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Title: Size-dependent phase transition in methylammonium lead iodide perovskite microplate crystals

Abstract

Methylammonium lead iodide perovskite has attracted considerable recent interest for solution processable solar cells and other optoelectronic applications. The orthorhombic-to-tetragonal phase transition in perovskite can significantly alter its optical, electrical properties and impact the corresponding applications. Here, we report a systematic investigation of the size-dependent orthorhombic-to-tetragonal phase transition using a combined temperature-dependent optical, electrical transport and transmission electron microscopy study. Our studies of individual perovskite microplates with variable thicknesses demonstrate that the phase transition temperature decreases with reducing microplate thickness. The sudden decrease of mobility around phase transition temperature and the presence of hysteresis loops in the temperature-dependent mobility confirm that the orthorhombic-to-tetragonal phase transition is a first-order phase transition. Lastly, our findings offer significant fundamental insight on the temperature-and size-dependent structural, optical and charge transport properties of perovskite materials, and can greatly impact future exploration of novel electronic and optoelectronic devices from these materials.

Authors:
 [1];  [2];  [3];  [1];  [3];  [3];  [4];  [2]
+ Show Author Affiliations
  1. Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry
  2. Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry, CA Nanosystems Inst.
  3. Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering
  4. Univ. of California, Los Angeles, CA (United States). CA Nanosystems Inst., Dept. of Materials Science and Engineering
Publication Date:
Research Org.:
Univ. of California, Los Angeles, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1270965
Grant/Contract Number:  
SC0008055
Resource Type:
Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 7; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; organometal halide perovskite; solar-cells; single-crystals; light; mobility; nanocrystals; deposition; diffusion; disorder; density

Citation Formats

Li, Dehui, Wang, Gongming, Cheng, Hung -Chieh, Chen, Chih -Yen, Wu, Hao, Liu, Yuan, Huang, Yu, and Duan, Xiangfeng. Size-dependent phase transition in methylammonium lead iodide perovskite microplate crystals. United States: N. p., 2016. Web. doi:10.1038/ncomms11330.
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Li, Dehui, Wang, Gongming, Cheng, Hung -Chieh, Chen, Chih -Yen, Wu, Hao, Liu, Yuan, Huang, Yu, & Duan, Xiangfeng. Size-dependent phase transition in methylammonium lead iodide perovskite microplate crystals. United States. https://doi.org/10.1038/ncomms11330
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Li, Dehui, Wang, Gongming, Cheng, Hung -Chieh, Chen, Chih -Yen, Wu, Hao, Liu, Yuan, Huang, Yu, and Duan, Xiangfeng. Thu . "Size-dependent phase transition in methylammonium lead iodide perovskite microplate crystals". United States. https://doi.org/10.1038/ncomms11330. https://www.osti.gov/servlets/purl/1270965.
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@article{osti_1270965,
title = {Size-dependent phase transition in methylammonium lead iodide perovskite microplate crystals},
author = {Li, Dehui and Wang, Gongming and Cheng, Hung -Chieh and Chen, Chih -Yen and Wu, Hao and Liu, Yuan and Huang, Yu and Duan, Xiangfeng},
abstractNote = {Methylammonium lead iodide perovskite has attracted considerable recent interest for solution processable solar cells and other optoelectronic applications. The orthorhombic-to-tetragonal phase transition in perovskite can significantly alter its optical, electrical properties and impact the corresponding applications. Here, we report a systematic investigation of the size-dependent orthorhombic-to-tetragonal phase transition using a combined temperature-dependent optical, electrical transport and transmission electron microscopy study. Our studies of individual perovskite microplates with variable thicknesses demonstrate that the phase transition temperature decreases with reducing microplate thickness. The sudden decrease of mobility around phase transition temperature and the presence of hysteresis loops in the temperature-dependent mobility confirm that the orthorhombic-to-tetragonal phase transition is a first-order phase transition. Lastly, our findings offer significant fundamental insight on the temperature-and size-dependent structural, optical and charge transport properties of perovskite materials, and can greatly impact future exploration of novel electronic and optoelectronic devices from these materials.},
doi = {10.1038/ncomms11330},
journal = {Nature Communications},
number = ,
volume = 7,
place = {United States},
year = {Thu Apr 21 00:00:00 EDT 2016},
month = {Thu Apr 21 00:00:00 EDT 2016}
}
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Works referenced in this record:

