The uranium from seawater program at PNNL: Overview of marine testing, adsorbent characterization, adsorbent durability, adsorbent toxicity, and deployment studies
Abstract
The Pacific Northwest National Laboratory's (PNNL) Marine Science Laboratory (MSL) located along the coast of Washington State is evaluating the performance of uranium adsorption materials being developed for seawater extraction under realistic marine conditions with natural seawater. Two types of exposure systems were employed in this program: flow-through columns for testing of fixed beds of individual fibers and pellets and a recirculating water flume for testing of braided adsorbent material. Testing consists of measurements of the adsorption of uranium and other elements from seawater as a function of time, typically 42 to 56 day exposures, to determine the adsorbent capacity and adsorption rate (kinetics). Analysis of uranium and other trace elements collected by the adsorbents was conducted following strong acid digestion of the adsorbent with 50% aqua regia using either Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) or Inductively Coupled Plasma Mass Spectrometer (ICP-MS). The ORNL 38H adsorbent had a 56 day adsorption capacity of 3.30 ± 0.68 g U/ kg adsorbent (normalized to a salinity of 35 psu), a saturation adsorption capacity of 4.89 ± 0.83 g U/kg of adsorbent material (normalized to a salinity of 35 psu) and a half-saturation time of 28 10 days. The AF1 adsorbentmore »
- Authors:
-
more »
- Marine Sciences Lab., Sequim, WA (United States). Pacific Northwest National Lab.
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Idaho, Moscow, ID (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Woods Hole Oceanographic Institution, Woods Hole, MA (United States)
- Univ. of Miami, Miami, FL (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Nuclear Energy (NE)
- OSTI Identifier:
- 1286943
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Industrial and Engineering Chemistry Research
- Additional Journal Information:
- Journal Volume: 55; Journal Issue: 15; Journal ID: ISSN 0888-5885
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; uranium; seawater; amidoxime; adsorption capacity; adsorption kinetics; marine testing; uranium toxicity; biofouling; themodynamic modelling
Citation Formats
Gill, Gary A., Kuo, Li -Jung, Janke, Christopher James, Park, Jiyeon, Jeters, Robert T., Bonheyo, George T., Pan, Horng -Bin, Wai, Chien, Khangaonkar, Tarang P., Bianucci, Laura, Wood, Jordana R., Warner, Marvin G., Peterson, Sonja, Abrecht, David G., Mayes, Richard T., Tsouris, Costas, Oyola, Yatsandra, Strivens, Jonathan E., Schlafer, Nicholas J., Addleman, Shane R., Chouyyok, Wilaiwan, Das, Sadananda, Kim, Jungseung, Buesseler, Ken, Breier, Crystal, and D'Alessandro, Evan. The uranium from seawater program at PNNL: Overview of marine testing, adsorbent characterization, adsorbent durability, adsorbent toxicity, and deployment studies. United States: N. p., 2016.
Web. doi:10.1021/acs.iecr.5b03649.
Gill, Gary A., Kuo, Li -Jung, Janke, Christopher James, Park, Jiyeon, Jeters, Robert T., Bonheyo, George T., Pan, Horng -Bin, Wai, Chien, Khangaonkar, Tarang P., Bianucci, Laura, Wood, Jordana R., Warner, Marvin G., Peterson, Sonja, Abrecht, David G., Mayes, Richard T., Tsouris, Costas, Oyola, Yatsandra, Strivens, Jonathan E., Schlafer, Nicholas J., Addleman, Shane R., Chouyyok, Wilaiwan, Das, Sadananda, Kim, Jungseung, Buesseler, Ken, Breier, Crystal, & D'Alessandro, Evan. The uranium from seawater program at PNNL: Overview of marine testing, adsorbent characterization, adsorbent durability, adsorbent toxicity, and deployment studies. United States. https://doi.org/10.1021/acs.iecr.5b03649
Gill, Gary A., Kuo, Li -Jung, Janke, Christopher James, Park, Jiyeon, Jeters, Robert T., Bonheyo, George T., Pan, Horng -Bin, Wai, Chien, Khangaonkar, Tarang P., Bianucci, Laura, Wood, Jordana R., Warner, Marvin G., Peterson, Sonja, Abrecht, David G., Mayes, Richard T., Tsouris, Costas, Oyola, Yatsandra, Strivens, Jonathan E., Schlafer, Nicholas J., Addleman, Shane R., Chouyyok, Wilaiwan, Das, Sadananda, Kim, Jungseung, Buesseler, Ken, Breier, Crystal, and D'Alessandro, Evan. Sun .
