Pressure effects on magnetic ground states in cobalt doped multiferroic Mn1-xCoxWO4

Wang, Jinchen; Ye, Feng; Chi, Songxue; Fernandez-Baca, Jaime A.; Cao, Huibo; Tian, Wei; Gooch, Mellisa; Poudel, N.; Wang, Yaqi Q.; Lorenz, Bernd; Chu, C. W.

doi:10.1103/PhysRevB.93.155164

Title: Pressure effects on magnetic ground states in cobalt doped multiferroic Mn_1-xCo_xWO₄

Abstract

Using x-ray and high pressure neutron diffraction, we studied the pressure effect on structural and magnetic properties of multiferroic Mn_1-xCo_xWO₄ single crystals (x = 0, 0.05, 0.135 and 0.17), and compared it with the effects of doping. Both Co doping and pressure stretch the Mn-Mn chain along the c direction. At high doping level (x = 0.135 and 0.17), pressure and Co doping drive the system in a very similar way and induce a spin-flop transition for the x = 0.135 compound. In contrast, magnetic ground states at lower doping level (x = 0 and 0.05) are robust against pressure but experience a pronounced change upon Co substitution. As Co introduces both chemical pressure and magnetic anisotropy into the frustrated magnetic system, our results suggest the magnetic anisotropy is the main driving force for the Co induced phase transitions at low doping level, and chemical pressure plays a more significant role at higher Co concentrations.

Authors:

Wang, Jinchen ^[1]; Ye, Feng ^[2]; Chi, Songxue ^[3]; Fernandez-Baca, Jaime A. ^[3]; Cao, Huibo ^[3]; Tian, Wei ^[3]; Gooch, Mellisa ^[4]; Poudel, N. ^[4]; Wang, Yaqi Q. ^[4]; Lorenz, Bernd ^[4]; Chu, C. W. ^[5]

Renmin Univ. of China, Beijing (China); Univ. of Kentucky, Lexington, KY (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Kentucky, Lexington, KY (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Houston, Houston, TX (United States)
Univ. of Houston, Houston, TX (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Publication Date:: Thu Apr 28 00:00:00 EDT 2016

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). High Flux Isotope Reactor (HFIR); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1324079

Alternate Identifier(s):: OSTI ID: 1249887

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 93; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Wang, Jinchen, Ye, Feng, Chi, Songxue, Fernandez-Baca, Jaime A., Cao, Huibo, Tian, Wei, Gooch, Mellisa, Poudel, N., Wang, Yaqi Q., Lorenz, Bernd, and Chu, C. W. Pressure effects on magnetic ground states in cobalt doped multiferroic Mn1-xCoxWO4.  United States: N. p., 2016. 
Web.  doi:10.1103/PhysRevB.93.155164.

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                    Wang, Jinchen, Ye, Feng, Chi, Songxue, Fernandez-Baca, Jaime A., Cao, Huibo, Tian, Wei, Gooch, Mellisa, Poudel, N., Wang, Yaqi Q., Lorenz, Bernd, & Chu, C. W. Pressure effects on magnetic ground states in cobalt doped multiferroic Mn1-xCoxWO4.  United States.  https://doi.org/10.1103/PhysRevB.93.155164

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                    Wang, Jinchen, Ye, Feng, Chi, Songxue, Fernandez-Baca, Jaime A., Cao, Huibo, Tian, Wei, Gooch, Mellisa, Poudel, N., Wang, Yaqi Q., Lorenz, Bernd, and Chu, C. W. Thu .  
"Pressure effects on magnetic ground states in cobalt doped multiferroic Mn1-xCoxWO4".  United States.  https://doi.org/10.1103/PhysRevB.93.155164.  https://www.osti.gov/servlets/purl/1324079.

