Mesoporous xEr2O3·CoTiO3 composite oxide catalysts for low temperature dehydrogenation of ethylbenzene to styrene using CO2 as a soft oxidant

Yue, Yanfeng; Zhang, Li; Chen, Jihua; Hensley, Dale K.; Dai, Sheng; Overbury, Steven H.

doi:10.1039/C6RA04228G

Title: Mesoporous xEr₂O₃·CoTiO₃ composite oxide catalysts for low temperature dehydrogenation of ethylbenzene to styrene using CO₂ as a soft oxidant

Abstract

Here, a series of mesoporous xEr₂O₃·CoTiO₃ composite oxide catalysts have been prepared using a template method and tested as a new type of catalyst for the oxidative dehydrogenation of ethylbenzene to styrene by using CO₂ as a soft oxidant. Among the catalysts tested, the 0.25Er₂O₃·CoTiO₃ sample with a ratio of 1 : 4 : 4 content and calcined at 600 °C exhibited the highest ethylbenzene conversion (58%) and remarkable styrene selectivity (95%) at low temperature (450 °C).

Authors:

Yue, Yanfeng ^[1]; Zhang, Li ^[2]; Chen, Jihua ^[3]; Hensley, Dale K. ^[3]; Dai, Sheng ^[4]; Overbury, Steven H. ^[2]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Sul Ross State Univ., Alpine, TX (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

Publication Date:: Fri Jan 01 00:00:00 EST 2016

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1311228

Alternate Identifier(s):: OSTI ID: 1319230

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: RSC Advances

Additional Journal Information:: Journal Volume: 6; Journal Issue: 39; Journal ID: ISSN 2046-2069

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Yue, Yanfeng, Zhang, Li, Chen, Jihua, Hensley, Dale K., Dai, Sheng, and Overbury, Steven H. Mesoporous xEr2O3·CoTiO3 composite oxide catalysts for low temperature dehydrogenation of ethylbenzene to styrene using CO2 as a soft oxidant.  United States: N. p., 2016. 
Web.  doi:10.1039/C6RA04228G.

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                    Yue, Yanfeng, Zhang, Li, Chen, Jihua, Hensley, Dale K., Dai, Sheng, & Overbury, Steven H. Mesoporous xEr2O3·CoTiO3 composite oxide catalysts for low temperature dehydrogenation of ethylbenzene to styrene using CO2 as a soft oxidant.  United States.  https://doi.org/10.1039/C6RA04228G

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                    Yue, Yanfeng, Zhang, Li, Chen, Jihua, Hensley, Dale K., Dai, Sheng, and Overbury, Steven H. Fri .  
"Mesoporous xEr2O3·CoTiO3 composite oxide catalysts for low temperature dehydrogenation of ethylbenzene to styrene using CO2 as a soft oxidant".  United States.  https://doi.org/10.1039/C6RA04228G.  https://www.osti.gov/servlets/purl/1311228.

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@article{osti_1311228,

  title        = {Mesoporous xEr2O3·CoTiO3 composite oxide catalysts for low temperature dehydrogenation of ethylbenzene to styrene using CO2 as a soft oxidant},

  author       = {Yue, Yanfeng and Zhang, Li and Chen, Jihua and Hensley, Dale K. and Dai, Sheng and Overbury, Steven H.},

  abstractNote = {Here, a series of mesoporous xEr2O3·CoTiO3 composite oxide catalysts have been prepared using a template method and tested as a new type of catalyst for the oxidative dehydrogenation of ethylbenzene to styrene by using CO2 as a soft oxidant. Among the catalysts tested, the 0.25Er2O3·CoTiO3 sample with a ratio of 1 : 4 : 4 content and calcined at 600 °C exhibited the highest ethylbenzene conversion (58%) and remarkable styrene selectivity (95%) at low temperature (450 °C).},

  doi          = {10.1039/C6RA04228G},

  journal      = {RSC Advances},

  number       = 39,

  volume       = 6,

  place        = {United States},

  year         = {Fri Jan 01 00:00:00 EST 2016},

  month        = {Fri Jan 01 00:00:00 EST 2016}

}

Copy to clipboard

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Works referencing / citing this record:

Synthesis of hierarchically macro-mesoporous CoTiO ₃ with improved gas sensing properties
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Title: Mesoporous xEr2O3·CoTiO3 composite oxide catalysts for low temperature dehydrogenation of ethylbenzene to styrene using CO2 as a soft oxidant

Abstract

Citation Formats

Homogeneously Dispersed Ceria Nanocatalyst Stabilized with Ordered Mesoporous Alumina journal, February 2010

Catalytic oxidations with sulfur dioxide II. Alkylaromatics journal, May 1970

Effect of ceria on the structure and catalytic activity of V2O5/TiO2–ZrO2 for oxidehydrogenation of ethylbenzene to styrene utilizing CO2 as soft oxidant journal, September 2009

Mesostructured Ni-doped ceria as an efficient catalyst for styrene synthesis by oxidative dehydrogenation of ethylbenzene journal, October 2011

VOx supported SBA-15 catalysts for the oxidative dehydrogenation of ethylbenzene to styrene in the presence of N2O journal, May 2006

Iron Oxide Catalysts for Dehydrogenation of Ethylbenzene in the Presence of Steam journal, January 1974

Active phase in potassium-promoted iron oxide catalyst for dehydrogenation of ethylbenzene journal, January 1986

