu/Al2O3, and Cu powder journal May 1983
The interaction of formic acid with transition metal surfaces, studied in ultrahigh vacuum journal May 1994
Formic acid desorption from graphitized Ni(110) journal February 1976
The kinetics and mechanism of catalytic reactions by molecular beam relaxation spectroscopy: HCOOH decomposition journal June 1977
A vibrational study of formic acid interaction with clean and oxygen-covered silver (110) surfaces journal April 1981
A spectroscopic study of the adsorption and reactions of methanol, formaldehyde and methyl formate on clean and oxygenated Cu(110) surfaces journal June 1985
Reactions of formic acid and formaldehyde on Rh(111) and Rh(111)-(2 × 2)O surfaces journal May 1991
Adsorption and reaction of HCOOH on K-promoted Pd(100) surfaces journal December 1991
Adsorption and decomposition of formic acid on Ni{110} journal March 1995
The adsorption and decomposition of formaldehyde and formic acid on the clean and modified Fe (100) surface journal February 1996
Potassium-promoted synthesis of surface formate and reactions of formic acid on Co{100} journal March 1996
Thermal desorption of gases journal July 1962
Diagnosis of the nature of carboxylate coordination from the direction of shifts of carbonoxygen stretching frequencies journal October 1985
Reaction Kinetics and Mechanism on Metal Single Crystal Surfaces book January 1980
Quantitative determination of the number of active surface sites and the turnover frequencies for methanol oxidation over metal oxide catalysts journal November 2000
Electronic factors in catalysis: the volcano curve and the effect of promotion in catalytic ammonia synthesis journal December 2001
Hydrogen from formic acid decomposition over Pd and Au catalysts journal September 2010
Production of CO-free H2 from formic acid. A comparative study of the catalytic behavior of Pt metals on a carbon support journal April 2011
Volcano-Curves for Dehydrogenation of 2-Propanol and Hydrogenation of Nitrobenzene by SiO 2 -Supported Metal Nanoparticles Catalysts As Described in Terms of a d-Band Model journal August 2012
Theoretical Analysis of Transition-Metal Catalysts for Formic Acid Decomposition journal March 2014
Trends in Formic Acid Decomposition on Model Transition Metal Surfaces: A Density Functional Theory study journal November 2014
The temperature and coverage dependences of adsorbed formic acid and its conversion to formate on platinum(111) journal February 1992
Active oxygen on Group VIII metals: activation of formic acid and formaldehyde on Pd(100) journal January 1988
Using first principles to predict bimetallic catalysts for the ammonia decomposition reaction journal April 2010
Hydrogenation catalysts journal January 1950