"The uranium from seawater program at PNNL: Overview of marine testing, adsorbent characterization, adsorbent durability, adsorbent toxicity, and deployment studies". United States. https://doi.org/10.1021/acs.iecr.5b03649. https://www.osti.gov/servlets/purl/1286943.
@article{osti_1286943,
title = {The uranium from seawater program at PNNL: Overview of marine testing, adsorbent characterization, adsorbent durability, adsorbent toxicity, and deployment studies},
author = {Gill, Gary A. and Kuo, Li -Jung and Janke, Christopher James and Park, Jiyeon and Jeters, Robert T. and Bonheyo, George T. and Pan, Horng -Bin and Wai, Chien and Khangaonkar, Tarang P. and Bianucci, Laura and Wood, Jordana R. and Warner, Marvin G. and Peterson, Sonja and Abrecht, David G. and Mayes, Richard T. and Tsouris, Costas and Oyola, Yatsandra and Strivens, Jonathan E. and Schlafer, Nicholas J. and Addleman, Shane R. and Chouyyok, Wilaiwan and Das, Sadananda and Kim, Jungseung and Buesseler, Ken and Breier, Crystal and D'Alessandro, Evan},
abstractNote = {The Pacific Northwest National Laboratory's (PNNL) Marine Science Laboratory (MSL) located along the coast of Washington State is evaluating the performance of uranium adsorption materials being developed for seawater extraction under realistic marine conditions with natural seawater. Two types of exposure systems were employed in this program: flow-through columns for testing of fixed beds of individual fibers and pellets and a recirculating water flume for testing of braided adsorbent material. Testing consists of measurements of the adsorption of uranium and other elements from seawater as a function of time, typically 42 to 56 day exposures, to determine the adsorbent capacity and adsorption rate (kinetics). Analysis of uranium and other trace elements collected by the adsorbents was conducted following strong acid digestion of the adsorbent with 50% aqua regia using either Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) or Inductively Coupled Plasma Mass Spectrometer (ICP-MS). The ORNL 38H adsorbent had a 56 day adsorption capacity of 3.30 ± 0.68 g U/ kg adsorbent (normalized to a salinity of 35 psu), a saturation adsorption capacity of 4.89 ± 0.83 g U/kg of adsorbent material (normalized to a salinity of 35 psu) and a half-saturation time of 28 10 days. The AF1 adsorbent material had a 56 day adsorption capacity of 3.9 ± 0.2 g U/kg adsorbent material (normalized to a salinity of 35 psu), a saturation capacity of 5.4 ± 0.2 g U/kg adsorbent material (normalized to a salinity of 35 psu) and a half saturation time of 23 2 days. The ORNL amidoxime-based adsorbent materials are not specific for uranium, but also adsorb other elements from seawater. The major doubly charged cations in seawater (Ca and Mg) account for a majority of the cations adsorbed (61% by mass and 74% by molar percent). For the ORNL AF1 adsorbent material, U is the 4th most abundant element adsorbed by mass and 7th most abundant by molar percentage. Marine testing at Woods Hole Oceanographic Institution with the ORNL AF1 adsorbent produced 15% and 55% higher adsorption capacities than observed at PNNL for column and flume testing, respectively. Variations in competing ions may be the explanation for the regional differences. In addition to marine testing, a number of other efforts are underway to characterize adsorbents and impacts of deployment on the marine environment. Highlights include: Hydrodynamic modelling predicts that a farm of adsorbent materials will likely have minimal effect on ocean currents and removal of uranium and other elements from seawater when densities are < 1800 braids/km2. A decrease in U adsorption capacity of up to 30% was observed after 42 days of exposure due to biofouling when the ORNL braided adsorbent AI8 was exposed to raw seawater in a flume in the presence of light. An identical raw seawater exposure with no light exposure showed little or no impact to adsorption capacity from biofouling. No toxicity was observed with column effluents of any absorbent materials tested to date. Toxicity could be induced with some non amidoxime-based absorbents only when