In situ studies of surface of NiFe2O4 catalyst during complete oxidation of methane
Abstract
Here, NiFe2O4 with an inverse spinel structure exhibits high activity for a complete oxidation of methane at 400 °C–425 °C and a higher temperature. The surface of the catalyst and its adsorbates were well characterized with ambient pressure X-ray photoelectron spectroscopy (AP-XPS) and in situ infrared spectroscopy (IR). In situ studies of the surface of NiFe2O4 using AP-XPS suggest the formation of methoxy-like and formate-like intermediates at a temperature lower than 200 °C, supported by the observed vibrational signatures in in situ IR studies. Evolutions of C1s photoemission features and the nominal atomic ratios of C/(Ni + Fe) of the catalyst surface suggest that the formate-like intermediate is transformed to product molecules CO2 and H2O in the temperature range of 250–300 °C. In situ studies suggest the formation of a spectator, – Olattice – CH2 – Olattice –. It strongly bonds to surface through C–O bonds and cannot be activated even at 400 °C.
- Authors:
-
- Univ. of Kansas, Lawrence, KS (United States)
- Hubei Univ. of Technology, Wuhan (People's Republic of China)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- (Feng) [Univ. of Kansas, Lawrence, KS (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1324204
- Alternate Identifier(s):
- OSTI ID: 1251782
- Grant/Contract Number:
- AC05-00OR22725; SC0014561
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Surface Science
- Additional Journal Information:
- Journal Volume: 648; Journal Issue: C; Journal ID: ISSN 0039-6028
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; complete oxidation; transition metal oxide; methane; in situ study
Citation Formats
Zhang, Shiran, Shan, Junjun, Nie, Longhui, Nguyen, Luan, Wu, Zili, and Tao, Franklin. In situ studies of surface of NiFe2O4 catalyst during complete oxidation of methane. United States: N. p., 2015.
Web. doi:10.1016/j.susc.2015.12.011.
Zhang, Shiran, Shan, Junjun, Nie, Longhui, Nguyen, Luan, Wu, Zili, & Tao, Franklin. In situ studies of surface of NiFe2O4 catalyst during complete oxidation of methane. United States. https://doi.org/10.1016/j.susc.2015.12.011
Zhang, Shiran, Shan, Junjun, Nie, Longhui, Nguyen, Luan, Wu, Zili, and Tao, Franklin. Mon .
"In situ studies of surface of NiFe2O4 catalyst during complete oxidation of methane". United States. https://doi.org/10.1016/j.susc.2015.12.011. https://www.osti.gov/servlets/purl/1324204.
@article{osti_1324204,
title = {In situ studies of surface of NiFe2O4 catalyst during complete oxidation of methane},
author = {Zhang, Shiran and Shan, Junjun and Nie, Longhui and Nguyen, Luan and Wu, Zili and Tao, Franklin},
abstractNote = {Here, NiFe2O4 with an inverse spinel structure exhibits high activity for a complete oxidation of methane at 400 °C–425 °C and a higher temperature. The surface of the catalyst and its adsorbates were well characterized with ambient pressure X-ray photoelectron spectroscopy (AP-XPS) and in situ infrared spectroscopy (IR). In situ studies of the surface of NiFe2O4 using AP-XPS suggest the formation of methoxy-like and formate-like intermediates at a temperature lower than 200 °C, supported by the observed vibrational signatures in in situ IR studies. Evolutions of C1s photoemission features and the nominal atomic ratios of C/(Ni + Fe) of the catalyst surface suggest that the formate-like intermediate is transformed to product molecules CO2 and H2O in the temperature range of 250–300 °C. In situ studies suggest the formation of a spectator, – Olattice – CH2 – Olattice –. It strongly bonds to surface through C–O bonds and cannot be activated even at 400 °C.},
doi = {10.1016/j.susc.2015.12.011},
journal = {Surface Science},
number = C,
volume = 648,
place = {United States},
year = {Mon Dec 21 00:00:00 EST 2015},
month = {Mon Dec 21 00:00:00 EST 2015}
}
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