Promotional Effects of In on Non-Oxidative Methane Transformation Over Mo-ZSM-5

Zhang, Yang; Kidder, Michelle; Ruther, Rose E.; Nanda, Jagjit; Foo, Guo Shiou; Wu, Zili; Narula, Chaitanya K.

doi:10.1007/s10562-016-1831-5

Title: Promotional Effects of In on Non-Oxidative Methane Transformation Over Mo-ZSM-5

Journal Article · 15 August 2016 · Catalysis Letters

DOI: https://doi.org/10.1007/s10562-016-1831-5 · OSTI ID:1302883

Zhang, Yang ^[1]; Kidder, Michelle ^[2]; Ruther, Rose E. ^[1]; Nanda, Jagjit ^[1]; Foo, Guo Shiou ^[2]; Wu, Zili ^[2]; Narula, Chaitanya K. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

In this paper, we present a new class of catalysts, InMo-ZSM-₅, which can be prepared by indium impregnation of Mo-ZSM-₅. The incorporation of indium dramatically decreases coke formation during methane dehydroaromatization. The benzene and C₂ hydrocarbons selectivity among total hydrocarbons over InMo-ZSM-₅ remains comparable to that of Mo-ZSM-₅ despite reduced methane conversion due to decreased coke formation. We found 1 wt% indium to be optimal loading for reducing coke selectivity to half that of Mo-ZSM-₅. Characterization methods were not helpful in discerning the interaction of In with Mo but experiments with bimetallic 1In2Mo-ZSM-₅ and mechanical mixture 1In+2Mo-ZSM-₅ suggest that In and Mo need to be in close proximity to suppress coke formation. Finally, this is supported by temperature programmed reduction experiments which show that In incorporation leads to lower Mo reduction temperature in In2Mo-ZMS-₅.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1302883

Journal Information:: Catalysis Letters, Journal Name: Catalysis Letters; ISSN 1011-372X

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Polyoxometalates as alternative Mo precursors for methane dehydroaromatization on Mo/ZSM-5 and Mo/MCM-22 catalysts Julian, Ignacio; Hueso, José L.; Lara, Nidya Catalysis Science & Technology, Vol. 9, Issue 21 https://doi.org/10.1039/c9cy01490j	journal	January 2019

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InMo-ZSM-5

Title: Promotional Effects of In on Non-Oxidative Methane Transformation Over Mo-ZSM-5

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