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Title: A POM–organic framework anode for Li-ion battery

Abstract

Rechargeable Li-ion batteries (LIBs) are currently the dominant power source for portable electronic devices and electric vehicles, and for small-scale stationary energy storage. However, one bottleneck of the anode materials for LIBs is the poor cycling performance caused by the fact that the anodes cannot maintain their integrity over several charge–discharge cycles. In this work, we demonstrate an approach to improving the cycling performance of lithium-ion battery anodes by constructing an extended 3D network of flexible redox active polyoxometalate (POM) clusters with redox active organic linkers, herein described as POMOF. In addition, this architecture enables the accommodation of large volume changes during cycling at relatively high current rates. For example, the POMOF anode exhibits a high reversible capacity of 540 mA h g–1 after 360 cycles at a current rate of 0.25C and a long cycle life at a current rate of 1.25C (>500 cycles).

Authors:
 [1];  [2];  [3];  [3];  [3];  [3];  [3];  [3];  [3];  [3];  [3];  [2];  [2]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Sul Ross State Univ., Alpine, TX (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1319223
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 3; Journal Issue: 45; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Yue, Yanfeng, Li, Yunchao, Bi, Zhonghe, Veith, Gabriel M., Bridges, Craig A., Guo, Bingkun, Chen, Jihua, Mullins, David R., Surwade, Sumedh P., Mahurin, Shannon M., Liu, Hongjun, Paranthaman, M. Parans, and Dai, Sheng. A POM–organic framework anode for Li-ion battery. United States: N. p., 2015. Web. doi:10.1039/C5TA06785E.
Yue, Yanfeng, Li, Yunchao, Bi, Zhonghe, Veith, Gabriel M., Bridges, Craig A., Guo, Bingkun, Chen, Jihua, Mullins, David R., Surwade, Sumedh P., Mahurin, Shannon M., Liu, Hongjun, Paranthaman, M. Parans, & Dai, Sheng. A POM–organic framework anode for Li-ion battery. United States. doi:10.1039/C5TA06785E.
Yue, Yanfeng, Li, Yunchao, Bi, Zhonghe, Veith, Gabriel M., Bridges, Craig A., Guo, Bingkun, Chen, Jihua, Mullins, David R., Surwade, Sumedh P., Mahurin, Shannon M., Liu, Hongjun, Paranthaman, M. Parans, and Dai, Sheng. Mon . "A POM–organic framework anode for Li-ion battery". United States. doi:10.1039/C5TA06785E. https://www.osti.gov/servlets/purl/1319223.
@article{osti_1319223,
title = {A POM–organic framework anode for Li-ion battery},
author = {Yue, Yanfeng and Li, Yunchao and Bi, Zhonghe and Veith, Gabriel M. and Bridges, Craig A. and Guo, Bingkun and Chen, Jihua and Mullins, David R. and Surwade, Sumedh P. and Mahurin, Shannon M. and Liu, Hongjun and Paranthaman, M. Parans and Dai, Sheng},
abstractNote = {Rechargeable Li-ion batteries (LIBs) are currently the dominant power source for portable electronic devices and electric vehicles, and for small-scale stationary energy storage. However, one bottleneck of the anode materials for LIBs is the poor cycling performance caused by the fact that the anodes cannot maintain their integrity over several charge–discharge cycles. In this work, we demonstrate an approach to improving the cycling performance of lithium-ion battery anodes by constructing an extended 3D network of flexible redox active polyoxometalate (POM) clusters with redox active organic linkers, herein described as POMOF. In addition, this architecture enables the accommodation of large volume changes during cycling at relatively high current rates. For example, the POMOF anode exhibits a high reversible capacity of 540 mA h g–1 after 360 cycles at a current rate of 0.25C and a long cycle life at a current rate of 1.25C (>500 cycles).},
doi = {10.1039/C5TA06785E},
journal = {Journal of Materials Chemistry. A},
number = 45,
volume = 3,
place = {United States},
year = {2015},
month = {10}
}

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Cited by: 12 works
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Works referenced in this record:

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005


Synthesis and Electrode Performance of Nanostructured V 2 O 5 by Using a Carbon Tube-in-Tube as a Nanoreactor and an Efficient Mixed-Conducting Network
journal, November 2008

  • Hu, Yong-Sheng; Liu, Xi; Müller, Jens-O.
  • Angewandte Chemie International Edition, Vol. 48, Issue 1
  • DOI: 10.1002/anie.200802988

Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

Influence of the Benzoquinone Sorption on the Structure and Electrochemical Performance of the MIL-53(Fe) Hybrid Porous Material in a Lithium-Ion Battery
journal, April 2009

  • de Combarieu, G.; Morcrette, M.; Millange, F.
  • Chemistry of Materials, Vol. 21, Issue 8
  • DOI: 10.1021/cm8032324

Metal–semiconductor interfacial reactions: Ni/Si system
journal, April 1981

  • Cheung, N. W.; Grunthaner, P. J.; Grunthaner, F. J.
  • Journal of Vacuum Science and Technology, Vol. 18, Issue 3
  • DOI: 10.1116/1.570994

Mixed Transition-Metal Oxides: Design, Synthesis, and Energy-Related Applications
journal, January 2014

  • Yuan, Changzhou; Wu, Hao Bin; Xie, Yi
  • Angewandte Chemie International Edition, Vol. 53, Issue 6
  • DOI: 10.1002/anie.201303971

Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors
journal, September 2012

  • Choi, Nam-Soon; Chen, Zonghai; Freunberger, Stefan A.
  • Angewandte Chemie International Edition, Vol. 51, Issue 40
  • DOI: 10.1002/anie.201201429

Synthesis and electrochemical performance of Li and Ni 1,4,5,8-naphthalenetetracarboxylates as anodes for Li-ion batteries
journal, November 2012


Examination of the Nickel Site Structure and Reaction Mechanism in Streptomyces seoulensis Superoxide Dismutase
journal, March 1999

  • Choudhury, Suranjan B.; Lee, Jin-Won; Davidson, Gerard
  • Biochemistry, Vol. 38, Issue 12
  • DOI: 10.1021/bi982537j

Raman spectroscopic studies of Ni–W oxide thin films
journal, March 2001


Selective Capture of Carbon Dioxide under Humid Conditions by Hydrophobic Chabazite-Type Zeolitic Imidazolate Frameworks
journal, July 2014

  • Nguyen, Nhung T. T.; Furukawa, Hiroyasu; Gándara, Felipe
  • Angewandte Chemie International Edition, Vol. 53, Issue 40
  • DOI: 10.1002/anie.201403980

Raman spectroscopy of carbon materials: structural basis of observed spectra
journal, September 1990

  • Wang, Yan; Alsmeyer, Daniel C.; McCreery, Richard L.
  • Chemistry of Materials, Vol. 2, Issue 5
  • DOI: 10.1021/cm00011a018

Conjugated dicarboxylate anodes for Li-ion batteries
journal, January 2009

  • Armand, M.; Grugeon, S.; Vezin, H.
  • Nature Materials, Vol. 8, Issue 2, p. 120-125
  • DOI: 10.1038/nmat2372

Crack Pattern Formation in Thin Film Lithium-Ion Battery Electrodes
journal, January 2011

  • Li, Juchuan; Dozier, Alan K.; Li, Yunchao
  • Journal of The Electrochemical Society, Vol. 158, Issue 6
  • DOI: 10.1149/1.3574027

Strain-Promoted “Click” Modification of a Mesoporous Metal–Organic Framework
journal, November 2012

  • Liu, Chong; Li, Tao; Rosi, Nathaniel L.
  • Journal of the American Chemical Society, Vol. 134, Issue 46
  • DOI: 10.1021/ja307713q

Luminescent Functional Metal–Organic Frameworks
journal, June 2011

  • Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong
  • Chemical Reviews, Vol. 112, Issue 2
  • DOI: 10.1021/cr200101d

X-ray spectroscopic studies of nickel complexes, with application to the structure of nickel sites in hydrogenases
journal, March 1991

  • Colpas, Gerard J.; Maroney, Michael J.; Bagyinka, Csaba.
  • Inorganic Chemistry, Vol. 30, Issue 5
  • DOI: 10.1021/ic00005a010

A block PCP crystal: anisotropic hybridization of porous coordination polymers by face-selective epitaxial growth
journal, January 2009

  • Furukawa, Shuhei; Hirai, Kenji; Takashima, Yohei
  • Chemical Communications, Issue 34
  • DOI: 10.1039/b909993j

Flexible (Breathing) Interpenetrated Metal−Organic Frameworks for CO 2 Separation Applications
journal, December 2008

  • Thallapally, Praveen K.; Tian, Jian; Radha Kishan, Motkuri
  • Journal of the American Chemical Society, Vol. 130, Issue 50
  • DOI: 10.1021/ja806391k

UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates
journal, February 1988

  • Rumelfanger, Robert; Asher, Sanford A.; Perry, Mildred B.
  • Applied Spectroscopy, Vol. 42, Issue 2
  • DOI: 10.1366/0003702884428365

Fe3O4 Nanoparticles Confined in Mesocellular Carbon Foam for High Performance Anode Materials for Lithium-Ion Batteries
journal, April 2011

  • Kang, Eunae; Jung, Yoon Seok; Cavanagh, Andrew S.
  • Advanced Functional Materials, Vol. 21, Issue 13
  • DOI: 10.1002/adfm.201002576

Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009

  • Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
  • DOI: 10.1039/b802426j

Zeolitic polyoxometalates metal organic frameworks (Z-POMOF) with imidazole ligands and ε-Keggin ions as building blocks; computational evaluation of hypothetical polymorphs and a synthesis approach
journal, January 2010

  • Rodriguez Albelo, L. Marleny; Ruiz-Salvador, A. Rabdel; Lewis, Dewi W.
  • Physical Chemistry Chemical Physics, Vol. 12, Issue 30
  • DOI: 10.1039/c004234j

Use of Polyoxometalate Catalysts in Ionic Liquids to Enhance the Dissolution and Delignification of Woody Biomass
journal, December 2010


Three-Dimensionally “Curved” NiO Nanomembranes as Ultrahigh Rate Capability Anodes for Li-Ion Batteries with Long Cycle Lifetimes
journal, October 2013

  • Sun, Xiaolei; Yan, Chenglin; Chen, Yao
  • Advanced Energy Materials, Vol. 4, Issue 4
  • DOI: 10.1002/aenm.201300912

XPS study of copper aluminate catalysts
journal, May 1980


Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000

  • Poizot, P.; Laruelle, S.; Grugeon, S.
  • Nature, Vol. 407, Issue 6803, p. 496-499
  • DOI: 10.1038/35035045

A 3d–4f heterometallic 3D POMOF based on lacunary Dawson polyoxometalates
journal, January 2013

  • Yu, Tingting; Ma, Huiyuan; Zhang, Chunjing
  • Dalton Transactions, Vol. 42, Issue 46
  • DOI: 10.1039/c3dt51983j

XAFS Study of Tungsten L 1 - and L 3 -Edges:  Structural Analysis of WO 3 Species Loaded on TiO 2 as a Catalyst for Photo-oxidation of NH 3
journal, May 2008

  • Yamazoe, Seiji; Hitomi, Yutaka; Shishido, Tetsuya
  • The Journal of Physical Chemistry C, Vol. 112, Issue 17
  • DOI: 10.1021/jp711250f

Reduction of the Irreversible Capacity in Hard-Carbon Anode Materials Prepared from Sucrose for Li-Ion Batteries
journal, January 1998

  • Buiel, Edward
  • Journal of The Electrochemical Society, Vol. 145, Issue 6
  • DOI: 10.1149/1.1838585

Polyoxoniobate chemistry in the 21st century
journal, January 2011


Designed Synthesis of POM–Organic Frameworks from {Ni 6 PW 9 } Building Blocks under Hydrothermal Conditions
journal, May 2008

  • Zheng, Shou-Tian; Zhang, Jie; Yang, Guo-Yu
  • Angewandte Chemie International Edition, Vol. 47, Issue 21
  • DOI: 10.1002/anie.200705709

Diamondoid-Structured Cu-Dicarboxylate-based Metal-Organic Frameworks as High-Capacity Anodes for Lithium-Ion Storage
journal, October 2014

  • Senthil Kumar, R.; Nithya, C.; Gopukumar, S.
  • Energy Technology, Vol. 2, Issue 11
  • DOI: 10.1002/ente.201402076

Polyoxometalate-Based Molecular Materials
journal, February 1998

  • Coronado, Eugenio; Gómez-García, Carlos J.
  • Chemical Reviews, Vol. 98, Issue 1
  • DOI: 10.1021/cr970471c

Mimicking Zeolite to Its Core: Porous Sodalite Cages as Hangers for Pendant Trimeric M 3 (OH) Clusters (M = Mg, Mn, Co, Ni, Cd)
journal, January 2012

  • Zheng, Shou-Tian; Wu, Tao; Zuo, Fan
  • Journal of the American Chemical Society, Vol. 134, Issue 4
  • DOI: 10.1021/ja209800x