the ratio of solid absorbent to test media was increased to highly unrealistic levels. Thermodynamic modeling of the seawater-amidoxime adsorbent was performed using the geochemical modeling program PHREEQC. Modeling of the binding of Ca, Mg, Fe, Ni, Cu, U, and V from batch interactions with seawater across a variety of concentrations of the amidoxime binding group reveal that when binding sites are limited (1 x 10-8 binding sites/kg seawater), vanadium heavily out-competes other ions for the amidoxime sites. In contrast, when binding sites are abundant magnesium and calcium dominate the total percentage of metals bound to the sorbent.},
doi = {10.1021/acs.iecr.5b03649},
journal = {Industrial and Engineering Chemistry Research},
number = 15,
volume = 55,
place = {United States},
year = {Sun Feb 07 00:00:00 EST 2016},
month = {Sun Feb 07 00:00:00 EST 2016}
}
Web of Science
Works referenced in this record:
Elution of Uranium and Transition Metals from Amidoxime-Based Polymer Adsorbents for Sequestering Uranium from Seawater
journal, December 2015
- Pan, Horng-Bin; Kuo, Li-Jung; Wai, Chien M.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Enhancing Uranium Uptake by Amidoxime Adsorbent in Seawater: An Investigation for Optimum Alkaline Conditioning Parameters
journal, September 2015
- Das, S.; Tsouris, C.; Zhang, C.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Development of a Kelp-Type Structure Module in a Coastal Ocean Model to Assess the Hydrodynamic Impact of Seawater Uranium Extraction Technology
journal, February 2014
- Wang, Taiping; Khangaonkar, Tarang; Long, Wen
- Journal of Marine Science and Engineering, Vol. 2, Issue 1
Characterization and Testing of Amidoxime-Based Adsorbent Materials to Extract Uranium from Natural Seawater
journal, December 2015
- Kuo, Li-Jung; Janke, Christopher J.; Wood, Jordana R.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Uptake of Uranium from Seawater by Amidoxime-Based Polymeric Adsorbent: Field Experiments, Modeling, and Updated Economic Assessment
journal, March 2014
- Kim, Jungseung; Tsouris, Costas; Oyola, Yatsandra
- Industrial & Engineering Chemistry Research, Vol. 53, Issue 14
Polymer brush coatings for combating marine biofouling
journal, May 2014
- Yang, Wen Jing; Neoh, Koon-Gee; Kang, En-Tang
- Progress in Polymer Science, Vol. 39, Issue 5
Complexation of uranium( vi ) with glutarimidoxioxime: thermodynamic and computational studies
journal, January 2015
- Endrizzi, Francesco; Melchior, Andrea; Tolazzi, Marilena
- Dalton Transactions, Vol. 44, Issue 31
Complexation of calcium and magnesium with glutarimidedioxime: Implications for the extraction of uranium from seawater
journal, July 2015
- Leggett, Christina J.; Rao, Linfeng
- Polyhedron, Vol. 95
Optimization and evaluation of mixed-bed chemisorbents for extracting fission and activation products from marine and fresh waters
journal, December 2011
- Johnson, Bryce E.; Santschi, Peter H.; Addleman, Raymond Shane
- Analytica Chimica Acta, Vol. 708, Issue 1-2
The Adsorption Properties and Kinetics of Uranium(VI) with a Novel Fibrous and Polymeric Adsorbent Containing Amidoxime Chelating Functional Group from Seawater
journal, January 2003
- Zhang, Anyun; Uchiyama, Gunzo; Asakura, Toshihide
- Separation Science and Technology, Vol. 38, Issue 8
Current and emerging environmentally-friendly systems for fouling control in the marine environment
journal, December 2013
- Gittens, Jeanette E.; Smith, Thomas J.; Suleiman, Rami
- Biotechnology Advances, Vol. 31, Issue 8
Characterization of Uranium Uptake Kinetics from Seawater in Batch and Flow-Through Experiments
journal, June 2013
- Kim, Jungseung; Oyola, Yatsandra; Tsouris, Costas
- Industrial & Engineering Chemistry Research, Vol. 52, Issue 27
Chemical aspects of uranium recovery from seawater by amidoximated electron-beam-grafted polypropylene membranes
journal, November 2008
- Das, Sadananda; Pandey, A. K.; Athawale, Anjali
- Desalination, Vol. 232, Issue 1-3, p. 243-253
Uranium Sorption with Functionalized Mesoporous Carbon Materials
journal, October 2013
- Carboni, Michaël; Abney, Carter W.; Taylor-Pashow, Kathryn M. L.
