Magnetic and magnetocaloric properties of iron subs tituted holmium chromite and dysprosium chromite
Abstract
In this work, structural, magnetic, and magnetocaloric properties of HoCrO3 and Fe substituted HoCrO3 and DyCrO3 (i.e. HoCr0.7Fe0.3O3 and DyCr0.7Fe0.3O3) powder samples were synthesized via a solution route. The structural properties of the samples were examined by Raman spectroscopy and x-ray diffraction techniques, which were further confirmed using first-principle calculations. The dc magnetic measurements indicate that the Cr3+ ordering temperatures for the HoCrO3, HoCr0.7Fe0.3O3, and DyCr0.7Fe0.3O3 samples are 140 K, 174 K, and 160 K, respectively. The ac magnetic measurements not only confirmed the Cr3+ ordering transitions in these samples (obtained using dc magnetic measurements), but also clearly showed the Ho3+ ordering at ~10 K in the present HoCrO3 and HoCr0.7Fe0.3O3 samples, which to our knowledge, is the first ac magnetic evidence of Ho3+ ordering in this system. The effective magnetic moments were determined to be 11.67μB, 11.30μB, and 11.27μB for the HoCrO3, HoCr0.7Fe0.3O3, and DyCr0.7Fe0.3O3 samples, respectively. For the first time, the magnetocaloric properties of HoCrO3 and HoCr0.7Fe0.3O3 were studied here, showing their potential for applications in magnetic refrigeration. In an applied dc magnetic field of 7 T, the maximum magnetocaloric value were determined to be 7.2 (at 20 K), 6.83 (at 20 K), 13.08 J/kg K (at 5more »
- Authors:
-
- Univ. of Connecticut, Storrs, CT (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Oak Ridge Leadership Computing Facility (OLCF)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1324067
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- RSC Advances
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 12; Journal ID: ISSN 2046-2069
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Yin, Shiqi, Sharma, Vinit, McDannald, Austin, Reboredo, Fernando A., and Jain, Menka. Magnetic and magnetocaloric properties of iron subs tituted holmium chromite and dysprosium chromite. United States: N. p., 2016.
Web. doi:10.1039/C5RA24323H.
Yin, Shiqi, Sharma, Vinit, McDannald, Austin, Reboredo, Fernando A., & Jain, Menka. Magnetic and magnetocaloric properties of iron subs tituted holmium chromite and dysprosium chromite. United States. https://doi.org/10.1039/C5RA24323H
Yin, Shiqi, Sharma, Vinit, McDannald, Austin, Reboredo, Fernando A., and Jain, Menka. Mon .
"Magnetic and magnetocaloric properties of iron subs tituted holmium chromite and dysprosium chromite". United States. https://doi.org/10.1039/C5RA24323H. https://www.osti.gov/servlets/purl/1324067.
@article{osti_1324067,
title = {Magnetic and magnetocaloric properties of iron subs tituted holmium chromite and dysprosium chromite},
author = {Yin, Shiqi and Sharma, Vinit and McDannald, Austin and Reboredo, Fernando A. and Jain, Menka},
abstractNote = {In this work, structural, magnetic, and magnetocaloric properties of HoCrO3 and Fe substituted HoCrO3 and DyCrO3 (i.e. HoCr0.7Fe0.3O3 and DyCr0.7Fe0.3O3) powder samples were synthesized via a solution route. The structural properties of the samples were examined by Raman spectroscopy and x-ray diffraction techniques, which were further confirmed using first-principle calculations. The dc magnetic measurements indicate that the Cr3+ ordering temperatures for the HoCrO3, HoCr0.7Fe0.3O3, and DyCr0.7Fe0.3O3 samples are 140 K, 174 K, and 160 K, respectively. The ac magnetic measurements not only confirmed the Cr3+ ordering transitions in these samples (obtained using dc magnetic measurements), but also clearly showed the Ho3+ ordering at ~10 K in the present HoCrO3 and HoCr0.7Fe0.3O3 samples, which to our knowledge, is the first ac magnetic evidence of Ho3+ ordering in this system. The effective magnetic moments were determined to be 11.67μB, 11.30μB, and 11.27μB for the HoCrO3, HoCr0.7Fe0.3O3, and DyCr0.7Fe0.3O3 samples, respectively. For the first time, the magnetocaloric properties of HoCrO3 and HoCr0.7Fe0.3O3 were studied here, showing their potential for applications in magnetic refrigeration. In an applied dc magnetic field of 7 T, the maximum magnetocaloric value were determined to be 7.2 (at 20 K), 6.83 (at 20 K), 13.08 J/kg K (at 5 K) and the relative cooling power were 408, 387, and 500 J/kg for the HoCrO3, HoCr0.7Fe0.3O3, and DyCr0.7Fe0.3O3 samples, respectively.},
doi = {10.1039/C5RA24323H},
journal = {RSC Advances},
number = 12,
volume = 6,
place = {United States},
year = {Mon Jan 11 00:00:00 EST 2016},
month = {Mon Jan 11 00:00:00 EST 2016}
}
Web of Science
Works referenced in this record:
Massive Magnetic-Field-Induced Structural Transformation in and the Nature of the Giant Magnetocaloric Effect
journal, November 2003
- Pecharsky, V. K.; Holm, A. P.; Gschneidner, K. A.