The emergence of perovskite solar cells
journal, July 2014

  • Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J.
  • Nature Photonics, Vol. 8, Issue 7, p. 506-514
  • DOI: 10.1038/nphoton.2014.134

Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012

Efficient planar heterojunction perovskite solar cells by vapour deposition
journal, September 2013

  • Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J.
  • Nature, Vol. 501, Issue 7467, p. 395-398
  • DOI: 10.1038/nature12509

Sequential deposition as a route to high-performance perovskite-sensitized solar cells
journal, July 2013

  • Burschka, Julian; Pellet, Norman; Moon, Soo-Jin
  • Nature, Vol. 499, Issue 7458, p. 316-319
  • DOI: 10.1038/nature12340

Interface engineering of highly efficient perovskite solar cells
journal, July 2014

Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques
journal, December 2013

Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
journal, July 2014

  • Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan
  • Nature Materials, Vol. 13, Issue 9, p. 897-903
  • DOI: 10.1038/nmat4014

The light and shade of perovskite solar cells
journal, August 2014

Electro-optics of perovskite solar cells
journal, December 2014

  • Lin, Qianqian; Armin, Ardalan; Nagiri, Ravi Chandra Raju
  • Nature Photonics, Vol. 9, Issue 2
  • DOI: 10.1038/nphoton.2014.284

Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals
journal, January 2015

Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
journal, January 2015

High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015

Solution-processed hybrid perovskite photodetectors with high detectivity
journal, November 2014

  • Dou, Letian; Yang, Yang (Micheal); You, Jingbi
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6404

Low-temperature solution-processed wavelength-tunable perovskites for lasing
journal, March 2014

  • Xing, Guichuan; Mathews, Nripan; Lim, Swee Sien
  • Nature Materials, Vol. 13, Issue 5
  • DOI: 10.1038/nmat3911

Room-Temperature Near-Infrared High-Q Perovskite Whispering-Gallery Planar Nanolasers
journal, September 2014

  • Zhang, Qing; Ha, Son Tung; Liu, Xinfeng
  • Nano Letters, Vol. 14, Issue 10
  • DOI: 10.1021/nl503057g

Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors
journal, April 2015

  • Zhu, Haiming; Fu, Yongping; Meng, Fei
  • Nature Materials, Vol. 14, Issue 6
  • DOI: 10.1038/nmat4271

Bright light-emitting diodes based on organometal halide perovskite
journal, August 2014

  • Tan, Zhi-Kuang; Moghaddam, Reza Saberi; Lai, May Ling
  • Nature Nanotechnology, Vol. 9, Issue 9
  • DOI: 10.1038/nnano.2014.149

Lead iodide perovskite light-emitting field-effect transistor
journal, June 2015

  • Chin, Xin Yu; Cortecchia, Daniele; Yin, Jun
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8383

Laser liftoff of gallium arsenide thin films
journal, February 2015

  • Hayes, Garrett J.; Clemens, Bruce M.
  • MRS Communications, Vol. 5, Issue 1
  • DOI: 10.1557/mrc.2015.2

Growth of CH3NH3PbI3 cuboids with controlled size for high-efficiency perovskite solar cells
journal, August 2014

  • Im, Jeong-Hyeok; Jang, In-Hyuk; Pellet, Norman
  • Nature Nanotechnology, Vol. 9, Issue 11
  • DOI: 10.1038/nnano.2014.181

Charge carrier recombination channels in the low-temperature phase of organic-inorganic lead halide perovskite thin films
journal, August 2014

  • Wehrenfennig, Christian; Liu, Mingzhen; Snaith, Henry J.
  • APL Materials, Vol. 2, Issue 8
  • DOI: 10.1063/1.4891595

Complete structure and cation orientation in the perovskite photovoltaic methylammonium lead iodide between 100 and 352 K
journal, January 2015

  • Weller, Mark T.; Weber, Oliver J.; Henry, Paul F.
  • Chemical Communications, Vol. 51, Issue 20
  • DOI: 10.1039/C4CC09944C

Calorimetric and IR spectroscopic studies of phase transitions in methylammonium trihalogenoplumbates (II)†
journal, January 1990