- Industrial & Engineering Chemistry Research, Vol. 52, Issue 43
Potential Impact of Seawater Uranium Extraction on Marine Life
journal, December 2015
- Park, Jiyeon; Jeters, Robert T.; Kuo, Li-Jung
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Surface functionalized nanostructured ceramic sorbents for the effective collection and recovery of uranium from seawater
journal, January 2016
- Chouyyok, Wilaiwan; Pittman, Jonathan W.; Warner, Marvin G.
- Dalton Transactions, Vol. 45, Issue 28
Cationically Charged Poly(amidoxime)-Grafted Polypropylene Nonwoven Fabric for Potential Uranium Extraction from Seawater
journal, August 2015
- Zeng, Zehua; Wei, Yanqi; Shen, Liang
- Industrial & Engineering Chemistry Research, Vol. 54, Issue 35
A New Type of Amidoxime-Group-Containing Adsorbent for the Recovery of Uranium from Seawater. III. Recycle Use of Adsorbent
journal, August 1986
- Omichi, H.; Katakai, A.; Sugo, T.
- Separation Science and Technology, Vol. 21, Issue 6-7
The adsorption mechanism of uranium(VI) from seawater on a macroporous fibrous polymeric adsorbent containing amidoxime chelating functional group
journal, November 2003
- Zhang, Anyun; Asakura, Toshihide; Uchiyama, Gunzo
- Reactive and Functional Polymers, Vol. 57, Issue 1
Investigation of the role of chelating ligand in the synthesis of ion-imprinted polymeric resins on the selective enrichment of uranium(VI)
journal, March 2007
- Metilda, P.; Gladis, J. Mary; Venkateswaran, G.
- Analytica Chimica Acta, Vol. 587, Issue 2
Complexation of glutarimidedioxime with Fe(iii), Cu(ii), Pb(ii), and Ni(ii), the competing ions for the sequestration of U(vi) from seawater
journal, January 2013
- Sun, Xiaoqi; Xu, Chao; Tian, Guoxin
- Dalton Transactions, Vol. 42, Issue 40
Use of amidoximated hydrogel for removal and recovery of U(VI) ion from water samples
journal, October 2010
- Hazer, Orhan; Kartal, Şenol
- Talanta, Vol. 82, Issue 5
Review of cost estimates for uranium recovery from seawater
journal, May 2015
- Lindner, Harry; Schneider, Erich
- Energy Economics, Vol. 49
Uranium recovery from seawater: development of fiber adsorbents prepared via atom-transfer radical polymerization
journal, January 2014
- Saito, Tomonori; Brown, Suree; Chatterjee, Sabornie
- J. Mater. Chem. A, Vol. 2, Issue 35
Re-evaluating the 238U-salinity relationship in seawater: Implications for the 238U–234Th disequilibrium method
journal, December 2011
- Owens, S. A.; Buesseler, K. O.; Sims, K. W. W.
- Marine Chemistry, Vol. 127, Issue 1-4
Automated on-line flow-injection ICP-MS determination of trace metals (Mn, Fe, Co, Ni, Cu and Zn) in open ocean seawater: Application to the GEOTRACES program
journal, September 2013
- Lagerström, M. E.; Field, M. P.; Séguret, M.
