Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides

Johnstone, Erik V.; Poineau, Frederic; Forster, Paul M.; Ma, Longzou; Hartmann, Thomas; Cornelius, Andrew; Antonio, Daniel; Sattelberger, Alfred P.; Czerwinski, Kenneth R.

doi:10.1021/ic301011c

Title: Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides

Abstract

Technetium (Tc) is the lightest element that doesn't occur in nature. At UNLV, our radiochemistry program gives us access to Tc and the ability to make various Tc compounds. Here we describe the preparation and characterization of TcCl₄. The Tc atom is found to have a magnetic moment and magnetically orders at low temperature. As discerning trends in the transition metals, of which Tc is one, is important for understanding all transition metal compounds, this research is relevant to understanding these materials.

Authors:

Johnstone, Erik V. ^[1]; Poineau, Frederic ^[1]; Forster, Paul M. ^[1]; Ma, Longzou ^[2]; Hartmann, Thomas ^[2]; Cornelius, Andrew ^[3]; Antonio, Daniel ^[3]; Sattelberger, Alfred P. ^[4]; Czerwinski, Kenneth R. ^[1]

Univ. of Nevada, Las Vegas, NV (United States). Dept. of Chemistry
Univ. of Nevada, Las Vegas, NV (United States). Harry Reid Center for Environmental Studies
Univ. of Nevada, Las Vegas, NV (United States). Dept. of Physics and Astronomy
Univ. of Nevada, Las Vegas, NV (United States). Dept. of Chemistry; Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Mon Jul 09 00:00:00 EDT 2012

Research Org.:: Univ. of Nevada, Las Vegas, NV (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1307429

Report Number(s):: DOE-UNLV-05278
Journal ID: ISSN 0020-1669

Grant/Contract Number:: SC0005278; 47824B

Resource Type:: Accepted Manuscript

Journal Name:: Inorganic Chemistry

Additional Journal Information:: Journal Volume: 51; Journal Issue: 15; Journal ID: ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Technetium, Magnetism, Transition Metal

Citation Formats


                    Johnstone, Erik V., Poineau, Frederic, Forster, Paul M., Ma, Longzou, Hartmann, Thomas, Cornelius, Andrew, Antonio, Daniel, Sattelberger, Alfred P., and Czerwinski, Kenneth R. Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides.  United States: N. p., 2012. 
Web.  doi:10.1021/ic301011c.

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                    Johnstone, Erik V., Poineau, Frederic, Forster, Paul M., Ma, Longzou, Hartmann, Thomas, Cornelius, Andrew, Antonio, Daniel, Sattelberger, Alfred P., & Czerwinski, Kenneth R. Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides.  United States.  https://doi.org/10.1021/ic301011c

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                    Johnstone, Erik V., Poineau, Frederic, Forster, Paul M., Ma, Longzou, Hartmann, Thomas, Cornelius, Andrew, Antonio, Daniel, Sattelberger, Alfred P., and Czerwinski, Kenneth R. Mon .  
"Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides".  United States.  https://doi.org/10.1021/ic301011c.  https://www.osti.gov/servlets/purl/1307429.

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@article{osti_1307429,

  title        = {Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides},

  author       = {Johnstone, Erik V. and Poineau, Frederic and Forster, Paul M. and Ma, Longzou and Hartmann, Thomas and Cornelius, Andrew and Antonio, Daniel and Sattelberger, Alfred P. and Czerwinski, Kenneth R.},

  abstractNote = {Technetium (Tc) is the lightest element that doesn't occur in nature. At UNLV, our radiochemistry program gives us access to Tc and the ability to make various Tc compounds. Here we describe the preparation and characterization of TcCl4. The Tc atom is found to have a magnetic moment and magnetically orders at low temperature. As discerning trends in the transition metals, of which Tc is one, is important for understanding all transition metal compounds, this research is relevant to understanding these materials.},

  doi          = {10.1021/ic301011c},

  journal      = {Inorganic Chemistry},

  number       = 15,

  volume       = 51,

  place        = {United States},

  year         = {Mon Jul 09 00:00:00 EDT 2012},

  month        = {Mon Jul 09 00:00:00 EDT 2012}

}

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https://doi.org/10.1021/ic301011c