  • Onoda-Yamamuro, Noriko; Matsuo, Takasuke; Suga, Hiroshi
  • Journal of Physics and Chemistry of Solids, Vol. 51, Issue 12
  • DOI: 10.1016/0022-3697(90)90021-7

Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties
journal, July 2013

  • Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G.
  • Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038
  • DOI: 10.1021/ic401215x

Size Dependence of Structural Metastability in Semiconductor Nanocrystals
journal, April 1997

Size Dependence of a Temperature-Induced Solid–Solid Phase Transition in Copper(I) Sulfide
journal, September 2011

  • Rivest, Jessy B.; Fong, Lam-Kiu; Jain, Prashant K.
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 19
  • DOI: 10.1021/jz2010144

Gate-tunable phase transitions in thin flakes of 1T-TaS2
journal, January 2015

Temperature-dependent excitonic photoluminescence of hybrid organometal halide perovskite films
journal, January 2014

  • Wu, Kewei; Bera, Ashok; Ma, Chun
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 41
  • DOI: 10.1039/C4CP03573A

Ionic transport in hybrid lead iodide perovskite solar cells
journal, June 2015

  • Eames, Christopher; Frost, Jarvist M.; Barnes, Piers R. F.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8497

Molecular ferroelectric contributions to anomalous hysteresis in hybrid perovskite solar cells
journal, August 2014

  • Frost, Jarvist M.; Butler, Keith T.; Walsh, Aron
  • APL Materials, Vol. 2, Issue 8
  • DOI: 10.1063/1.4890246

Dielectric study of CH3NH3PbX3 (X = Cl, Br, I)
journal, July 1992

  • Onoda-Yamamuro, Noriko; Matsuo, Takasuke; Suga, Hiroshi
  • Journal of Physics and Chemistry of Solids, Vol. 53, Issue 7
  • DOI: 10.1016/0022-3697(92)90121-S

Dielectric-Constant-Enhanced Hall Mobility in Complex Oxides
journal, June 2012

  • Siemons, Wolter; McGuire, Michael A.; Cooper, Valentino R.
  • Advanced Materials, Vol. 24, Issue 29
  • DOI: 10.1002/adma.201104665

Giant switchable photovoltaic effect in organometal trihalide perovskite devices
journal, December 2014

  • Xiao, Zhengguo; Yuan, Yongbo; Shao, Yuchuan
  • Nature Materials, Vol. 14, Issue 2
  • DOI: 10.1038/nmat4150

The Raman Spectrum of the CH 3 NH 3 PbI 3 Hybrid Perovskite: Interplay of Theory and Experiment
journal, December 2013

  • Quarti, Claudio; Grancini, Giulia; Mosconi, Edoardo
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 2
  • DOI: 10.1021/jz402589q

Lattice dynamics and vibrational spectra of the orthorhombic, tetragonal, and cubic phases of methylammonium lead iodide
journal, October 2015

High Charge Carrier Mobilities and Lifetimes in Organolead Trihalide Perovskites
journal, December 2013

  • Wehrenfennig, Christian; Eperon, Giles E.; Johnston, Michael B.
  • Advanced Materials, Vol. 26, Issue 10
  • DOI: 10.1002/adma.201305172

Terahertz mobility measurements on poly-3-hexylthiophene films: Device comparison, molecular weight, and film processing effects
journal, January 2008

  • Esenturk, Okan; Melinger, Joseph S.; Heilweil, Edwin J.
  • Journal of Applied Physics, Vol. 103, Issue 2
  • DOI: 10.1063/1.2828028

Insights into the Charge Carrier Terahertz Mobility in Polyfluorenes from Large-Scale Atomistic Simulations and Time-Resolved Terahertz Spectroscopy
journal, September 2012

  • Vukmirović, Nenad; Ponseca, Carlito S.; Němec, Hynek
  • The Journal of Physical Chemistry C, Vol. 116, Issue 37
  • DOI: 10.1021/jp3055262

Temperature-Dependent Hall and Field-Effect Mobility in Strongly Coupled All-Inorganic Nanocrystal Arrays
journal, January 2014

  • Jang, Jaeyoung; Liu, Wenyong; Son, Jae Sung
  • Nano Letters, Vol. 14, Issue 2
  • DOI: 10.1021/nl403889u