- Marine Chemistry, Vol. 155
Exchanges of Uranium(VI) Species in Amidoxime-Functionalized Sorbents
journal, April 2009
- Das, Sadananda; Pandey, Ashok K.; Athawale, Anjali A.
- The Journal of Physical Chemistry B, Vol. 113, Issue 18
Chemical Speciation of Uranium(VI) in Marine Environments: Complexation of Calcium and Magnesium Ions with [(UO 2 )(CO 3 ) 3 ] 4− and the Effect on the Extraction of Uranium from Seawater
journal, September 2014
- Endrizzi, Francesco; Rao, Linfeng
- Chemistry - A European Journal, Vol. 20, Issue 44
Organo-functionalized mesoporous silicas for efficient uranium extraction
journal, November 2013
- Vivero-Escoto, Juan L.; Carboni, Michaël; Abney, Carter W.
- Microporous and Mesoporous Materials, Vol. 180
Comparison of Analytical Methods for the Determination of Uranium in Seawater Using Inductively Coupled Plasma Mass Spectrometry
journal, December 2015
- Wood, Jordana R.; Gill, Gary A.; Kuo, Li-Jung
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Structural and spectroscopic studies of a rare non-oxido V( v ) complex crystallized from aqueous solution
journal, January 2016
- Leggett, C. J.; Parker, B. F.; Teat, S. J.
- Chemical Science, Vol. 7, Issue 4
Current status of adsorbent for metal ions with radiation grafting and crosslinking techniques
journal, July 2005
- Seko, Noriaki; Tamada, Masao; Yoshii, Fumio
- Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 236, Issue 1-4
Recovery of Uranium from Seawater: A Review of Current Status and Future Research Needs
journal, January 2013
- Kim, Jungseung; Tsouris, Costas; Mayes, Richard T.
- Separation Science and Technology, Vol. 48, Issue 3
Collection of Lanthanides and Actinides from Natural Waters with Conventional and Nanoporous Sorbents
journal, October 2012
- Johnson, Bryce E.; Santschi, Peter H.; Chuang, Chia-Ying
- Environmental Science & Technology, Vol. 46, Issue 20
The Cost of Recovering Uranium from Seawater by a Braided Polymer Adsorbent System
journal, May 2013
- Schneider, Erich; Sachde, Darshan
- Science & Global Security, Vol. 21, Issue 2
Recovery of uranium from seawater. XII. Preparation and characterization of lightly crosslinked highly porous chelating resins containing amidoxime groups
journal, September 1992
- Egawa, Hiroaki; Kabay, Nalan; Shuto, Taketomi
- Journal of Applied Polymer Science, Vol. 46, Issue 1
Natural antifouling compounds: Effectiveness in preventing invertebrate settlement and adhesion
journal, May 2015
- Almeida, Joana R.; Vasconcelos, Vitor
- Biotechnology Advances, Vol. 33, Issue 3-4
Macroporous monoliths for trace metal extraction from seawater
journal, January 2015
- Yue, Yanfeng; Mayes, Richard T.; Gill, Gary
- RSC Advances, Vol. 5, Issue 62
Improved detection of toxic chemicals using bioluminescent bacteria
journal, October 2002
- Girotti, Stefano; Bolelli, Luca; Roda, Aldo
- Analytica Chimica Acta, Vol. 471, Issue 1
Extracting Uranium from Seawater: Promising AF Series Adsorbents
journal, November 2015
- Das, S.; Oyola, Y.; Mayes, Richard T.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Extracting Uranium from Seawater: Promising AI Series Adsorbents
journal, November 2015
- Das, S.; Oyola, Y.; Mayes, R. T.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Alternative Alkaline Conditioning of Amidoxime Based Adsorbent for Uranium Extraction from Seawater
journal, October 2015
- Das, S.; Liao, W. -P.; Flicker Byers, M.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Nanostructured Metal Oxide Sorbents for the Collection and Recovery of Uranium from Seawater
journal, December 2015
- Chouyyok, Wilaiwan; Warner, Cynthia L.; Mackie, Katherine E.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Fine Fibrous Amidoxime Adsorbent Synthesized by Grafting and Uranium Adsorption–Elution Cyclic Test with Seawater
journal, January 2004
- Seko, Noriaki; Katakai, Akio; Tamada, Masao
- Separation Science and Technology, Vol. 39, Issue 16
Effect of Biofouling on the Performance of Amidoxime-Based Polymeric Uranium Adsorbents
journal, December 2015
- Park, Jiyeon; Gill, Gary A.; Strivens, Jonathan E.
