The effect of interstitial carbon on the mechanical properties and dislocation substructure evolution in Fe40.4Ni11.3Mn34.8Al7.5Cr6 high entropy alloys
Abstract
A systematic study of the effects of up to 1.1 at. % carbon on the mechanical properties and evolution of the dislocation substructure in a series of a high entropy alloys (HEA) based on Fe40.4Ni11.3Mn34.8Al7.5Cr6 is presented. Transmission electron microscopy (TEM), synchrotron X-ray diffraction (XRD) and atom probe tomography (APT) were used to show that all the alloys are single-phase f.c.c. random solid solutions. The lattice constant, determined from synchrotron XRD measurements, increases linearly with increasing carbon concentration, which leads to a linear relationship between the yield strength and the carbon concentration. The dislocation substructures, as determined by a TEM, show a transition from wavy slip to planar slip and, at higher strains, and from cell-forming structure (dislocations cells, cell blocks and dense dislocation walls) to non-cell forming structure (Taylor lattice, microbands and domain boundaries) with the addition of carbon, features related to the increase in lattice friction stress. The stacking fault energy (measured via weak-beam imaging of the separation of dislocation partials) decreases with increasing carbon content, which also contributes to the transition from wavy slip to planar slip. The formation of non-cell forming structure induced by carbon leads to a high degree of strain hardening and a substantialmore »
- Authors:
-
- Dartmouth College, Hanover, NH (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1324207
- Alternate Identifier(s):
- OSTI ID: 1397975
- Grant/Contract Number:
- AC05-00OR22725; FG02-07ER46392
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Acta Materialia
- Additional Journal Information:
- Journal Volume: 120; Journal Issue: C; Journal ID: ISSN 1359-6454
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; high entropy alloy; interstitial strengthening; dislocation structures; strain hardening; weak-beam imaging
Citation Formats
Wang, Zhangwei, Baker, Ian, Cai, Zhonghou, Chen, Si, Poplawsky, Jonathan D., and Guo, Wei. The effect of interstitial carbon on the mechanical properties and dislocation substructure evolution in Fe40.4Ni11.3Mn34.8Al7.5Cr6 high entropy alloys. United States: N. p., 2016.
Web. doi:10.1016/j.actamat.2016.08.072.
Wang, Zhangwei, Baker, Ian, Cai, Zhonghou, Chen, Si, Poplawsky, Jonathan D., & Guo, Wei. The effect of interstitial carbon on the mechanical properties and dislocation substructure evolution in Fe40.4Ni11.3Mn34.8Al7.5Cr6 high entropy alloys. United States. https://doi.org/10.1016/j.actamat.2016.08.072
Wang, Zhangwei, Baker, Ian, Cai, Zhonghou, Chen, Si, Poplawsky, Jonathan D., and Guo, Wei. Thu .
"The effect of interstitial carbon on the mechanical properties and dislocation substructure evolution in Fe40.4Ni11.3Mn34.8Al7.5Cr6 high entropy alloys". United States. https://doi.org/10.1016/j.actamat.2016.08.072. https://www.osti.gov/servlets/purl/1324207.
@article{osti_1324207,
title = {The effect of interstitial carbon on the mechanical properties and dislocation substructure evolution in Fe40.4Ni11.3Mn34.8Al7.5Cr6 high entropy alloys},
author = {Wang, Zhangwei and Baker, Ian and Cai, Zhonghou and Chen, Si and Poplawsky, Jonathan D. and Guo, Wei},
abstractNote = {A systematic study of the effects of up to 1.1 at. % carbon on the mechanical properties and evolution of the dislocation substructure in a series of a high entropy alloys (HEA) based on Fe40.4Ni11.3Mn34.8Al7.5Cr6 is presented. Transmission electron microscopy (TEM), synchrotron X-ray diffraction (XRD) and atom probe tomography (APT) were used to show that all the alloys are single-phase f.c.c. random solid solutions. The lattice constant, determined from synchrotron XRD measurements, increases linearly with increasing carbon concentration, which leads to a linear relationship between the yield strength and the carbon concentration. The dislocation substructures, as determined by a TEM, show a transition from wavy slip to planar slip and, at higher strains, and from cell-forming structure (dislocations cells, cell blocks and dense dislocation walls) to non-cell forming structure (Taylor lattice, microbands and domain boundaries) with the addition of carbon, features related to the increase in lattice friction stress. The stacking fault energy (measured via weak-beam imaging of the separation of dislocation partials) decreases with increasing carbon content, which also contributes to the transition from wavy slip to planar slip. The formation of non-cell forming structure induced by carbon leads to a high degree of strain hardening and a substantial increase in the ultimate tensile strength. In conclusion, the consequent postponement of necking due to the high strain hardening, along with the plasticity accommodation arising from the formation of microbands and domain boundaries, result in an increase of ductility due to the carbon addition.},
doi = {10.1016/j.actamat.2016.08.072},
journal = {Acta Materialia},
number = C,
volume = 120,
place = {United States},
year = {Thu Sep 01 00:00:00 EDT 2016},
month = {Thu Sep 01 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
A fracture-resistant high-entropy alloy for cryogenic applications
journal, September 2014
- Gludovatz, B.; Hohenwarter, A.; Catoor, D.