From Molecules to Crystal Engineering:  Supramolecular Isomerism and Polymorphism in Network Solids
journal, June 2001

  • Moulton, Brian; Zaworotko, Michael J.
  • Chemical Reviews, Vol. 101, Issue 6
  • DOI: 10.1021/cr9900432

Lithium storage in a metal organic framework with diamondoid topology – a case study on metal formates
journal, January 2010

  • Saravanan, Kuppan; Nagarathinam, Mangayarkarasi; Balaya, Palani
  • Journal of Materials Chemistry, Vol. 20, Issue 38
  • DOI: 10.1039/c0jm01671c

Lewis Acid–Base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries
journal, April 2014

  • Zheng, Jianming; Tian, Jian; Wu, Dangxin
  • Nano Letters, Vol. 14, Issue 5
  • DOI: 10.1021/nl404721h

Synthesis and electrochemical properties of substituted heteropoly acid with Dawson structure H7[In(H2O)P2W17O61]·23H2O
journal, January 2012

  • Qian, Xueyu; Tong, Xia; Wu, Qingyin
  • Dalton Transactions, Vol. 41, Issue 33
  • DOI: 10.1039/c2dt30467h

Highly Stable Crystalline Catalysts Based on a Microporous Metal−Organic Framework and Polyoxometalates
journal, February 2009

  • Sun, Chun-Yan; Liu, Shu-Xia; Liang, Da-Dong
  • Journal of the American Chemical Society, Vol. 131, Issue 5
  • DOI: 10.1021/ja807357r

Fabrication of Graphene-Encapsulated Oxide Nanoparticles: Towards High-Performance Anode Materials for Lithium Storage
journal, September 2010

  • Yang, Shubin; Feng, Xinliang; Ivanovici, Sorin
  • Angewandte Chemie International Edition, Vol. 49, Issue 45, p. 8408-8411
  • DOI: 10.1002/anie.201003485

Plastic Crystal Electrolyte Materials: New Perspectives on Solid State Ionics
journal, July 2001


Designing Higher Surface Area Metal–Organic Frameworks: Are Triple Bonds Better Than Phenyls?
journal, June 2012

  • Farha, Omar K.; Wilmer, Christopher E.; Eryazici, Ibrahim
  • Journal of the American Chemical Society, Vol. 134, Issue 24
  • DOI: 10.1021/ja302623w

Template-Free Synthesis of Hierarchical Porous Metal–Organic Frameworks
journal, June 2013

  • Yue, Yanfeng; Qiao, Zhen-An; Fulvio, Pasquale F.
  • Journal of the American Chemical Society, Vol. 135, Issue 26
  • DOI: 10.1021/ja402694f

Highly Reversible Lithium Storage in Spheroidal Carbon-Coated Silicon Nanocomposites as Anodes for Lithium-Ion Batteries
journal, October 2006

  • Ng, See-How; Wang, Jiazhao; Wexler, David
  • Angewandte Chemie International Edition, Vol. 45, Issue 41, p. 6896-6899
  • DOI: 10.1002/anie.200601676

1,2,4-Triazolium perfluorobutanesulfonate as an archetypal pure protic organic ionic plastic crystal electrolyte for all-solid-state fuel cells
journal, January 2015

  • Luo, Jiangshui; Jensen, Annemette H.; Brooks, Neil R.
  • Energy & Environmental Science, Vol. 8, Issue 4
  • DOI: 10.1039/C4EE02280G

Polymer-Supported and Free-Standing Metal-Organic Framework Membrane
journal, July 2012

  • Ben, Teng; Lu, Chunjing; Pei, Cuiying
  • Chemistry - A European Journal, Vol. 18, Issue 33
  • DOI: 10.1002/chem.201201574

New types of hybrid solids of tetravanadate polyanions and cucurbituril
journal, January 2012

  • Han, Li-Wei; Lin, Jing-Xiang; Lü, Jian
  • Dalton Transactions, Vol. 41, Issue 33
  • DOI: 10.1039/c2dt30559c

Amorphous Hierarchical Porous GeO x as High-Capacity Anodes for Li Ion Batteries with Very Long Cycling Life
journal, December 2011

  • Wang, Xiao-Liang; Han, Wei-Qiang; Chen, Haiyan
  • Journal of the American Chemical Society, Vol. 133, Issue 51
  • DOI: 10.1021/ja208880f