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
Extraction of Trivalent Lanthanides with Oxa-Diamides in Supercritical Fluid Carbon Dioxide
journal, April 2008
- Tian, Guoxin; Liao, Weisheng; Wai, Chien M.
- Industrial & Engineering Chemistry Research, Vol. 47, Issue 8
Collection of fission and activation product elements from fresh and ocean waters: A comparison of traditional and novel sorbents
journal, January 2011
- Johnson, Bryce E.; Santschi, Peter H.; Shane Addleman, Raymond
- Applied Radiation and Isotopes, Vol. 69, Issue 1
pH Effect on the uranium adsorption from seawater by a macroporous fibrous polymeric material containing amidoxime chelating functional group
journal, May 2005
- Zhang, Anyun; Uchiyama, Gunzo; Asakura, Toshihide
- Reactive and Functional Polymers, Vol. 63, Issue 2
Fractional Elution and Determination of Uranium and Vanadium Adsorbed on Amidoxime Fiber from Seawater.
journal, January 2000
- Suzuki, Toshihiro; Saito, Kyoichi; Sugo, Takanobu
- Analytical Sciences, Vol. 16, Issue 4
Towards understanding KOH conditioning of amidoxime-based polymer adsorbents for sequestering uranium from seawater
journal, January 2015
- Pan, Horng-Bin; Kuo, Li-Jung; Wood, Jordana
- RSC Advances, Vol. 5, Issue 122
Current Status of Technology for Collection of Uranium from Seawater
conference, January 2012
- Tamada, Masao
- International Seminar on Nuclear War and Planetary Emergencies 42nd Session, International Seminar on Nuclear War and Planetary Emergencies — 42nd Session
Description of input and examples for PHREEQC version 3: a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations
report, January 2013
- Parkhurst, David L.; Appelo, C. A. J.
Experimental Thermodynamic Studies for Efficient Extraction of Uranium from Seawater
report, August 2014
- Leggett, Christina
Works referencing / citing this record:
A Bio‐inspired Nano‐pocket Spatial Structure for Targeting Uranyl Capture
journal, January 2020
- Yuan, Yihui; Feng, Shiwei; Feng, Lijuan
- Angewandte Chemie International Edition, Vol. 59, Issue 11
Engineering robust metal–phenolic network membranes for uranium extraction from seawater
journal, January 2019
- Luo, Wei; Xiao, Gao; Tian, Fan
- Energy & Environmental Science, Vol. 12, Issue 2
Amidoxime Polymers for Uranium Adsorption: Influence of Comonomers and Temperature
journal, November 2017
- Ladshaw, Austin P.; Wiechert, Alexander I.; Das, Sadananda
- Materials, Vol. 10, Issue 11
The use of silver nanoparticles for the recovery of uranium from seawater by means of biofouling mitigation
journal, January 2018
- Byers, Margaret Flicker; Landsberger, Sheldon; Schneider, Erich
- Sustainable Energy & Fuels, Vol. 2, Issue 10
Ultrafast and Highly Selective Uranium Extraction from Seawater by Hydrogel‐like Spidroin‐based Protein Fiber
journal, July 2019
- Yuan, Yihui; Yu, Qiuhan; Wen, Jun
- Angewandte Chemie, Vol. 131, Issue 34
Photoinduced Multiple Effects to Enhance Uranium Extraction from Natural Seawater by Black Phosphorus Nanosheets
journal, November 2019
- Yuan, Yihui; Niu, Biye; Yu, Qiuhan
- Angewandte Chemie, Vol. 132, Issue 3
A Dual‐Surface Amidoximated Halloysite Nanotube for High‐Efficiency Economical Uranium Extraction from Seawater
journal, September 2019
- Zhao, Shilei; Yuan, Yihui; Yu, Qiuhan
- Angewandte Chemie International Edition, Vol. 58, Issue 42
Interactions of vanadium( iv ) with amidoxime ligands: redox reactivity
journal, January 2018
- Parker, B. F.; Hohloch, S.; Pankhurst, J. R.
