Promotional Effects of In on Non-Oxidative Methane Transformation Over Mo-ZSM-5
In this paper, we present a new class of catalysts, InMo-ZSM-5, which can be prepared by indium impregnation of Mo-ZSM-5. The incorporation of indium dramatically decreases coke formation during methane dehydroaromatization. The benzene and C2 hydrocarbons selectivity among total hydrocarbons over InMo-ZSM-5 remains comparable to that of Mo-ZSM-5 despite reduced methane conversion due to decreased coke formation. We found 1 wt% indium to be optimal loading for reducing coke selectivity to half that of Mo-ZSM-5. Characterization methods were not helpful in discerning the interaction of In with Mo but experiments with bimetallic 1In2Mo-ZSM-5 and mechanical mixture 1In+2Mo-ZSM-5 suggest that In and Mo need to be in close proximity to suppress coke formation. Finally, this is supported by temperature programmed reduction experiments which show that In incorporation leads to lower Mo reduction temperature in In2Mo-ZMS-5.
- Authors:
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[1]
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; [1]
; [1]
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- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Publication Date:
- Grant/Contract Number:
- AC05-00OR22725
- Type:
- Accepted Manuscript
- Journal Name:
- Catalysis Letters
- Additional Journal Information:
- Journal Name: Catalysis Letters; Journal ID: ISSN 1011-372X
- Publisher:
- Springer
- Research Org:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org:
- USDOE
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; methane to benzene; methane dehydroaromatization; coking suppression; heterobimetallic zeolites; InMo-ZSM-5
- OSTI Identifier:
- 1302883
- Free Publicly Accessible Full Text
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Accepted Manuscript (DOE)
- Publisher's Version of Record
- https://doi.org/10.1007/s10562-016-1831-5