Hollow Carbon-Nanotube/Carbon-Nanofiber Hybrid Anodes for Li-Ion Batteries
journal, October 2013

  • Chen, Yuming; Li, Xiaoyan; Park, Kyusung
  • Journal of the American Chemical Society, Vol. 135, Issue 44
  • DOI: 10.1021/ja408421n

Zeolitic Polyoxometalate-Based Metal−Organic Frameworks (Z-POMOFs): Computational Evaluation of Hypothetical Polymorphs and the Successful Targeted Synthesis of the Redox-Active Z-POMOF1
journal, November 2009

  • Marleny Rodriguez-Albelo, L.; Ruiz-Salvador, A. Rabdel; Sampieri, Alvaro
  • Journal of the American Chemical Society, Vol. 131, Issue 44
  • DOI: 10.1021/ja905009e

Enhanced Lithium Ion Battery Cycling of Silicon Nanowire Anodes by Template Growth to Eliminate Silicon Underlayer Islands
journal, October 2013

  • Cho, Jeong-Hyun; Picraux, S. Tom
  • Nano Letters, Vol. 13, Issue 11
  • DOI: 10.1021/nl4036498

Metal organic frameworks for electrochemical applications
journal, January 2012

  • Morozan, Adina; Jaouen, Frédéric
  • Energy & Environmental Science, Vol. 5, Issue 11
  • DOI: 10.1039/c2ee22989g

Immobilization of MP-11 into a Mesoporous Metal–Organic Framework, MP-11@mesoMOF: A New Platform for Enzymatic Catalysis
journal, July 2011

  • Lykourinou, Vasiliki; Chen, Yao; Wang, Xi-Sen
  • Journal of the American Chemical Society, Vol. 133, Issue 27
  • DOI: 10.1021/ja2038003

Unraveling the storage mechanism in organic carbonyl electrodes for sodium-ion batteries
journal, September 2015


Metal–organic frameworks as platforms for clean energy
journal, January 2013

  • Li, Shun-Li; Xu, Qiang
  • Energy & Environmental Science, Vol. 6, Issue 6
  • DOI: 10.1039/c3ee40507a

Mesoporous silicon sponge as an anti-pulverization structure for high-performance lithium-ion battery anodes
journal, July 2014

  • Li, Xiaolin; Gu, Meng; Hu, Shenyang
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5105

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    A photochromic zinc-based coordination polymer for a Li-ion battery anode with high capacity and stable cycling stability
    journal, January 2018

    • Xia, Shu-Biao; Li, Fu-Shao; Shen, Xiang
    • Dalton Transactions, Vol. 47, Issue 37
    • DOI: 10.1039/c8dt02930j

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    journal, July 2018

    • Lin, Chia-Ching; Lin, Wei-Hsiang; Huang, Shao-Chu
    • Advanced Materials Interfaces, Vol. 5, Issue 15
    • DOI: 10.1002/admi.201800491

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    journal, January 2017

    • Zhu, Pei-Pei; Sheng, Ning; Li, Meng-Ting
    • Journal of Materials Chemistry A, Vol. 5, Issue 34
    • DOI: 10.1039/c7ta05254e

    Diamondoid-structured polymolybdate-based metal–organic frameworks as high-capacity anodes for lithium-ion batteries
    journal, January 2017

    • Wang, Yuan-Yuan; Zhang, Mi; Li, Shun-Li
    • Chemical Communications, Vol. 53, Issue 37
    • DOI: 10.1039/c6cc10208e

    A highly stable polyoxometalate-based metal–organic framework with π–π stacking for enhancing lithium ion battery performance
    journal, January 2017

    • Huang, Qing; Wei, Tao; Zhang, Mi
    • Journal of Materials Chemistry A, Vol. 5, Issue 18
    • DOI: 10.1039/c7ta00900c

    Heightened Integration of POM‐based Metal–Organic Frameworks with Functionalized Single‐Walled Carbon Nanotubes for Superior Energy Storage
    journal, August 2019

    • Li, Xiao; Zhou, Kun‐Feng; Tong, Zhi‐Bo
    • Chemistry – An Asian Journal, Vol. 14, Issue 19
    • DOI: 10.1002/asia.201901143

    Reactions of [Ru(NO)Cl 5 ] 2− with pseudotrilacunary {XW 9 O 33 } 9− (X = As III , Sb III ) anions
    journal, January 2019