- Science, Vol. 345, Issue 6201
Microstructures and properties of high-entropy alloys
journal, April 2014
- Zhang, Yong; Zuo, Ting Ting; Tang, Zhi
- Progress in Materials Science, Vol. 61
Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes
journal, May 2004
- Yeh, J.-W.; Chen, S.-K.; Lin, S.-J.
- Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303
An assessment on the future development of high-entropy alloys: Summary from a recent workshop
journal, November 2015
- Lu, Z. P.; Wang, H.; Chen, M. W.
- Intermetallics, Vol. 66
Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures
journal, December 2014
- Wu, Z.; Bei, H.; Pharr, G. M.
- Acta Materialia, Vol. 81
Effect of boron on grain-boundaries in Ni3Al†
journal, February 1985
- Liu, C. T.; White, C. L.; Horton, J. A.
- Acta Metallurgica, Vol. 33, Issue 2
The effect of boron on the lattice properties of Ni3Al
journal, March 1988
- Baker, I.; Huang, B.; Schulson, E. M.
- Acta Metallurgica, Vol. 36, Issue 3
Grain boundary accommodation of slip in Ni3Al containing boron
journal, July 1986
- Schulson, E. M.; Weihs, T. P.; Baker, I.
- Acta Metallurgica, Vol. 34, Issue 7
Nano-twin mediated plasticity in carbon-containing FeNiCoCrMn high entropy alloys
journal, October 2015
- Wu, Z.; Parish, C. M.; Bei, H.
- Journal of Alloys and Compounds, Vol. 647
High strength Fe–Mn–(Al, Si) TRIP/TWIP steels development — properties — application
journal, January 2000
- Grässel, O.; Krüger, L.; Frommeyer, G.
- International Journal of Plasticity, Vol. 16, Issue 10-11
Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off
journal, May 2016
- Li, Zhiming; Pradeep, Konda Gokuldoss; Deng, Yun
- Nature, Vol. 534, Issue 7606
The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy
journal, September 2013
- Otto, F.; Dlouhý, A.; Somsen, Ch.
- Acta Materialia, Vol. 61, Issue 15
Design of a twinning-induced plasticity high entropy alloy
journal, August 2015
- Deng, Y.; Tasan, C. C.; Pradeep, K. G.
- Acta Materialia, Vol. 94
Origin of Extended Tensile Ductility of a Fe-28Mn-10Al-1C Steel
journal, May 2009
- Yoo, J. D.; Hwang, S. W.; Park, K. -T.
- Metallurgical and Materials Transactions A, Vol. 40, Issue 7
Microband-induced plasticity in a high Mn–Al–C light steel
journal, November 2008
- Yoo, Je Doo; Park, Kyung-Tae
- Materials Science and Engineering: A, Vol. 496, Issue 1-2
Interstitial strengthening of a f.c.c. FeNiMnAlCr high entropy alloy
journal, October 2016
- Wang, Zhangwei; Baker, Ian
- Materials Letters, Vol. 180
Effect of chemical composition on work hardening of Fe—Mn—C TWIP steels
journal, March 2011
- Bouaziz, O.; Zurob, H.; Chehab, B.
- Materials Science and Technology, Vol. 27, Issue 3
An experimental investigation of extrapolation methods in the derivation of accurate unit-cell dimensions of crystals
journal, May 1945
- Nelson, J. B.; Riley, D. P.
- Proceedings of the Physical Society, Vol. 57, Issue 3
An atom probe perspective on phase separation and precipitation in duplex stainless steels
journal, May 2016
- Guo, Wei; Garfinkel, David A.; Tucker, Julie D.
- Nanotechnology, Vol. 27, Issue 25
Strategies for fabricating atom probe specimens with a dual beam FIB
journal, March 2005
- Miller, M. K.; Russell, K. F.; Thompson, G. B.
- Ultramicroscopy, Vol. 102, Issue 4
Performance of a local electrode atom probe
journal, January 2007
- Miller, M. K.; Russell, K. F.
- Surface and Interface Analysis, Vol. 39, Issue 2-3
On the room-temperature deformation mechanisms of lamellar-structured Fe30Ni20Mn35Al15
journal, May 2011
- Liao, Yifeng; Baker, Ian
- Materials Science and Engineering: A, Vol. 528, Issue 12
Quantitative binomial distribution analyses of nanoscale like‐solute atom clustering and segregation in atom probe tomography data
journal, July 2008
- Moody, Michael P.; Stephenson, Leigh T.; Ceguerra, Anna V.