First-order structural phase transition in CaFe 2 As 2
journal, July 2008

Hysteresis and hierarchies: Dynamics of disorder-driven first-order phase transformations
journal, May 1993

Analysis of Multivalley and Multibandgap Absorption and Enhancement of Free Carriers Related to Exciton Screening in Hybrid Perovskites
journal, May 2014

  • Even, Jacky; Pedesseau, Laurent; Katan, Claudine
  • The Journal of Physical Chemistry C, Vol. 118, Issue 22
  • DOI: 10.1021/jp503337a

Strain-induced spatially indirect exciton recombination in zinc-blende/wurtzite CdS heterostructures
journal, June 2015

Evidence of type‐II band alignment at the ordered GaInP to GaAs heterointerface
journal, February 1995

  • Liu, Q.; Derksen, S.; Lindner, A.
  • Journal of Applied Physics, Vol. 77, Issue 3
  • DOI: 10.1063/1.358979

Size-Dependent Photon Emission from Organometal Halide Perovskite Nanocrystals Embedded in an Organic Matrix
journal, January 2015

  • Di, Dawei; Musselman, Kevin P.; Li, Guangru
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 3
  • DOI: 10.1021/jz502615e

Tuning the Light Emission Properties by Band Gap Engineering in Hybrid Lead Halide Perovskite
journal, December 2014

  • D’Innocenzo, Valerio; Srimath Kandada, Ajay Ram; De Bastiani, Michele
  • Journal of the American Chemical Society, Vol. 136, Issue 51
  • DOI: 10.1021/ja511198f

Comparative study on the excitons in lead-halide-based perovskite-type crystals CH3NH3PbBr3 CH3NH3PbI3
journal, September 2003

  • Tanaka, Kenichiro; Takahashi, Takayuki; Ban, Takuma
  • Solid State Communications, Vol. 127, Issue 9-10, p. 619-623
  • DOI: 10.1016/S0038-1098(03)00566-0

Surface Depletion Induced Quantum Confinement in CdS Nanobelts
journal, May 2012

  • Li, Dehui; Zhang, Jun; Xiong, Qihua
  • ACS Nano, Vol. 6, Issue 6
  • DOI: 10.1021/nn301053r

Strongly enhanced charge-density-wave order in monolayer NbSe2
journal, July 2015

  • Xi, Xiaoxiang; Zhao, Liang; Wang, Zefang
  • Nature Nanotechnology, Vol. 10, Issue 9, p. 765-769
  • DOI: 10.1038/nnano.2015.143

Elucidating the role of disorder and free-carrier recombination kinetics in CH3NH3PbI3 perovskite films
journal, July 2015

  • La-o-vorakiat, Chan; Salim, Teddy; Kadro, Jeannette
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8903

Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors
journal, May 2013

  • Heo, Jin Hyuck; Im, Sang Hyuk; Noh, Jun Hong
  • Nature Photonics, Vol. 7, Issue 6, p. 486-491
  • DOI: 10.1038/nphoton.2013.80

Strongly enhanced charge-density-wave order in monolayer NbSe$_2$
text, January 2015

Hysteresis and hierarchies: dynamics of disorder-driven first-order phase transformations
text, January 1992

Dielectric-Constant-Enhanced Hall Mobility in Complex Oxides
journal, June 2012

  • Siemons, Wolter; McGuire, Michael A.; Cooper, Valentino R.
  • Advanced Materials, Vol. 24, Issue 29
  • DOI: 10.1002/adma.201104665

Tuning the Light Emission Properties by Band Gap Engineering in Hybrid Lead Halide Perovskite
journal, December 2014

  • D’Innocenzo, Valerio; Srimath Kandada, Ajay Ram; De Bastiani, Michele
  • Journal of the American Chemical Society, Vol. 136, Issue 51
  • DOI: 10.1021/ja511198f

Temperature-Dependent Hall and Field-Effect Mobility in Strongly Coupled All-Inorganic Nanocrystal Arrays
journal, January 2014

  • Jang, Jaeyoung; Liu, Wenyong; Son, Jae Sung
  • Nano Letters, Vol. 14, Issue 2
  • DOI: 10.1021/nl403889u

Room-Temperature Near-Infrared High-Q Perovskite Whispering-Gallery Planar Nanolasers
journal, September 2014