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@article{osti_1324079,

  title        = {Pressure effects on magnetic ground states in cobalt doped multiferroic Mn1-xCoxWO4},

  author       = {Wang, Jinchen and Ye, Feng and Chi, Songxue and Fernandez-Baca, Jaime A. and Cao, Huibo and Tian, Wei and Gooch, Mellisa and Poudel, N. and Wang, Yaqi Q. and Lorenz, Bernd and Chu, C. W.},

  abstractNote = {Using x-ray and high pressure neutron diffraction, we studied the pressure effect on structural and magnetic properties of multiferroic Mn1-xCoxWO4 single crystals (x = 0, 0.05, 0.135 and 0.17), and compared it with the effects of doping. Both Co doping and pressure stretch the Mn-Mn chain along the c direction. At high doping level (x = 0.135 and 0.17), pressure and Co doping drive the system in a very similar way and induce a spin-flop transition for the x = 0.135 compound. In contrast, magnetic ground states at lower doping level (x = 0 and 0.05) are robust against pressure but experience a pronounced change upon Co substitution. As Co introduces both chemical pressure and magnetic anisotropy into the frustrated magnetic system, our results suggest the magnetic anisotropy is the main driving force for the Co induced phase transitions at low doping level, and chemical pressure plays a more significant role at higher Co concentrations.},

  doi          = {10.1103/PhysRevB.93.155164},

  journal      = {Physical Review B},

  number       = ,

  volume       = 93,

  place        = {United States},

  year         = {Thu Apr 28 00:00:00 EDT 2016},

  month        = {Thu Apr 28 00:00:00 EDT 2016}

}

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Title: Pressure effects on magnetic ground states in cobalt doped multiferroic Mn1-xCoxWO4

Abstract

Citation Formats

Magnetic control of ferroelectric polarization journal, November 2003

Multiferroics: Different ways to combine magnetism and ferroelectricity journal, November 2006

Multiferroics: a magnetic twist for ferroelectricity journal, January 2007

Multiferroics progress and prospects in thin films journal, January 2007

Multiferroics—toward strong coupling between magnetization and polarization in a solid journal, March 2007

Multiferroics of spin origin journal, July 2014

Spin Current and Magnetoelectric Effect in Noncollinear Magnets journal, July 2005

Role of the Dzyaloshinskii-Moriya interaction in multiferroic perovskites journal, March 2006

Ferroelectricity in Spiral Magnets journal, February 2006

Electric polarization reversal and memory in a multiferroic material induced by magnetic fields journal, May 2004

Bond electronic polarization induced by spin journal, December 2006

Microscopic theory of spin-polarization coupling in multiferroic transition metal oxides journal, October 2007

Ferroelectric Polarization Flop in a Frustrated Magnet MnWO 4 Induced by a Magnetic Field journal, August 2006

Ferroelectricity in the cycloidal spiral magnetic phase of Mn W O 4 journal, November 2006

A new multiferroic material: MnWO 4 journal, September 2006

Magnetic phase transitions of MnWO 4 studied by the use of neutron diffraction journal, September 1993

Incommensurate magnetic structures of multiferroic MnWO 4 studied within the superspace formalism journal, January 2013

Magnon dispersion in journal, January 1999

Long-range magnetic interactions in the multiferroic antiferromagnet MnWO 4 journal, April 2011

Magnetic structure and ferroelectric polarization of MnWO 4 investigated by density functional calculations and classical spin analysis journal, September 2009

Landau theory for the phase diagram of multiferroic Mn 1 − x (Fe,Zn,Mg) x WO 4 journal, May 2012

Magnetic-field dependence of the ferroelectric polarization and spin-lattice coupling in multiferroic Mn W O 4 journal, February 2008

Multiferroicity on the Zigzag-Chain Antiferromagnet MnWO 4 in High Magnetic Fields journal, May 2012

X phase of MnWO 4 journal, July 2014

Field effects with H ∥ b on the incommensurate magnetic structures of multiferroic MnW O 4 studied within the superspace formalism journal, March 2015

Magnetic switching and phase competition in the multiferroic antiferromagnet Mn 1 − x Fe x WO 4 journal, November 2008