- Microscopy Research and Technique, Vol. 71, Issue 7
Incipient plasticity and dislocation nucleation of FeCoCrNiMn high-entropy alloy
journal, May 2013
- Zhu, C.; Lu, Z. P.; Nieh, T. G.
- Acta Materialia, Vol. 61, Issue 8
On the origin of planar slip in f.c.c. alloys
journal, August 1989
- Gerold, V.; Karnthaler, H. P.
- Acta Metallurgica, Vol. 37, Issue 8
A novel, single phase, non-equiatomic FeMnNiCoCr high-entropy alloy with exceptional phase stability and tensile ductility
journal, February 2014
- Yao, M. J.; Pradeep, K. G.; Tasan, C. C.
- Scripta Materialia, Vol. 72-73
Microscopic versus macroscopic aspect of shear bands deformation
journal, October 1986
- Korbel, A.; Martin, P.
- Acta Metallurgica, Vol. 34, Issue 10
Microstructural aspects of strain localization in AlMg alloys
journal, October 1986
- Korbel, A.; Embury, J. D.; Hatherly, M.
- Acta Metallurgica, Vol. 34, Issue 10
Microband formation in shock-loaded and quasi-statically deformed metals
journal, December 1989
- Huang, J. C.; Gray, G. T.
- Acta Metallurgica, Vol. 37, Issue 12
Microstructural evolution in a non-cell forming metal: AlMg
journal, May 1993
- Hughes, D. A.
- Acta Metallurgica et Materialia, Vol. 41, Issue 5
Stacking Fault Energy in Silicon
journal, October 1962
- Aerts, E.; Delavignette, P.; Siems, R.
- Journal of Applied Physics, Vol. 33, Issue 10
Supra-Ductile and High-Strength Manganese-TRIP/TWIP Steels for High Energy Absorption Purposes.
journal, January 2003
- Frommeyer, Georg; Brüx, Udo; Neumann, Peter
- ISIJ International, Vol. 43, Issue 3
Boron extended solubility and strengthening potency in rapidly solidified Ni3Al
journal, October 1984
- Huang, S. C.; Taub, A. I.; Chang, K. M.
- Acta Metallurgica, Vol. 32, Issue 10
Carbon effects in rapidly solidified Ni 3 Al
journal, February 1986
- Huang, S. C.; Briant, C. L.; Chang, K. -M.
- Journal of Materials Research, Vol. 1, Issue 1
The room temperature strengthening effect of boron as a function of aluminum concentration in FeAl
journal, January 1998
- Baker, I.; Li, X.; Xiao, H.
- Intermetallics, Vol. 6, Issue 3
The strength, hardness and ductility of Ni3Al with and without boron
journal, May 1987
- Weihs, T. P.; Zinoviev, V.; Viens, D. V.
- Acta Metallurgica, Vol. 35, Issue 5
The flow stress of body-centered cubic metals: inherent lattice hardening or solution hardening?
journal, September 1967
- Fleischer, R. L.
- Acta Metallurgica, Vol. 15, Issue 9
Statistische theorien der mischkristallhärtung
journal, July 1972
- Labusch, R.
- Acta Metallurgica, Vol. 20, Issue 7
The theory of solution hardening
journal, March 1977
- Nabarro, F. R. N.
- Philosophical Magazine, Vol. 35, Issue 3
Transmission electron microscopy study of the stacking-fault energy and dislocation structure in CuMn alloys
journal, August 1987
- Steffens, Th.; Schwink, Ch.; Korner, A.
- Philosophical Magazine A, Vol. 56, Issue 2
Multistage strain hardening through dislocation substructure and twinning in a high strength and ductile weight-reduced Fe–Mn–Al–C steel
journal, September 2012
- Gutierrez-Urrutia, I.; Raabe, D.
- Acta Materialia, Vol. 60, Issue 16
Cold deformation microstructures
journal, November 1990
- Hansen, N.
- Materials Science and Technology, Vol. 6, Issue 11
Microstructural evolution in nickel during rolling and torsion
journal, June 1991
- Hughes, D. A.; Hansen, N.
- Materials Science and Technology, Vol. 7, Issue 6
Cell and band structures in cold rolled polycrystalline copper
journal, December 1991
- Ananthan, V. S.; Leffers, T.; Hansen, N.
- Materials Science and Technology, Vol. 7, Issue 12
Deformation structures in lightly rolled pure aluminium
journal, July 1989
- Bay, B.; Hansen, N.; Kuhlmann-Wilsdorf, D.
- Materials Science and Engineering: A, Vol. 113
Strain hardening behavior of aluminum alloyed Hadfield steel single crystals
journal, April 2005
- Canadinc, D.; Sehitoglu, H.; Maier, H. J.