  • Zhang, Qing; Ha, Son Tung; Liu, Xinfeng
  • Nano Letters, Vol. 14, Issue 10
  • DOI: 10.1021/nl503057g

Surface Depletion Induced Quantum Confinement in CdS Nanobelts
journal, May 2012

  • Li, Dehui; Zhang, Jun; Xiong, Qihua
  • ACS Nano, Vol. 6, Issue 6
  • DOI: 10.1021/nn301053r

Sequential deposition as a route to high-performance perovskite-sensitized solar cells
journal, July 2013

  • Burschka, Julian; Pellet, Norman; Moon, Soo-Jin
  • Nature, Vol. 499, Issue 7458, p. 316-319
  • DOI: 10.1038/nature12340

Lead iodide perovskite light-emitting field-effect transistor
journal, June 2015

  • Chin, Xin Yu; Cortecchia, Daniele; Yin, Jun
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8383

Ionic transport in hybrid lead iodide perovskite solar cells
journal, June 2015

  • Eames, Christopher; Frost, Jarvist M.; Barnes, Piers R. F.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8497

Elucidating the role of disorder and free-carrier recombination kinetics in CH3NH3PbI3 perovskite films
journal, July 2015

  • La-o-vorakiat, Chan; Salim, Teddy; Kadro, Jeannette
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8903

The light and shade of perovskite solar cells
journal, August 2014

Giant switchable photovoltaic effect in organometal trihalide perovskite devices
journal, December 2014

  • Xiao, Zhengguo; Yuan, Yongbo; Shao, Yuchuan
  • Nature Materials, Vol. 14, Issue 2
  • DOI: 10.1038/nmat4150

Bright light-emitting diodes based on organometal halide perovskite
journal, August 2014

  • Tan, Zhi-Kuang; Moghaddam, Reza Saberi; Lai, May Ling
  • Nature Nanotechnology, Vol. 9, Issue 9
  • DOI: 10.1038/nnano.2014.149

Growth of CH3NH3PbI3 cuboids with controlled size for high-efficiency perovskite solar cells
journal, August 2014

  • Im, Jeong-Hyeok; Jang, In-Hyuk; Pellet, Norman
  • Nature Nanotechnology, Vol. 9, Issue 11
  • DOI: 10.1038/nnano.2014.181

Terahertz mobility measurements on poly-3-hexylthiophene films: Device comparison, molecular weight, and film processing effects
journal, January 2008

  • Esenturk, Okan; Melinger, Joseph S.; Heilweil, Edwin J.
  • Journal of Applied Physics, Vol. 103, Issue 2
  • DOI: 10.1063/1.2828028

Charge carrier recombination channels in the low-temperature phase of organic-inorganic lead halide perovskite thin films
journal, August 2014

  • Wehrenfennig, Christian; Liu, Mingzhen; Snaith, Henry J.
  • APL Materials, Vol. 2, Issue 8
  • DOI: 10.1063/1.4891595

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013

  • Stranks, S. D.; Eperon, G. E.; Grancini, G.
  • Science, Vol. 342, Issue 6156, p. 341-344
  • DOI: 10.1126/science.1243982

Size Dependence of Structural Metastability in Semiconductor Nanocrystals
journal, April 1997

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    Probing and Controlling Intragrain Crystallinity for Improved Low Temperature-Processed Perovskite Solar Cells
    journal, November 2018

    • Du, Tian; Burgess, Claire H.; Lin, Chieh-Ting
    • Advanced Functional Materials, Vol. 28, Issue 51
    • DOI: 10.1002/adfm.201803943

    The Effect of Thermal Annealing on Charge Transport in Organolead Halide Perovskite Microplate Field-Effect Transistors
    journal, November 2016

    Controllable Epitaxial Growth of Core-Shell PbSe@CsPbBr 3 Wire Heterostructures
    journal, September 2018

    2D Perovskite Sr 2 Nb 3 O 10 for High‐Performance UV Photodetectors
    journal, November 2019

    Integrating Properties Modification in the Synthesis of Metal Halide Perovskites
    journal, November 2018

    • Huang, Ke; Liu, Jinxin; Chang, Xuejiao
    • Advanced Materials Technologies, Vol. 4, Issue 2
    • DOI: 10.1002/admt.201800321