- Physical Review Letters, Vol. 91, Issue 19
Recent developments in magnetocaloric materials
journal, May 2005
- Gschneidner, K. A.; Pecharsky, V. K.; Tsokol, A. O.
- Reports on Progress in Physics, Vol. 68, Issue 6, p. 1479-1539
Excellent magnetocaloric properties of melt-extracted Gd-based amorphous microwires
journal, September 2012
- Bingham, N. S.; Wang, H.; Qin, F.
- Applied Physics Letters, Vol. 101, Issue 10
Hysteresis and magnetocaloric effect at the magnetostructural phase transition of Ni-Mn-Ga and Ni-Mn-Co-Sn Heusler alloys
journal, January 2012
- Basso, Vittorio; Sasso, Carlo P.; Skokov, Konstantin P.
- Physical Review B, Vol. 85, Issue 1
Inverse magnetocaloric effect in ferromagnetic Ni–Mn–Sn alloys
journal, May 2005
- Krenke, Thorsten; Duman, Eyüp; Acet, Mehmet
- Nature Materials, Vol. 4, Issue 6
Pressure-Induced Colossal Magnetocaloric Effect in MnAs
journal, November 2004
- Gama, Sergio; Coelho, Adelino A.; de Campos, Ariana
- Physical Review Letters, Vol. 93, Issue 23
Review of the magnetocaloric effect in manganite materials
journal, January 2007
- Phan, Manh-Huong; Yu, Seong-Cho
- Journal of Magnetism and Magnetic Materials, Vol. 308, Issue 2
Low field induced giant anisotropic magnetocaloric effect in DyFeO 3 single crystal
journal, February 2015
- Ke, Ya-Jiao; Zhang, Xiang-Qun; Ge, Heng
- Chinese Physics B, Vol. 24, Issue 3
Magnetic Symmetry of Rare-Earth Orthochromites and Orthoferrites
journal, December 1973
- Yamaguchi, Tsuyoshi; Tsushima, Kunirô
- Physical Review B, Vol. 8, Issue 11
Neutron Diffraction Study of the Magnetic Properties of Rare-Earth-Iron Perovskites
journal, April 1960
- Koehler, W. C.; Wollan, E. O.; Wilkinson, M. K.
- Physical Review, Vol. 118, Issue 1
Infrared and Electronic Spectra of Rare Earth Perovskites: Ortho-Chromites, -Manganites and -Ferrites
journal, July 1970
- Rao, G. V. Subba; Rao, C. N. R.; Ferraro, J. R.
- Applied Spectroscopy, Vol. 24, Issue 4
Magnetic and magnetocaloric properties of TbMnO3 and Tb0.67R0.33MnO3 (R=Dy, Y, and Ho) bulk powders
journal, March 2015
- Staruch, M.; Kuna, L.; McDannald, A.
- Journal of Magnetism and Magnetic Materials, Vol. 377
Magnetic and magnetocaloric properties of bulk dysprosium chromite
journal, September 2013
- McDannald, A.; Kuna, L.; Jain, M.
- Journal of Applied Physics, Vol. 114, Issue 11
Multiferroicity and magnetoelectric coupling enhanced large magnetocaloric effect in DyFe 0.5 Cr 0.5 O 3
journal, January 2014
- Yin, L. H.; Yang, J.; Zhang, R. R.
