Neptunium and plutonium complexes with a sterically encumbered triamidoamine (TREN) scaffold
Abstract
Here, the syntheses and characterization of isostructural neptunium(IV) and plutonium(IV) complexes [MIV(TRENTIPS)(Cl)] [An = Np, Pu; TRENTIPS = {N(CH2CH2NSiPri3)3}3] are reported, along with the demonstration that they are likely reduced to the corresponding neptunium(III) and plutonium(III) products [MIII(TRENTIPS)]; this chemistry provides new platforms from which to target a plethora of unprecedented molecular functionalities in transuranic chemistry and the neptunium(IV) molecule is the first structurally characterized neptunium(IV)–amide complex.
- Authors:
-
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- The Univ. of Manchester, Manchester (United Kingdom)
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1304834
- Report Number(s):
- LA-UR-16-21047
Journal ID: ISSN 1359-7345; CHCOFS
- Grant/Contract Number:
- AC52-06NA25396
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 52; Journal Issue: 31; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Brown, Jessie L., Gaunt, Andrew J., King, David M., Liddle, Stephen T., Reilly, Sean D., Scott, Brian L., and Wooles, Ashley J. Neptunium and plutonium complexes with a sterically encumbered triamidoamine (TREN) scaffold. United States: N. p., 2016.
Web. doi:10.1039/C6CC01656A.
Brown, Jessie L., Gaunt, Andrew J., King, David M., Liddle, Stephen T., Reilly, Sean D., Scott, Brian L., & Wooles, Ashley J. Neptunium and plutonium complexes with a sterically encumbered triamidoamine (TREN) scaffold. United States. https://doi.org/10.1039/C6CC01656A
Brown, Jessie L., Gaunt, Andrew J., King, David M., Liddle, Stephen T., Reilly, Sean D., Scott, Brian L., and Wooles, Ashley J. Fri .
"Neptunium and plutonium complexes with a sterically encumbered triamidoamine (TREN) scaffold". United States. https://doi.org/10.1039/C6CC01656A. https://www.osti.gov/servlets/purl/1304834.
@article{osti_1304834,
title = {Neptunium and plutonium complexes with a sterically encumbered triamidoamine (TREN) scaffold},
author = {Brown, Jessie L. and Gaunt, Andrew J. and King, David M. and Liddle, Stephen T. and Reilly, Sean D. and Scott, Brian L. and Wooles, Ashley J.},
abstractNote = {Here, the syntheses and characterization of isostructural neptunium(IV) and plutonium(IV) complexes [MIV(TRENTIPS)(Cl)] [An = Np, Pu; TRENTIPS = {N(CH2CH2NSiPri3)3}3] are reported, along with the demonstration that they are likely reduced to the corresponding neptunium(III) and plutonium(III) products [MIII(TRENTIPS)]; this chemistry provides new platforms from which to target a plethora of unprecedented molecular functionalities in transuranic chemistry and the neptunium(IV) molecule is the first structurally characterized neptunium(IV)–amide complex.},
doi = {10.1039/C6CC01656A},
journal = {ChemComm},
number = 31,
volume = 52,
place = {United States},
year = {Fri Mar 11 00:00:00 EST 2016},
month = {Fri Mar 11 00:00:00 EST 2016}
}
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Works referencing / citing this record:
Enantiomerically Pure Tetravalent Neptunium Amidinates: Synthesis and Characterization
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