    Lead Halide Perovskite Based Microdisk Lasers for On-Chip Integrated Photonic Circuits
    journal, January 2018

    Anomalous Ambipolar Phototransistors Based on All‐Inorganic CsPbBr 3 Perovskite at Room Temperature
    journal, August 2019

    Giant Electric Bias‐Induced Tunability of Photoluminescence and Photoresistance in Hybrid Perovskite Films on Ferroelectric Substrates
    journal, August 2019

    • Ren, Lixia; Wang, Min; Guan, Xinwei
    • Advanced Optical Materials, Vol. 7, Issue 21
    • DOI: 10.1002/adom.201901092

    Application of Perovskite‐Structured Materials in Field‐Effect Transistors
    journal, September 2019

    • Wu, Tingjun; Pisula, Wojciech; Rashid, Mohd Yusoff Abd
    • Advanced Electronic Materials, Vol. 5, Issue 12
    • DOI: 10.1002/aelm.201900444

    Impact of Structural Dynamics on the Optical Properties of Methylammonium Lead Iodide Perovskites
    journal, June 2017

    • Panzer, Fabian; Li, Cheng; Meier, Tobias
    • Advanced Energy Materials, Vol. 7, Issue 16
    • DOI: 10.1002/aenm.201700286

    Localized Traps Limited Recombination in Lead Bromide Perovskites
    journal, January 2019

    • Fu, Jianhui; Jamaludin, Nur Fadilah; Wu, Bo
    • Advanced Energy Materials, Vol. 9, Issue 12
    • DOI: 10.1002/aenm.201803119

    Electron‐Beam‐Related Studies of Halide Perovskites: Challenges and Opportunities
    journal, February 2020

    • Ran, Junhui; Dyck, Ondrej; Wang, Xiaozheng
    • Advanced Energy Materials, Vol. 10, Issue 26
    • DOI: 10.1002/aenm.201903191

    Fabry-Pérot Oscillation and Room Temperature Lasing in Perovskite Cube-Corner Pyramid Cavities
    journal, January 2018

    Metal Halide Perovskites: Synthesis, Ion Migration, and Application in Field-Effect Transistors
    journal, July 2018

    Intrinsic Carrier Transport of Phase-Pure Homologous 2D Organolead Halide Hybrid Perovskite Single Crystals
    journal, November 2018

    Structural, optical and photoluminescence properties of hybrid metal–organic halide perovskite thin films prepared by a single step solution method
    journal, April 2018

    • Montes-Valenzuela, Isaac; Pérez-Sánchez, Francisco; Morales-Acevedo, Arturo
    • Journal of Materials Science: Materials in Electronics, Vol. 29, Issue 18
    • DOI: 10.1007/s10854-018-9062-8

    Single-crystal microplates of two-dimensional organic–inorganic lead halide layered perovskites for optoelectronics
    journal, January 2017

    Structural, optical, and electrical properties of phase-controlled cesium lead iodide nanowires
    journal, February 2017

    Surface depletion field in 2D perovskite microplates: Structural phase transition, quantum confinement and Stark effect
    journal, October 2019

    Single crystal hybrid perovskite field-effect transistors
    journal, December 2018

    Large lattice distortions and size-dependent bandgap modulation in epitaxial halide perovskite nanowires
    journal, January 2020

    Indirect to direct bandgap transition in methylammonium lead halide perovskite
    journal, January 2017

    • Wang, Tianyi; Daiber, Benjamin; Frost, Jarvist M.
    • Energy & Environmental Science, Vol. 10, Issue 2
    • DOI: 10.1039/c6ee03474h

    Energy level diagram of HC(NH 2 ) 2 PbI 3 single crystal evaluated by electrical and optical analyses
    journal, January 2018

    • Sekimoto, Takeyuki; Suzuka, Michio; Yokoyama, Tomoyasu
    • Physical Chemistry Chemical Physics, Vol. 20, Issue 3
    • DOI: 10.1039/c7cp07477h

    Growth, characterization, and thin film transistor application of CH 3 NH 3 PbI 3 perovskite on polymeric gate dielectric layers
    journal, January 2017

    • Ngai, Jenner H. L.; Ho, Johnny K. W.; Chan, Rocky K. H.
    • RSC Adv., Vol. 7, Issue 78
    • DOI: 10.1039/c7ra08699g

