Geometry of electromechanically active structures in Gadolinium - doped Cerium oxides
Abstract
Local distortions from average structure are important in many functional materials, such as electrostrictors or piezoelectrics, and contain clues about their mechanism of work. However, the geometric attributes of these distortions are exceedingly difficult to measure, leading to a gap in knowledge regarding their roles in electromechanical response. This task is particularly challenging in the case of recently reported non-classical electrostriction in Cerium-Gadolinium oxides (CGO), where only a small population of Ce-O bonds that are located near oxygen ion vacancies responds to external electric field. In this study, we used high-energy resolution fluorescence detection (HERFD) technique to collect X-ray absorption spectra in CGO in situ, with and without an external electric field, coupled with theoretical modeling to characterize three-dimensional geometry of electromechanically active units.
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1254031
- Alternate Identifier(s):
- OSTI ID: 1272367; OSTI ID: 1421040
- Grant/Contract Number:
- FG02- 03ER15476; FG02-03ER15476
- Resource Type:
- Published Article
- Journal Name:
- AIP Advances
- Additional Journal Information:
- Journal Name: AIP Advances Journal Volume: 6 Journal Issue: 5; Journal ID: ISSN 2158-3226
- Publisher:
- American Institute of Physics
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Li, Yuanyuan, Kraynis, Olga, Kas, Joshua, Weng, Tsu-Chien, Sokaras, Dimosthenis, Zacharowicz, Renee, Lubomirsky, Igor, and Frenkel, Anatoly I. Geometry of electromechanically active structures in Gadolinium - doped Cerium oxides. United States: N. p., 2016.
Web. doi:10.1063/1.4952645.
Li, Yuanyuan, Kraynis, Olga, Kas, Joshua, Weng, Tsu-Chien, Sokaras, Dimosthenis, Zacharowicz, Renee, Lubomirsky, Igor, & Frenkel, Anatoly I. Geometry of electromechanically active structures in Gadolinium - doped Cerium oxides. United States. https://doi.org/10.1063/1.4952645
Li, Yuanyuan, Kraynis, Olga, Kas, Joshua, Weng, Tsu-Chien, Sokaras, Dimosthenis, Zacharowicz, Renee, Lubomirsky, Igor, and Frenkel, Anatoly I. Sun .
"Geometry of electromechanically active structures in Gadolinium - doped Cerium oxides". United States. https://doi.org/10.1063/1.4952645.
@article{osti_1254031,
title = {Geometry of electromechanically active structures in Gadolinium - doped Cerium oxides},
author = {Li, Yuanyuan and Kraynis, Olga and Kas, Joshua and Weng, Tsu-Chien and Sokaras, Dimosthenis and Zacharowicz, Renee and Lubomirsky, Igor and Frenkel, Anatoly I.},
abstractNote = {Local distortions from average structure are important in many functional materials, such as electrostrictors or piezoelectrics, and contain clues about their mechanism of work. However, the geometric attributes of these distortions are exceedingly difficult to measure, leading to a gap in knowledge regarding their roles in electromechanical response. This task is particularly challenging in the case of recently reported non-classical electrostriction in Cerium-Gadolinium oxides (CGO), where only a small population of Ce-O bonds that are located near oxygen ion vacancies responds to external electric field. In this study, we used high-energy resolution fluorescence detection (HERFD) technique to collect X-ray absorption spectra in CGO in situ, with and without an external electric field, coupled with theoretical modeling to characterize three-dimensional geometry of electromechanically active units.},
doi = {10.1063/1.4952645},
journal = {AIP Advances},
number = 5,
volume = 6,
place = {United States},
year = {Sun May 01 00:00:00 EDT 2016},
month = {Sun May 01 00:00:00 EDT 2016}
}
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Works referenced in this record:
Characteristics of relaxor-based piezoelectric single crystals for ultrasonic transducers
journal, September 1997
- Seung-Eek Park, ; Shrout, T. R.
- IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control, Vol. 44, Issue 5
Stretching Dielectric Elastomer Performance
journal, December 2010
- Carpi, F.; Bauer, S.; De Rossi, D.
- Science, Vol. 330, Issue 6012
Stretchable, Transparent, Ionic Conductors
journal, August 2013
- Keplinger, C.; Sun, J. -Y.; Foo, C. C.
- Science, Vol. 341, Issue 6149
Elastic, dielectric, and piezoelectric anomalies and Raman spectroscopy of 0.5Ba(Ti 0.8 Zr 0.2 )O 3 -0.5(Ba 0.7 Ca 0.3 )TiO 3
journal, May 2012
- Damjanovic, Dragan; Biancoli, Alberto; Batooli, Leili
- Applied Physics Letters, Vol. 100, Issue 19
Giant Electrostriction in Gd-Doped Ceria
journal, August 2012
- Korobko, Roman; Patlolla, Anitha; Kossoy, Anna
- Advanced Materials, Vol. 24, Issue 43
Mobile Ferroelastic Domain Walls in Nanocrystalline PZT Films: the Direct Piezoelectric Effect
journal, July 2011
- Zednik, Ricardo J.; Varatharajan, Anbusathaiah; Oliver, Mark
- Advanced Functional Materials, Vol. 21, Issue 16
Properties of ferroelectric PbTiO3 thin films
journal, February 2002
- Kighelman, Zian; Damjanovic, Dragan; Cantoni, Marco
- Journal of Applied Physics, Vol. 91, Issue 3
An all-organic composite actuator material with a high dielectric constant
journal, September 2002
- Zhang, Q. M.; Li, Hengfeng; Poh, Martin
- Nature, Vol. 419, Issue 6904
Giant Electrostriction and Relaxor Ferroelectric Behavior in Electron-Irradiated Poly(vinylidene fluoride-trifluoroethylene) Copolymer
journal, June 1998
- Zhang, Q. M.
- Science, Vol. 280, Issue 5372
Bulk characterization methods for non-centrosymmetric materials: second-harmonic generation, piezoelectricity, pyroelectricity, and ferroelectricity
journal, January 2006
- Ok, Kang Min; Chi, Eun Ok; Halasyamani, P. Shiv
- Chemical Society Reviews, Vol. 35, Issue 8
Semiconducting and Piezoelectric Oxide Nanostructures Induced by Polar Surfaces
journal, October 2004
- Wang, Z. L.; Kong, X. Y.; Ding, Y.
- Advanced Functional Materials, Vol. 14, Issue 10
Electrostriction: Nonlinear Electromechanical Coupling in Solid Dielectrics
journal, November 1997
- Newnham, R. E.; Sundar, V.; Yimnirun, R.
- The Journal of Physical Chemistry B, Vol. 101, Issue 48
Large Nonclassical Electrostriction in (Y, Nb)-Stabilized δ -Bi 2 O 3
journal, January 2016
- Yavo, Nimrod; Smith, Alaric D.; Yeheskel, Ori
- Advanced Functional Materials, Vol. 26, Issue 7
In-situ extended X-ray absorption fine structure study of electrostriction in Gd doped ceria
journal, January 2015
- Korobko, Roman; Lerner, Alyssa; Li, Yuanyuan
- Applied Physics Letters, Vol. 106, Issue 4
Elimination of the inner-shell lifetime broadening in x-ray-absorption spectroscopy
journal, November 1991
- Hämäläinen, K.; Siddons, D. P.; Hastings, J. B.