- Dalton Transactions, Vol. 47, Issue 16
Amidoxime Polymers for Uranium Adsorption: Influence of Comonomers and Temperature
journal, November 2017
- Ladshaw, Austin P.; Wiechert, Alexander I.; Das, Sadananda
- Materials, Vol. 10, Issue 11
Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater
journal, November 2017
- Ivanov, Alexander S.; Leggett, Christina J.; Parker, Bernard F.
- Nature Communications, Vol. 8, Issue 1
Ultrafast and Highly Selective Uranium Extraction from Seawater by Hydrogel-like Spidroin-based Protein Fiber
journal, July 2019
- Yuan, Yihui; Yu, Qiuhan; Wen, Jun
- Angewandte Chemie International Edition, Vol. 58, Issue 34
Photoinduced Multiple Effects to Enhance Uranium Extraction from Natural Seawater by Black Phosphorus Nanosheets
journal, December 2019
- Yuan, Yihui; Niu, Biye; Yu, Qiuhan
- Angewandte Chemie International Edition, Vol. 59, Issue 3
Rational Design of Porous Nanofiber Adsorbent by Blow-Spinning with Ultrahigh Uranium Recovery Capacity from Seawater
journal, November 2018
- Yuan, Yihui; Zhao, Shilei; Wen, Jun
- Advanced Functional Materials, Vol. 29, Issue 2
Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater
journal, November 2017
- Ivanov, Alexander S.; Leggett, Christina J.; Parker, Bernard F.
- Nature Communications, Vol. 8, Issue 1
A Dual‐Surface Amidoximated Halloysite Nanotube for High‐Efficiency Economical Uranium Extraction from Seawater
journal, September 2019
- Zhao, Shilei; Yuan, Yihui; Yu, Qiuhan
- Angewandte Chemie, Vol. 131, Issue 42
A highly efficient uranium grabber derived from acrylic fiber for extracting uranium from seawater
journal, January 2020
- Pan, Horng-Bin; Wai, Chien M.; Kuo, Li-Jung
- Dalton Transactions, Vol. 49, Issue 9
Phosphate-Based Ultrahigh Molecular Weight Polyethylene Fibers for Efficient Removal of Uranium from Carbonate Solution Containing Fluoride Ions
journal, May 2018
- Li, Rong; Li, Yuna; Zhang, Maojiang
- Molecules, Vol. 23, Issue 6
Superhydrophilic phosphate and amide functionalized magnetic adsorbent: a new combination of anti-biofouling and uranium extraction from seawater
journal, January 2018
- Guo, Xuejie; Chen, Rongrong; Liu, Qi
- Environmental Science: Nano, Vol. 5, Issue 10
A Universally Applicable Strategy for Construction of Anti‐Biofouling Adsorbents for Enhanced Uranium Recovery from Seawater
journal, March 2019
- Yu, Qiuhan; Yuan, Yihui; Wen, Jun
- Advanced Science, Vol. 6, Issue 13
A Bio‐inspired Nano‐pocket Spatial Structure for Targeting Uranyl Capture
journal, March 2020
- Yuan, Yihui; Feng, Shiwei; Feng, Lijuan
- Angewandte Chemie, Vol. 132, Issue 11
Ultrafast Recovery of Uranium from Seawater by Bacillus velezensis Strain UUS‐1 with Innate Anti‐Biofouling Activity
journal, July 2019
- Yuan, Yihui; Yu, Qiuhan; Yang, Shuo
- Advanced Science, Vol. 6, Issue 18