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Works referenced in this record:

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Works referencing / citing this record:

From Tc ^VII to Tc ^I ; facile syntheses of bis-arene complexes [ ^99(m) Tc(arene) ₂ ] ⁺ from pertechnetate
journal, January 2015

Benz, Michael; Braband, Henrik; Schmutz, Paul
Chemical Science, Vol. 6, Issue 1
DOI: 10.1039/c4sc02461c

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Similar Records

Title: Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides

Abstract

Citation Formats

Preparation of the Binary Technetium Bromides: TcBr 3 and TcBr 4 journal, December 2008

Technetium: Chemistry and Radiopharmaceutical Applications book, February 2000

Chemistry of rhenium(IV) chloride. II. Structure of one of the polymorps (.beta.) and evidence for a new polymorph (.gamma.) journal, February 1973

Room temperature preparations of second and third transition series tetrafluorides and a possible novel structure type for OsF4 and RhF4 journal, December 2001

γ-Rhenium(IV) chloride, dirhenium octachloride-hexachloropropene, rhenium(IV) bromide journal, April 1972

Chemistry of Rhenium and Technetium. I. Synthesis of ReCl 5 , TcCl 4 and Related Compounds journal, July 1957

Technetium Chlorides journal, March 1962

Magnetic Evidence for Trinuclear Clusters in Rhenium(IV) Chloride journal, January 1965

The Crystal Structure of Technetium (IV) Chloride. A New AB 4 Structure journal, July 1966

Technetium(IV) Halides Predicted from First-Principles journal, June 2009

Chemistry of Rhenium and Technetium. II. Magnetic Susceptibilities of ReCl 5 , ReCl 3 , TcCl 4 and MoCl 5 journal, January 1959

Technetium Tetrachloride as A Precursor for Small Technetium(IV) Complexes journal, August 2006

405. Iodides of osmium and rhenium journal, January 1962

Binary halides of platinum: Preparations, thermal decomposition and structural results journal, October 1975

Technetium Dichloride: A New Binary Halide Containing Metal–Metal Multiple Bonds journal, June 2011

Synthesis and Structure of Technetium Trichloride journal, November 2010

β-Technetium Trichloride: Formation, Structure, and First-Principles Calculations journal, April 2012

A short history of SHELX journal, December 2007

Technetium Chlorides and Oxochlorides journal, June 1972

über das Osmium, seine analytische Bestimmung, seine Oxyde und seine Chloride journal, February 1910

Über das Beständigkeitsgebiet von vier wasserfreien Platinchloriden, über die Flüchtigkeit des Metalls im Chlorgas und die Darstellung sauerstoff-freien Chlors journal, April 1913

Preparation of trichloride and tetrachloride of molybdenum journal, September 1959

.alpha.-Molybdenum tetrachloride. A structural isomer containing molybdenum-molybdenum interactions journal, October 1968

The Preparation and Reactions of Some Tungsten(II) and Tungsten (IV) Halides journal, September 1964

Rheniumpentachlorid journal, October 1933

Preparation of β-rhenium tetrachloride journal, March 1969

A new preparation of rhenium(IV) chloride journal, January 1971

Anhydrous Ruthenium Chlorides journal, September 1963

Crystal structure of platinum tetrachloride journal, January 1972

The Crystal Structure of Zirconium(IV) Chloride: A New AB4-type Structure journal, February 1969

Structure of the high-temperature form of osmium(IV) chloride journal, August 1977