- Physical Review Letters, Vol. 67, Issue 20
Magnetic manipulation of molecules on a non-magnetic catalytic surface
journal, January 2013
- Sá, Jacinto; Szlachetko, Jakub; Sikora, Marcin
- Nanoscale, Vol. 5, Issue 18
Real Time Determination of the Electronic Structure of Unstable Reaction Intermediates during Au 2 O 3 Reduction
journal, December 2013
- Szlachetko, Jakub; Sá, Jacinto; Nachtegaal, Maarten
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 1
Polyhedral CeO 2 Nanoparticles: Size-Dependent Geometrical and Electronic Structure
journal, March 2012
- Paun, Cristina; Safonova, Olga V.; Szlachetko, Jakub
- The Journal of Physical Chemistry C, Vol. 116, Issue 13
Direct study of the f-electron configuration in lanthanide systems
journal, January 2011
- Kvashnina, Kristina O.; Butorin, Sergei M.; Glatzel, Pieter
- Journal of Analytical Atomic Spectrometry, Vol. 26, Issue 6
A seven-crystal Johann-type hard x-ray spectrometer at the Stanford Synchrotron Radiation Lightsource
journal, May 2013
- Sokaras, D.; Weng, T. -C.; Nordlund, D.
- Review of Scientific Instruments, Vol. 84, Issue 5
Evolution of the local structure at the phase transition in CeO -Gd O solid solutions
journal, February 2013
- Kossoy, A.; Wang, Q.; Korobko, R.
- Physical Review B, Vol. 87, Issue 5
A new method of directly determining the core–hole effect in the Ce L3 XAS of mixed valence Ce compounds—An application of resonant X-ray emission spectroscopy
journal, April 2011
- Kotani, A.; Kvashnina, K. O.; Butorin, S. M.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 184, Issue 3-6
Crystal-structure effects in the Ce -edge x-ray-absorption spectrum of : Multiple-scattering resonances and many-body final states
journal, August 1994
- Soldatov, A. V.; Ivanchenko, T. S.; Della Longa, S.
- Physical Review B, Vol. 50, Issue 8
X-ray absorption study of ceria nanorods promoting the disproportionation of hydrogen peroxide
journal, January 2016
- Wu, Tai-Sing; Zhou, Yunyun; Sabirianov, Renat F.
- Chemical Communications, Vol. 52, Issue 28
X-ray absorption studies of , , and . II. Rare-earth valence state by absorption edges
journal, July 1987
- Dexpert, H.; Karnatak, R. C.; Esteva, J. -M.
- Physical Review B, Vol. 36, Issue 3
Ab initio theory and calculations of X-ray spectra
journal, July 2009
- Rehr, John J.; Kas, Joshua J.; Prange, Micah P.
- Comptes Rendus Physique, Vol. 10, Issue 6
Parameter-free calculations of X-ray spectra with FEFF9
journal, January 2010
- Rehr, John J.; Kas, Joshua J.; Vila, Fernando D.
- Physical Chemistry Chemical Physics, Vol. 12, Issue 21
Theoretical approaches to x-ray absorption fine structure
journal, July 2000
- Rehr, J. J.; Albers, R. C.
- Reviews of Modern Physics, Vol. 72, Issue 3
Spectator and participator processes in the resonant photon-in and photon-out spectra at the Ce L3 edge of CeO2
journal, July 2012
- Kotani, A.; Kvashnina, K. O.; Butorin, S. M.
- The European Physical Journal B, Vol. 85, Issue 8
Works referencing / citing this record:
Enhanced electro-mechanical coupling of TiN/Ce 0.8 Gd 0.2 O 1.9 thin film electrostrictor
journal, July 2019
- Santucci, Simone; Zhang, Haiwu; Sanna, Simone
- APL Materials, Vol. 7, Issue 7
Towards the surface hydroxyl species in CeO 2 nanoparticles
journal, January 2019
- Plakhova, Tatiana V.; Romanchuk, Anna Yu.; Butorin, Sergei M.
- Nanoscale, Vol. 11, Issue 39
Suitability of Raman Spectroscopy for Assessing Anisotropic Strain in Thin Films of Doped Ceria
journal, January 2019
- Kraynis, Olga; Makagon, Evgeniy; Mishuk, Eran
- Advanced Functional Materials, Vol. 29, Issue 11
Investigation of periodically driven systems by x-ray absorption spectroscopy using asynchronous data collection mode
journal, April 2018
- Singh, H.; Donetsky, D.; Liu, J.
- Review of Scientific Instruments, Vol. 89, Issue 4