Effect of Nonmagnetic Substituents Mg and Zn on the Phase Competition in the Multiferroic Antiferromagnet MnWO 4 journal, November 2009

Robust ferroelectric state in multiferroic Mn 1 − x Zn x WO 4 journal, January 2011

Stabilized helical spin order and multiferroic phase coexistence in MnWO 4 : Consequence of 4 d Ru substitution of Mn journal, March 2013

Observation of spontaneous ferroelectric polarization reversal in multiferroic Mn1−xNixWO4 (x ≈ 0.16) journal, June 2014

Crystal structure, incommensurate magnetic order, and ferroelectricity in Mn 1 − x Cu x WO 4 ( 0 ≤ x ≤ 0.19 ) journal, June 2015

Stabilization of the elliptical spiral phase and the spin-flop transition in multiferroic Mn 1 − x Co x WO 4 journal, June 2009

Chemical doping-induced flop of ferroelectric polarization in multiferroic Mn 0.9 Co 0.1 WO 4 journal, December 2010

Magnetic and multiferroic phases of single-crystalline Mn 0.85 Co 0.15 WO 4 journal, November 2010

Magnetic order and spin-flop transitions in the cobalt-doped multiferroic Mn 1 − x Co x WO 4 journal, September 2012

Conical antiferromagnetic order in the ferroelectric phase of Mn 0.8 Co 0.2 WO 4 resulting from the competition between collinear and cycloidal structures journal, June 2012

Neutron diffraction, magnetic, and magnetoelectric studies of phase transitions in multiferroic Mn 0.90 Co 0.10 WO 4 journal, March 2012

Magnetic-field-induced spontaneous polarization reversal in multiferroic Mn 0.85 Co 0.15 WO 4 journal, February 2014

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Room-temperature vibrational properties of multiferroic MnWO 4 under quasi-hydrostatic compression up to 39 GPa journal, January 2014

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Title: Pressure effects on magnetic ground states in cobalt doped multiferroic Mn_1-xCo_xWO₄

Magnetic control of ferroelectric polarization
journal, November 2003

Multiferroics: Different ways to combine magnetism and ferroelectricity
journal, November 2006

Multiferroics: a magnetic twist for ferroelectricity
journal, January 2007

Multiferroics progress and prospects in thin films
journal, January 2007

Multiferroics—toward strong coupling between magnetization and polarization in a solid
journal, March 2007

Multiferroics of spin origin
journal, July 2014

Spin Current and Magnetoelectric Effect in Noncollinear Magnets
journal, July 2005

Role of the Dzyaloshinskii-Moriya interaction in multiferroic perovskites
journal, March 2006

Ferroelectricity in Spiral Magnets
journal, February 2006

Electric polarization reversal and memory in a multiferroic material induced by magnetic fields
journal, May 2004

Bond electronic polarization induced by spin
journal, December 2006

Microscopic theory of spin-polarization coupling in multiferroic transition metal oxides
journal, October 2007

Ferroelectric Polarization Flop in a Frustrated Magnet ${MnWO}_{4}$ Induced by a Magnetic Field
journal, August 2006

Ferroelectricity in the cycloidal spiral magnetic phase of $Mn W O_{4}$
journal, November 2006

A new multiferroic material: MnWO ₄
journal, September 2006

Magnetic phase transitions of ${MnWO}_{4}$ studied by the use of neutron diffraction
journal, September 1993

Incommensurate magnetic structures of multiferroic MnWO $_{4}$ studied within the superspace formalism
journal, January 2013

Magnon dispersion in
journal, January 1999

Long-range magnetic interactions in the multiferroic antiferromagnet MnWO $_{4}$
journal, April 2011

Magnetic structure and ferroelectric polarization of ${MnWO}_{4}$ investigated by density functional calculations and classical spin analysis
journal, September 2009

Landau theory for the phase diagram of multiferroic Mn $_{1 - x}$ (Fe,Zn,Mg) $_{x}$ WO $_{4}$
journal, May 2012

Magnetic-field dependence of the ferroelectric polarization and spin-lattice coupling in multiferroic $Mn W O_{4}$
journal, February 2008