- Applied Physics Letters, Vol. 104, Issue 3
Review of Recent Work on the Magnetic and Spectroscopic Properties of the Rare‐Earth Orthoferrites
journal, March 1969
- White, R. L.
- Journal of Applied Physics, Vol. 40, Issue 3
Large magnetocaloric effect induced by intrinsic structural transition in Dy 1− x Ho x MnO 3
journal, May 2012
- Shao, Mingjie; Cao, Shixun; Yuan, Shujuan
- Applied Physics Letters, Vol. 100, Issue 22
Magnetocaloric properties of rare-earth substituted DyCrO 3
journal, July 2015
- McDannald, A.; Jain, M.
- Journal of Applied Physics, Vol. 118, Issue 4
Rare earth chromites: a new family of multiferroics
journal, January 2007
- Sahu, Jyoti Ranjan; Serrao, Claudy Rayan; Ray, Nirat
- J. Mater. Chem., Vol. 17, Issue 1
Magnetic exchange interactions of rare-earth-substituted bulk powders
journal, June 2015
- McDannald, A.; Kuna, L.; Seehra, M. S.
- Physical Review B, Vol. 91, Issue 22
Magnetic Properties of Perovskite GdCrO3
journal, June 2001
- Yoshii, K.
- Journal of Solid State Chemistry, Vol. 159, Issue 1
Magnetization reversal and Yb3+/Cr3+ spin ordering at low temperature for perovskite YbCrO3 chromites
journal, July 2010
- Su, Yuling; Zhang, Jincang; Feng, Zhenjie
- Journal of Applied Physics, Vol. 108, Issue 1
Structure magnétique de DyCro3
journal, January 1968
- Bertaut, E. F.; Mareschal, J.
- Journal de Physique, Vol. 29, Issue 1
Heat capacity and magnetic phase transitions of rare-earth orthoferrite HoFeO3
journal, April 2002
- Bhattacharjee, Ashis; Saito, Kazuya; Sorai, Michio
- Journal of Physics and Chemistry of Solids, Vol. 63, Issue 4
Large magnetocaloric effect in HoFeO3 single crystal
journal, June 2012
- Shao, Mingjie; Cao, Shixun; Wang, Yabin
- Solid State Communications, Vol. 152, Issue 11
Dopant-mediated structural and magnetic properties of TbMnO 3
journal, July 2015
- Sharma, Vinit; McDannald, A.; Staruch, M.
- Applied Physics Letters, Vol. 107, Issue 1
Ferroelectricity and Giant Magnetocapacitance in Perovskite Rare-Earth Manganites
journal, June 2004
- Goto, T.; Kimura, T.; Lawes, G.
- Physical Review Letters, Vol. 92, Issue 25
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium
journal, May 1994
- Kresse, G.; Hafner, J.
- Physical Review B, Vol. 49, Issue 20, p. 14251-14269
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Formation enthalpies by mixing GGA and GGA calculations
journal, July 2011
- Jain, Anubhav; Hautier, Geoffroy; Ong, Shyue Ping
- Physical Review B, Vol. 84, Issue 4
Magnetic ordering in TbMn 0.5 Cr 0.5 O 3 studied by neutron diffraction and first-principles calculations
journal, July 2014
- Staruch, M.; Sharma, V.; dela Cruz, C.
- Journal of Applied Physics, Vol. 116, Issue 3
Facet-dependent catalytic activity of MnO electrocatalysts for oxygen reduction and oxygen evolution reactions
journal, January 2015
- Kuo, Chung-Hao; Mosa, Islam M.; Thanneeru, Srinivas
- Chemical Communications, Vol. 51, Issue 27
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013
- Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy
- APL Materials, Vol. 1, Issue 1
Finding Nature’s Missing Ternary Oxide Compounds Using Machine Learning and Density Functional Theory
journal, June 2010
- Hautier, Geoffroy; Fischer, Christopher C.; Jain, Anubhav
- Chemistry of Materials, Vol. 22, Issue 12
Static and dynamic magnetic properties and effect of surface chemistry on the morphology and crystallinity of DyCrO3 nanoplatelets
journal, January 2013
- Gupta, Preeti; Bhargava, Richa; Das, Raja
- RSC Advances, Vol. 3, Issue 48
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
Atomic Weights of the Elements 2005
journal, June 2007
- Wieser, M. E.
