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Title: Origin of Active Oxygen in a Ternary CuO x /Co 3O 4–CeO 2 Catalyst for CO Oxidation

Abstract

In this paper, we have studied CO oxidation over a ternary CuO x/Co 3O 4-CeO 2 catalyst and employed the techniques of N 2 adsorption/desporption, XRD, TPR, TEM, in situ DRIFTS and QMS (Quadrupole mass spectrometer) to explore the origin of active oxygen. DRIFTS-QMS results with labeled 18O2 indicate that the origin of active oxygens in CuO x/Co 3O 4-CeO 2 obeys a model, called as queue mechanism. Namely gas-phase molecular oxygens are dissociated to atomic oxygens and then incorporate in oxygen vacancies located at the interface of Co 3O 4-CeO 2 to form active crystalline oxygens, and these active oxygens diffuse to the CO-Cu + sites thanks to the oxygen vacancy concentration magnitude and react with the activated CO to form CO 2. This process, obeying a queue rule, provides active oxygens to form CO 2 from gas-phase O 2 via oxygen vacancies and crystalline oxygen at the interface of Co 3O 4-CeO 2.

Authors:
 [1];  [2];  [3];  [4];  [2];  [5]
  1. Hunan Univ., Changsha (China). School of Chemistry and Chemical Engineering
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
  3. Arizona State Univ., Mesa, AZ (United States). School of Letters and Sciences
  4. Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
  5. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1286745
Grant/Contract Number:  
AC05-00OR22725; 21103045; 1210040; 1103312
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Physical Chemistry. C
Additional Journal Information:
Journal Volume: 118; Journal Issue: 48; Journal ID: ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; CuOx/Co3O4-CeO2; CO oxidation; Queue mechanism; Interface interaction; Oxygen vacancy

Citation Formats

Liu, Zhigang, Wu, Zili, Peng, Xihong, Binder, Andrew, Chai, Songhai, and Dai, Sheng. Origin of Active Oxygen in a Ternary CuOx /Co3O4–CeO 2 Catalyst for CO Oxidation. United States: N. p., 2014. Web. doi:10.1021/jp508487x.
Liu, Zhigang, Wu, Zili, Peng, Xihong, Binder, Andrew, Chai, Songhai, & Dai, Sheng. Origin of Active Oxygen in a Ternary CuOx /Co3O4–CeO 2 Catalyst for CO Oxidation. United States. doi:10.1021/jp508487x.
Liu, Zhigang, Wu, Zili, Peng, Xihong, Binder, Andrew, Chai, Songhai, and Dai, Sheng. Fri . "Origin of Active Oxygen in a Ternary CuOx /Co3O4–CeO 2 Catalyst for CO Oxidation". United States. doi:10.1021/jp508487x. https://www.osti.gov/servlets/purl/1286745.
@article{osti_1286745,
title = {Origin of Active Oxygen in a Ternary CuOx /Co3O4–CeO 2 Catalyst for CO Oxidation},
author = {Liu, Zhigang and Wu, Zili and Peng, Xihong and Binder, Andrew and Chai, Songhai and Dai, Sheng},
abstractNote = {In this paper, we have studied CO oxidation over a ternary CuOx/Co3O4-CeO2 catalyst and employed the techniques of N2 adsorption/desporption, XRD, TPR, TEM, in situ DRIFTS and QMS (Quadrupole mass spectrometer) to explore the origin of active oxygen. DRIFTS-QMS results with labeled 18O2 indicate that the origin of active oxygens in CuOx/Co3O4-CeO2 obeys a model, called as queue mechanism. Namely gas-phase molecular oxygens are dissociated to atomic oxygens and then incorporate in oxygen vacancies located at the interface of Co3O4-CeO2 to form active crystalline oxygens, and these active oxygens diffuse to the CO-Cu+ sites thanks to the oxygen vacancy concentration magnitude and react with the activated CO to form CO2. This process, obeying a queue rule, provides active oxygens to form CO2 from gas-phase O2 via oxygen vacancies and crystalline oxygen at the interface of Co3O4-CeO2.},
doi = {10.1021/jp508487x},
journal = {Journal of Physical Chemistry. C},
number = 48,
volume = 118,
place = {United States},
year = {2014},
month = {11}
}

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Cited by: 13 works
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