- Acta Materialia, Vol. 53, Issue 6
The role of dense dislocation walls on the deformation response of aluminum alloyed hadfield steel polycrystals
journal, April 2007
- Canadinc, D.; Sehitoglu, H.; Maier, H. J.
- Materials Science and Engineering: A, Vol. 454-455
Dislocation and twin substructure evolution during strain hardening of an Fe–22wt.% Mn–0.6wt.% C TWIP steel observed by electron channeling contrast imaging
journal, September 2011
- Gutierrez-Urrutia, I.; Raabe, D.
- Acta Materialia, Vol. 59, Issue 16
The plasticity of pure single crystals
journal, April 1964
- Nabarro, F. R. N.; Basinski, Z. S.; Holt, D. B.
- Advances in Physics, Vol. 13, Issue 50
Physics and phenomenology of strain hardening: the FCC case
journal, January 2003
- Kocks, U. F.; Mecking, H.
- Progress in Materials Science, Vol. 48, Issue 3
Works referencing / citing this record:
Ultra-High Strength TiC/Refractory High-Entropy-Alloy Composite Prepared by Powder Metallurgy
journal, February 2017
- Liu, Bin; Wang, Jingshi; Chen, Jian
- JOM, Vol. 69, Issue 4
Impact of interstitial C on phase stability and stacking-fault energy of the CrMnFeCoNi high-entropy alloy
journal, November 2019
- Ikeda, Yuji; Tanaka, Isao; Neugebauer, Jörg
- Physical Review Materials, Vol. 3, Issue 11
Multicomponent intermetallic nanoparticles and superb mechanical behaviors of complex alloys
journal, November 2018
- Yang, T.; Zhao, Y. L.; Tong, Y.
- Science, Vol. 362, Issue 6417
Microstructure and Mechanical Properties Evolution of the Al, C-Containing CoCrFeNiMn-Type High-Entropy Alloy during Cold Rolling
journal, December 2017
- Klimova, Margarita; Stepanov, Nikita; Shaysultanov, Dmitry
- Materials, Vol. 11, Issue 1
Excellent room temperature ductility of as-cast TRIP high-entropy alloy via Mo and C alloying
journal, September 2019
- Lv, Yukun; Zhao, Xuerou; Shi, Tuo
- Journal of Materials Science, Vol. 55, Issue 5
Synthesis and characterisation of TiC reinforced CoCrFeNi composite by hot-pressing sintering
journal, December 2019
- Zhang, Guopeng; Wang, Guifang; Yang, Tianhai
- Materials Science and Technology, Vol. 36, Issue 4
First-Principles Study on a New All-d-Metal Full-Heusler-Based Shape-Memory Alloy Cd 2 MnPd
journal, September 2019
- Chen, Zongbin; Wei, Huan; Xu, Heju
- SPIN, Vol. 09, Issue 03
Ab initio -informed phase-field modeling of dislocation core structures in equal-molar CoNiRu multi-principal element alloys
journal, August 2019
- Su, Yanqing; Xu, Shuozhi; Beyerlein, Irene J.
- Modelling and Simulation in Materials Science and Engineering, Vol. 27, Issue 8
Enhanced strength and ductility in a high-entropy alloy via ordered oxygen complexes
journal, November 2018
- Lei, Zhifeng; Liu, Xiongjun; Wu, Yuan
- Nature, Vol. 563, Issue 7732
Tribological properties of FeCoCrNiAlBx high-entropy alloys coating prepared by laser cladding
journal, February 2017
- Lin, Dan-yang; Zhang, Nan-nan; He, Bin
- Journal of Iron and Steel Research International, Vol. 24, Issue 2
Effect of interstitial carbon on the evolution of early-stage irradiation damage in equi-atomic FeMnNiCoCr high-entropy alloys
journal, January 2020
- Lu, Eryang; Makkonen, Ilja; Mizohata, Kenichiro
- Journal of Applied Physics, Vol. 127, Issue 2
Metastability in high-entropy alloys: A review
journal, September 2018
- Wei, Shaolou; He, Feng; Tasan, Cemal Cem
- Journal of Materials Research, Vol. 33, Issue 19
FCC to BCC transformation-induced plasticity based on thermodynamic phase stability in novel V10Cr10Fe45CoxNi35−x medium-entropy alloys
journal, February 2019
- Jo, Y. H.; Choi, W. M.; Kim, D. G.
- Scientific Reports, Vol. 9, Issue 1
Microstructure and Mechanical Properties Evolution of the Al, C-Containing CoCrFeNiMn-Type High-Entropy Alloy during Cold Rolling
journal, December 2017
- Klimova, Margarita; Stepanov, Nikita; Shaysultanov, Dmitry
- Materials, Vol. 11, Issue 1