- Journal of Physical and Chemical Reference Data, Vol. 36, Issue 2
Magnetic and dielectric properties and Raman spectroscopy of GdCrO3 nanoparticles
journal, January 2010
- Jaiswal, Adhish; Das, Raja; Vivekanand, K.
- Journal of Applied Physics, Vol. 107, Issue 1
Synthesis and optical studies of GdCrO3 nanoparticles
journal, September 2010
- Jaiswal, Adhish; Das, Raja; Adyanthaya, Suguna
- Journal of Nanoparticle Research, Vol. 13, Issue 3
X-ray analysis of ZnO nanoparticles by Williamson–Hall and size–strain plot methods
journal, January 2011
- Khorsand Zak, A.; Abd. Majid, W. H.; Abrishami, M. E.
- Solid State Sciences, Vol. 13, Issue 1
Phonon Raman scattering of CrO perovskites ( , La, Pr, Sm, Gd, Dy, Ho, Yb, Lu)
journal, February 2012
- Weber, M. C.; Kreisel, J.; Thomas, P. A.
- Physical Review B, Vol. 85, Issue 5
Band gap tuning and orbital mediated electron–phonon coupling in HoFe 1−x Cr x O 3 (0 ≤ x ≤ 1)
journal, September 2015
- Kotnana, Ganesh; Jammalamadaka, S. Narayana
- Journal of Applied Physics, Vol. 118, Issue 12
Using Raman and dielectric spectroscopy to elucidate the spin phonon and magnetoelectric coupling in DyCrO 3 nanoplatelets
journal, January 2015
- Gupta, Preeti; Poddar, Pankaj
- RSC Advances, Vol. 5, Issue 14
Works referencing / citing this record:
Spin-phonon coupling in HoCr 1 − x Fe x O 3 ( x = 0 and 0.5) compounds
journal, February 2018
- Kotnana, Ganesh; Sathe, Vasant. G.; Narayana Jammalamadaka, S.
- Journal of Raman Spectroscopy, Vol. 49, Issue 4
The Crystal Structure, Raman Spectra, and Magnetic Properties of HoCrO3 Annealed in Different Atmospheres
journal, September 2018
- Liu, Yuzhuang; Peng, Haiping; Ju, Wei
- Journal of Superconductivity and Novel Magnetism, Vol. 32, Issue 6
Sol–gel synthesis of DyCrO 3 and 10% Fe-doped DyCrO 3 nanoparticles with enhanced photocatalytic hydrogen production abilities
journal, January 2018
- Ahsan, Ragib; Mitra, Avijit; Omar, Saleh
- RSC Advances, Vol. 8, Issue 26
Enhancement in magnetocaloric properties of holmium chromite by gadolinium substitution
journal, July 2016
- Yin, S.; Jain, M.
- Journal of Applied Physics, Vol. 120, Issue 4
Particle size dependence of the magnetic and magneto-caloric properties of HoCrO 3
journal, February 2017
- Yin, Shiqi; Sauyet, Theodore; Seehra, Mohindar S.
- Journal of Applied Physics, Vol. 121, Issue 6
Effect of Gd substitution on the structural, magnetic, and magnetocaloric properties of HoCrO 3
journal, February 2018
- Yin, Shiqi; Zhong, Wei; Guild, Curtis J.
- Journal of Applied Physics, Vol. 123, Issue 5
Enhancement in magnetocaloric properties of ErCrO 3 via A-site Gd substitution
journal, May 2018
- Shi, Jianhang; Yin, Shiqi; Seehra, Mohindar S.
- Journal of Applied Physics, Vol. 123, Issue 19
Effect of rare-earth (Er and Gd) substitution on the magnetic and multiferroic properties of DyFe 0.5 Cr 0.5 O 3
journal, September 2016
- Sharma, Mohit K.; Basu, Tathamay; Mukherjee, K.
- Journal of Physics: Condensed Matter, Vol. 28, Issue 42
Spin reorientation and metamagnetic transitions in perovskites ( , Dy, Ho, Er)
journal, October 2018
- Bolletta, Juan P.; Pomiro, Fernando; Sánchez, Rodolfo D.
- Physical Review B, Vol. 98, Issue 13
Effect of rare-earth (Er and Gd) substitution on the magnetic and multiferroic properties of DyFe0.5Cr0.5O3
text, January 2016
- Sharma, Mohit K.; Basu, Tathamay; Mukherjee, K.
- arXiv