    Photon-generated carriers excite superoxide species inducing long-term photoluminescence enhancement of MAPbI 3 perovskite single crystals
    journal, January 2017

    • Feng, Xiyuan; Su, Huimin; Wu, Yinghui
    • Journal of Materials Chemistry A, Vol. 5, Issue 24
    • DOI: 10.1039/c7ta03066e

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    journal, January 2018

    • Jung, Hye Ri; Nguyen, Bich Phuong; Jin, Hye-Jin
    • CrystEngComm, Vol. 20, Issue 41
    • DOI: 10.1039/c8ce01229f

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    journal, January 2018

    • Duan, Yunrui; Li, Jie; Li, Tao
    • Physical Chemistry Chemical Physics, Vol. 20, Issue 14
    • DOI: 10.1039/c8cp00185e

    Remarkable long-term stability of nanoconfined metal–halide perovskite crystals against degradation and polymorph transitions
    journal, January 2018

    • Kong, Xiaoqing; Shayan, Kamran; Lee, Sangchul
    • Nanoscale, Vol. 10, Issue 17
    • DOI: 10.1039/c8nr01352g

    Pressure-induced fluorescence enhancement of FA α PbBr 2+α composite perovskites
    journal, January 2019

    • Nguyen, Lan Anh Thi; Minh, Duong Nguyen; Yuan, Ye
    • Nanoscale, Vol. 11, Issue 13
    • DOI: 10.1039/c8nr09780a

    Beyond quantum confinement: excitonic nonlocality in halide perovskite nanoparticles with Mie resonances
    journal, January 2019

    • Berestennikov, A. S.; Li, Y.; Iorsh, I. V.
    • Nanoscale, Vol. 11, Issue 14
    • DOI: 10.1039/c8nr09837a

    Solvent-induced surface disorder and doping-induced lattice distortion in anatase TiO 2 nanocrystals for enhanced photoreversible color switching
    journal, January 2019

    • Yang, Kewei; Chen, Xiaoyu; Zheng, Zhenhuan
    • Journal of Materials Chemistry A, Vol. 7, Issue 8
    • DOI: 10.1039/c8ta10045d

    Lithium-ion batteries: outlook on present, future, and hybridized technologies
    journal, January 2019

    • Kim, Taehoon; Song, Wentao; Son, Dae-Yong
    • Journal of Materials Chemistry A, Vol. 7, Issue 7
    • DOI: 10.1039/c8ta10513h

    Synthesis of ultrathin two-dimensional organic–inorganic hybrid perovskite nanosheets for polymer field-effect transistors
    journal, January 2018

    • Zhu, Lijie; Zhang, Huaye; Lu, Qipeng
    • Journal of Materials Chemistry C, Vol. 6, Issue 15
    • DOI: 10.1039/c8tc00289d

    Metal halide perovskites: stability and sensing-ability
    journal, January 2018

    • Zhu, Zhaohua; Sun, Qian; Zhang, Zhipeng
    • Journal of Materials Chemistry C, Vol. 6, Issue 38
    • DOI: 10.1039/c8tc03164a

    Tetradic phosphor white light with variable CCT and superlative CRI through organolead halide perovskite nanocrystals
    journal, January 2019

    • Adhikari, Gopi C.; Vargas, Preston A.; Zhu, Hongyang
    • Nanoscale Advances, Vol. 1, Issue 5
    • DOI: 10.1039/c9na00125e

    The scaling of the ligand concentration and Soret effect induced phase transition in CsPbBr 3 perovskite quantum dots
    journal, January 2019

    • Li, Jiagen; Hu, Menglei; Wang, Zhaojin
    • Journal of Materials Chemistry A, Vol. 7, Issue 48
    • DOI: 10.1039/c9ta10226d

    Reversible air-induced optical and electrical modulation of methylammonium lead bromide (MAPbBr 3 ) single crystals
    journal, September 2017

    • Zhang, Huotian; Liu, Yiting; Lu, Haizhou
    • Applied Physics Letters, Vol. 111, Issue 10
    • DOI: 10.1063/1.5001843

    Computational screening of methylammonium based halide perovskites with bandgaps suitable for perovskite-perovskite tandem solar cells
    journal, December 2018