Multiferroicity on the Zigzag-Chain Antiferromagnet MnWO ₄ in High Magnetic Fields
journal, May 2012

X phase of ${MnWO}_{4}$
journal, July 2014

Field effects with $H ∥ b$ on the incommensurate magnetic structures of multiferroic $MnW O_{4}$ studied within the superspace formalism
journal, March 2015

Magnetic switching and phase competition in the multiferroic antiferromagnet ${Mn}_{1 - x} {Fe}_{x} {WO}_{4}$
journal, November 2008

Effect of Nonmagnetic Substituents Mg and Zn on the Phase Competition in the Multiferroic Antiferromagnet MnWO ₄
journal, November 2009

Robust ferroelectric state in multiferroic ${Mn}_{1 - x} {Zn}_{x} {WO}_{4}$
journal, January 2011

Stabilized helical spin order and multiferroic phase coexistence in MnWO $_{4}$ : Consequence of $4 d$ Ru substitution of Mn
journal, March 2013

Observation of spontaneous ferroelectric polarization reversal in multiferroic Mn1−xNixWO4 (x ≈ 0.16)
journal, June 2014

Crystal structure, incommensurate magnetic order, and ferroelectricity in ${Mn}_{1 - x} {Cu}_{x} WO_{4} (0 \leq x \leq 0.19)$
journal, June 2015

Stabilization of the elliptical spiral phase and the spin-flop transition in multiferroic ${Mn}_{1 - x} {Co}_{x} {WO}_{4}$
journal, June 2009

Chemical doping-induced flop of ferroelectric polarization in multiferroic ${Mn}_{0.9} {Co}_{0.1} {WO}_{4}$
journal, December 2010

Magnetic and multiferroic phases of single-crystalline ${Mn}_{0.85} {Co}_{0.15} {WO}_{4}$
journal, November 2010

Magnetic order and spin-flop transitions in the cobalt-doped multiferroic Mn $_{1 - x}$ Co $_{x}$ WO $_{4}$
journal, September 2012

Conical antiferromagnetic order in the ferroelectric phase of Mn $_{0.8}$ Co $_{0.2}$ WO $_{4}$ resulting from the competition between collinear and cycloidal structures
journal, June 2012

Neutron diffraction, magnetic, and magnetoelectric studies of phase transitions in multiferroic Mn $_{0.90}$ Co $_{0.10}$ WO $_{4}$
journal, March 2012

Magnetic-field-induced spontaneous polarization reversal in multiferroic ${Mn}_{0.85}$ ${Co}_{0.15}$ ${WO}_{4}$
journal, February 2014

The complex multiferroic phase diagram of Mn _{1− x} Co _x WO ₄
journal, July 2012

Local symmetry and magnetic anisotropy in multiferroic ${MnWO}_{4}$ and antiferromagnetic ${CoWO}_{4}$ studied by soft x-ray absorption spectroscopy
journal, November 2010

Competing Magnetic Anisotropy Fields and Double Polarization Flops in Multiferroic Mn _{1- x} Co _x WO ₄
journal, December 2013

Pressure effects on the electronic and optical properties of $A$ WO $_{4}$ wolframites ( $A$ $=$ Cd, Mg, Mn, and Zn): The distinctive behavior of multiferroic MnWO $_{4}$
journal, September 2012

Pressure and temperature dependence of Raman scattering of MnWO4
journal, October 2013

Room-temperature vibrational properties of multiferroic MnWO ₄ under quasi-hydrostatic compression up to 39 GPa
journal, January 2014

High-pressure structural phase transition in ${MnWO}_{4}$
journal, March 2015

Origin of multiferroicity in MnWO $_{4}$
journal, April 2013

Direct observation of noncollinear order of Co and Mn moments in multiferroic $M n_{0.85} C o_{0.15} W O_{4}$
journal, June 2015

A Brief Review of the Effects of Pressure on Wolframite-Type Oxides
journal, January 2018