Hybridization of Au nanoparticle-loaded TiO2 with BN nanosheets for efficient solar-driven photocatalysis journal, January 2014

Selective conversion of ethylbenzene into styrene over K2O/TiO2-ZrO2 catalysts: Unified effects of K2O and CO2 journal, May 2007

Nonoxidative dehydrogenation of ethylbenzene over TiO2$z.sbnd;ZrO2 catalysts I. Effect of composition on surface properties and catalytic activities journal, October 1983

Role of carbon dioxide in the ethylbenzene dehydrogenation coupled with reverse water–gas shift journal, March 2004

Influence of SBA-15 support on CeO2–ZrO2 catalyst for the dehydrogenation of ethylbenzene to styrene with CO2 journal, January 2007

Oxidative dehydrogenation of ethylbenzene over vanadia-alumina catalysts in the presence of nitrous oxide: structure-activity relationship journal, March 2005

Dehydrogenation of ethylbenzene over potassium-promoted iron oxide containing cerium and molybdenum oxides journal, December 1986

Rational design of the carbon nanofiber catalysts for oxidative dehydrogenation of ethylbenzene journal, April 2007

Role Of CO 2 As a Soft Oxidant For Dehydrogenation of Ethylbenzene to Styrene over a High-Surface-Area Ceria Catalyst journal, October 2015

Studies of catalytic activity and coke deactivation of spinel oxides during ethylbenzene dehydrogenation journal, May 2009

A membrane reactor for the production of sytrene from ethylbenzene journal, December 1993

Mesostructured CeO2 as an Effective Catalyst for Styrene Synthesis by Oxidative Dehydrogenation of Ethylbenzene journal, October 2009

Kinetics of the dehydrogenation of ethylbenzene to styrene over unpromoted and K-promoted model iron oxide catalysts journal, January 1995

Defect-Site Promoted Surface Reorganization in Nanocrystalline Ceria for the Low-Temperature Activation of Ethylbenzene journal, March 2007

Structure and properties of the alumina-supported vanadia catalysts for ethylbenzene dehydrogenation in the presence of carbon dioxide journal, April 2006

Utilization of carbon dioxide as soft oxidant for oxydehydrogenation of ethylbenzene to styrene over V2O5–CeO2/TiO2–ZrO2 catalyst journal, April 2009

Mg–V–Al mixed oxides with mesoporous properties using layered double hydroxides as precursors: catalytic behavior for the process of ethylbenzene dehydrogenation to styrene under a carbon dioxide flow journal, August 2003

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Title: Mesoporous xEr₂O₃·CoTiO₃ composite oxide catalysts for low temperature dehydrogenation of ethylbenzene to styrene using CO₂ as a soft oxidant

Homogeneously Dispersed Ceria Nanocatalyst Stabilized with Ordered Mesoporous Alumina
journal, February 2010

Catalytic oxidations with sulfur dioxide II. Alkylaromatics
journal, May 1970

Effect of ceria on the structure and catalytic activity of V2O5/TiO2–ZrO2 for oxidehydrogenation of ethylbenzene to styrene utilizing CO2 as soft oxidant
journal, September 2009

Mesostructured Ni-doped ceria as an efficient catalyst for styrene synthesis by oxidative dehydrogenation of ethylbenzene
journal, October 2011

VOx supported SBA-15 catalysts for the oxidative dehydrogenation of ethylbenzene to styrene in the presence of N2O
journal, May 2006

Iron Oxide Catalysts for Dehydrogenation of Ethylbenzene in the Presence of Steam
journal, January 1974

Active phase in potassium-promoted iron oxide catalyst for dehydrogenation of ethylbenzene
journal, January 1986

Hybridization of Au nanoparticle-loaded TiO2 with BN nanosheets for efficient solar-driven photocatalysis
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Selective conversion of ethylbenzene into styrene over K2O/TiO2-ZrO2 catalysts: Unified effects of K2O and CO2
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Nonoxidative dehydrogenation of ethylbenzene over TiO2$z.sbnd;ZrO2 catalysts I. Effect of composition on surface properties and catalytic activities
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Role of carbon dioxide in the ethylbenzene dehydrogenation coupled with reverse water–gas shift
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Influence of SBA-15 support on CeO2–ZrO2 catalyst for the dehydrogenation of ethylbenzene to styrene with CO2
journal, January 2007

Oxidative dehydrogenation of ethylbenzene over vanadia-alumina catalysts in the presence of nitrous oxide: structure-activity relationship
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Dehydrogenation of ethylbenzene over potassium-promoted iron oxide containing cerium and molybdenum oxides
journal, December 1986

Rational design of the carbon nanofiber catalysts for oxidative dehydrogenation of ethylbenzene
journal, April 2007

Role Of CO ₂ As a Soft Oxidant For Dehydrogenation of Ethylbenzene to Styrene over a High-Surface-Area Ceria Catalyst
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A membrane reactor for the production of sytrene from ethylbenzene
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Mesostructured CeO2 as an Effective Catalyst for Styrene Synthesis by Oxidative Dehydrogenation of Ethylbenzene
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Kinetics of the dehydrogenation of ethylbenzene to styrene over unpromoted and K-promoted model iron oxide catalysts
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Defect-Site Promoted Surface Reorganization in Nanocrystalline Ceria for the Low-Temperature Activation of Ethylbenzene
journal, March 2007

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Utilization of carbon dioxide as soft oxidant for oxydehydrogenation of ethylbenzene to styrene over V2O5–CeO2/TiO2–ZrO2 catalyst
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