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Title: Monodispersed Li 4Ti 5O 12 with Controlled Morphology as High Power Lithium Ion Battery Anodes

Monodispersed Li 4Ti 5O 12 (LTO) nanoparticles with controlled microstructure were successfully synthesized by a combination of hydrolysis and hydrothermal method followed by a post-annealing process. The scanning electron microscopy images showed that particles with a size of 30-40 nm were precisely controlled throughout the synthesis process. The electrochemical tests of the as-prepared LTO electrodes in a half-cell proved its high rate performance and outstanding cyclability which benefits from the preserved well-controlled nanoparticle size and morphology. LTO electrodes were also tested in a full cell configuration in pairing with LiFePO 4 cathodes, which demonstrated a capacity of 147.3 mAh g -1. In addition, we have also demonstrated that LTO materials prepared using lithium salts separated from geothermal brine solutions had good cyclability. These demonstrations provide a promising way for making low-cost, large-scale LTO electrode materials for energy storage applications.
Authors:
 [1] ;  [2] ;  [2] ;  [1] ;  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Cristal USA, Glen Burnie, MD (United States)
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
ChemNanoMat
Additional Journal Information:
Journal Volume: 2; Journal Issue: 7; Journal ID: ISSN 2199-692X
Publisher:
Wiley
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE
OSTI Identifier:
1271875
Alternate Identifier(s):
OSTI ID: 1401203

Li, Yunchao, Fu, Guoyi, Watson, Mark, Harrison, Stephen, and Paranthaman, M. Parans. Monodispersed Li4Ti5O12 with Controlled Morphology as High Power Lithium Ion Battery Anodes. United States: N. p., Web. doi:10.1002/cnma.201600106.
Li, Yunchao, Fu, Guoyi, Watson, Mark, Harrison, Stephen, & Paranthaman, M. Parans. Monodispersed Li4Ti5O12 with Controlled Morphology as High Power Lithium Ion Battery Anodes. United States. doi:10.1002/cnma.201600106.
Li, Yunchao, Fu, Guoyi, Watson, Mark, Harrison, Stephen, and Paranthaman, M. Parans. 2016. "Monodispersed Li4Ti5O12 with Controlled Morphology as High Power Lithium Ion Battery Anodes". United States. doi:10.1002/cnma.201600106. https://www.osti.gov/servlets/purl/1271875.
@article{osti_1271875,
title = {Monodispersed Li4Ti5O12 with Controlled Morphology as High Power Lithium Ion Battery Anodes},
author = {Li, Yunchao and Fu, Guoyi and Watson, Mark and Harrison, Stephen and Paranthaman, M. Parans},
abstractNote = {Monodispersed Li4Ti5O12 (LTO) nanoparticles with controlled microstructure were successfully synthesized by a combination of hydrolysis and hydrothermal method followed by a post-annealing process. The scanning electron microscopy images showed that particles with a size of 30-40 nm were precisely controlled throughout the synthesis process. The electrochemical tests of the as-prepared LTO electrodes in a half-cell proved its high rate performance and outstanding cyclability which benefits from the preserved well-controlled nanoparticle size and morphology. LTO electrodes were also tested in a full cell configuration in pairing with LiFePO4 cathodes, which demonstrated a capacity of 147.3 mAh g-1. In addition, we have also demonstrated that LTO materials prepared using lithium salts separated from geothermal brine solutions had good cyclability. These demonstrations provide a promising way for making low-cost, large-scale LTO electrode materials for energy storage applications.},
doi = {10.1002/cnma.201600106},
journal = {ChemNanoMat},
number = 7,
volume = 2,
place = {United States},
year = {2016},
month = {5}
}