    • Mukhacheva, Anna A.; Shmakova, Alexandra A.; Volchek, Victoria V.
    • Dalton Transactions, Vol. 48, Issue 42
    • DOI: 10.1039/c9dt03328a

    Mechanism of Sodium Ion Storage in Na 7 [H 2 PV 14 O 42 ] Anode for Sodium-Ion Batteries
    journal, July 2018

    • Lin, Chia-Ching; Lin, Wei-Hsiang; Huang, Shao-Chu
    • Advanced Materials Interfaces, Vol. 5, Issue 15
    • DOI: 10.1002/admi.201800491

    Heightened Integration of POM‐based Metal–Organic Frameworks with Functionalized Single‐Walled Carbon Nanotubes for Superior Energy Storage
    journal, August 2019

    • Li, Xiao; Zhou, Kun‐Feng; Tong, Zhi‐Bo
    • Chemistry – An Asian Journal, Vol. 14, Issue 19
    • DOI: 10.1002/asia.201901143

    Diamondoid-structured polymolybdate-based metal–organic frameworks as high-capacity anodes for lithium-ion batteries
    journal, January 2017

    • Wang, Yuan-Yuan; Zhang, Mi; Li, Shun-Li
    • Chemical Communications, Vol. 53, Issue 37
    • DOI: 10.1039/c6cc10208e

    A highly stable polyoxometalate-based metal–organic framework with π–π stacking for enhancing lithium ion battery performance
    journal, January 2017

    • Huang, Qing; Wei, Tao; Zhang, Mi
    • Journal of Materials Chemistry A, Vol. 5, Issue 18
    • DOI: 10.1039/c7ta00900c

    Fabrication and electrochemical performance of unprecedented POM-based metal–carbene frameworks
    journal, January 2017

    • Zhu, Pei-Pei; Sheng, Ning; Li, Meng-Ting
    • Journal of Materials Chemistry A, Vol. 5, Issue 34
    • DOI: 10.1039/c7ta05254e

    A photochromic zinc-based coordination polymer for a Li-ion battery anode with high capacity and stable cycling stability
    journal, January 2018

    • Xia, Shu-Biao; Li, Fu-Shao; Shen, Xiang
    • Dalton Transactions, Vol. 47, Issue 37
    • DOI: 10.1039/c8dt02930j

    Reactions of [Ru(NO)Cl 5 ] 2− with pseudotrilacunary {XW 9 O 33 } 9− (X = As III , Sb III ) anions
    journal, January 2019

    • Mukhacheva, Anna A.; Shmakova, Alexandra A.; Volchek, Victoria V.
    • Dalton Transactions, Vol. 48, Issue 42
    • DOI: 10.1039/c9dt03328a

    Metal-organic framework functionalization and design strategies for advanced electrochemical energy storage devices
    journal, July 2019


    Phosphorus anionic redox activity revealed by operando P K-edge X-ray absorption spectroscopy on diphosphonate-based conversion materials in Li-ion batteries
    journal, January 2018

    • Schmidt, Sebastian; Sallard, Sébastien; Borca, Camelia
    • Chemical Communications, Vol. 54, Issue 39
    • DOI: 10.1039/c8cc01350k

    An inorganic–organic hybrid supramolecular framework as a high-performance anode for lithium-ion batteries
    journal, January 2018

    • Xia, Shubiao; Li, Fushao; Li, Xue
    • Dalton Transactions, Vol. 47, Issue 15
    • DOI: 10.1039/c8dt00335a

    Encapsulating ionic liquids into POM-based MOFs to improve their conductivity for superior lithium storage
    journal, January 2018

    • Zhang, Mi; Zhang, A-Man; Wang, Xiao-Xiao
    • Journal of Materials Chemistry A, Vol. 6, Issue 18
    • DOI: 10.1039/c8ta01062e

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    journal, January 2019

    • Wu, Zhenzhen; Xie, Jian; Xu, Zhichuan J.
    • Journal of Materials Chemistry A, Vol. 7, Issue 9
    • DOI: 10.1039/c8ta11994e

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    journal, January 2019

    • Meng, Xing; Wang, Hai-Ning; Zou, Yan-Hong
    • Dalton Transactions, Vol. 48, Issue 28
    • DOI: 10.1039/c9dt01750j

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    journal, January 2017

    • Li, Yunchao; Adams, Ryan A.; Arora, Anjela
    • Journal of The Electrochemical Society, Vol. 164, Issue 6
    • DOI: 10.1149/2.1391706jes