Hexameres Molybdäntetrachlorid journal, August 1981

Crystal structure of niobium tetrachloride journal, March 1977

808. Technetium. Part I. The preparation and properties of potassium hexahalogenotechnetates journal, January 1958

602. The magnetic properties of some d 3-complexes journal, January 1961

A new isomer of molybdenum(IV) chloride journal, January 1977

Synthesis of Molybdenum Tetrachloride journal, February 1964

From Tc VII to Tc I ; facile syntheses of bis-arene complexes [ 99(m) Tc(arene) 2 ] + from pertechnetate journal, January 2015

Preparation of the Binary Technetium Bromides: TcBr ₃ and TcBr ₄
journal, December 2008

Technetium: Chemistry and Radiopharmaceutical Applications
book, February 2000

Chemistry of rhenium(IV) chloride. II. Structure of one of the polymorps (.beta.) and evidence for a new polymorph (.gamma.)
journal, February 1973

Room temperature preparations of second and third transition series tetrafluorides and a possible novel structure type for OsF4 and RhF4
journal, December 2001

γ-Rhenium(IV) chloride, dirhenium octachloride-hexachloropropene, rhenium(IV) bromide
journal, April 1972

Chemistry of Rhenium and Technetium. I. Synthesis of ReCl ₅ , TcCl ₄ and Related Compounds
journal, July 1957

Technetium Chlorides
journal, March 1962

Magnetic Evidence for Trinuclear Clusters in Rhenium(IV) Chloride
journal, January 1965

The Crystal Structure of Technetium (IV) Chloride. A New AB ₄ Structure
journal, July 1966

Technetium(IV) Halides Predicted from First-Principles
journal, June 2009

Chemistry of Rhenium and Technetium. II. Magnetic Susceptibilities of ReCl ₅ , ReCl ₃ , TcCl ₄ and MoCl ₅
journal, January 1959

Technetium Tetrachloride as A Precursor for Small Technetium(IV) Complexes
journal, August 2006

405. Iodides of osmium and rhenium
journal, January 1962

Binary halides of platinum: Preparations, thermal decomposition and structural results
journal, October 1975

Technetium Dichloride: A New Binary Halide Containing Metal–Metal Multiple Bonds
journal, June 2011

Synthesis and Structure of Technetium Trichloride
journal, November 2010

β-Technetium Trichloride: Formation, Structure, and First-Principles Calculations
journal, April 2012

A short history of SHELX
journal, December 2007

Technetium Chlorides and Oxochlorides
journal, June 1972

über das Osmium, seine analytische Bestimmung, seine Oxyde und seine Chloride
journal, February 1910

Über das Beständigkeitsgebiet von vier wasserfreien Platinchloriden, über die Flüchtigkeit des Metalls im Chlorgas und die Darstellung sauerstoff-freien Chlors
journal, April 1913

Preparation of trichloride and tetrachloride of molybdenum
journal, September 1959

.alpha.-Molybdenum tetrachloride. A structural isomer containing molybdenum-molybdenum interactions
journal, October 1968

The Preparation and Reactions of Some Tungsten(II) and Tungsten (IV) Halides
journal, September 1964

Rheniumpentachlorid
journal, October 1933

Preparation of β-rhenium tetrachloride
journal, March 1969

A new preparation of rhenium(IV) chloride
journal, January 1971

Anhydrous Ruthenium Chlorides
journal, September 1963

Crystal structure of platinum tetrachloride
journal, January 1972

The Crystal Structure of Zirconium(IV) Chloride: A New AB4-type Structure
journal, February 1969

Structure of the high-temperature form of osmium(IV) chloride
journal, August 1977

Hexameres Molybdäntetrachlorid
journal, August 1981

Crystal structure of niobium tetrachloride
journal, March 1977

808. Technetium. Part I. The preparation and properties of potassium hexahalogenotechnetates
journal, January 1958

602. The magnetic properties of some d 3-complexes
journal, January 1961

A new isomer of molybdenum(IV) chloride
journal, January 1977

Synthesis of Molybdenum Tetrachloride
journal, February 1964

From Tc ^VII to Tc ^I ; facile syntheses of bis-arene complexes [ ^99(m) Tc(arene) ₂ ] ⁺ from pertechnetate
journal, January 2015