    • Kar, M.; Körzdörfer, T.
    • The Journal of Chemical Physics, Vol. 149, Issue 21
    • DOI: 10.1063/1.5037535

    Electric-field-induced phase transition in 2D layered perovskite (BA) 2 PbI 4 microplate crystals
    journal, February 2020

    • Wang, Jiaqi; Shen, Hongzhi; Li, Junze
    • Applied Physics Letters, Vol. 116, Issue 5
    • DOI: 10.1063/1.5132825

    Phase-transition–induced p-n junction in single halide perovskite nanowire
    journal, August 2018

    • Kong, Qiao; Lee, Woochul; Lai, Minliang
    • Proceedings of the National Academy of Sciences, Vol. 115, Issue 36
    • DOI: 10.1073/pnas.1806515115

    Cation effect on excitons in perovskite nanocrystals from single-dot photoluminescence of C H 3 N H 3 Pb I 3
    journal, November 2019

    Nontrivial strength of van der Waals epitaxial interaction in soft perovskites
    journal, July 2018

    Understanding charge transport in lead iodide perovskite thin-film field-effect transistors
    journal, January 2017

    • Senanayak, Satyaprasad P.; Yang, Bingyan; Thomas, Tudor H.
    • Science Advances, Vol. 3, Issue 1
    • DOI: 10.1126/sciadv.1601935

    A general printing approach for scalable growth of perovskite single-crystal films
    journal, June 2018

    An Emerging Visible-Light Organic–Inorganic Hybrid Perovskite for Photocatalytic Applications
    journal, January 2020

    • Bresolin, Bianca-Maria; Ben Hammouda, Samia; Sillanpää, Mika
    • Nanomaterials, Vol. 10, Issue 1
    • DOI: 10.3390/nano10010115

    Printable Semiconductors for Backplane TFTs of Flexible OLED Displays
    journal, August 2019

    • Zhu, Huihui; Shin, Eun‐Sol; Liu, Ao
    • Advanced Functional Materials, Vol. 30, Issue 20
    • DOI: 10.1002/adfm.201904588

    Crystallographically Aligned Perovskite Structures for High-Performance Polarization-Sensitive Photodetectors
    journal, February 2017

    Enhanced Charge Transport in Hybrid Perovskite Field‐Effect Transistors via Microstructure Control
    journal, September 2018

    • Zeidell, Andrew M.; Tyznik, Colin; Jennings, Laura
    • Advanced Electronic Materials, Vol. 4, Issue 12
    • DOI: 10.1002/aelm.201800316

    Impact of microstructure on the electron–hole interaction in lead halide perovskites
    journal, January 2017

    • Mahboubi Soufiani, Arman; Yang, Zhuo; Young, Trevor
    • Energy & Environmental Science, Vol. 10, Issue 6
    • DOI: 10.1039/c7ee00685c

    Temperature and spectral dependence of CH 3 NH 3 PbI 3 films photoconductivity
    journal, May 2017

    • Khenkin, M. V.; Amasev, D. V.; Kozyukhin, S. A.
    • Applied Physics Letters, Vol. 110, Issue 22
    • DOI: 10.1063/1.4984899

    Substrate effects on photoluminescence and low temperature phase transition of methylammonium lead iodide hybrid perovskite thin films
    journal, July 2017

    • Shojaee, S. A.; Harriman, T. A.; Han, G. S.
    • Applied Physics Letters, Vol. 111, Issue 2
    • DOI: 10.1063/1.4993761

    Fabrication of single phase 2D homologous perovskite microplates by mechanical exfoliation
    journal, January 2018

    Emerging Characterizing Techniques in the Fine Structure Observation of Metal Halide Perovskite Crystal
    journal, May 2018

    Light-induced picosecond rotational disordering of the inorganic sublattice in hybrid perovskites
    text, January 2017

    • Wu, Xiaoxi; Tan, Liang Z.; Shen, Xiaozhe
    • Columbia University
    • DOI: 10.7916/d8sr0bbc

    Light-induced picosecond rotational disordering of the inorganic sublattice in hybrid perovskites
    journal, July 2017

    Understanding charge transport in lead iodide perovskite thin-film field-effect transistors
    text, January 2017

    • Senanayak, Satyaprasad; Yang, B.; Thomas, Tudor
    • Apollo - University of Cambridge Repository
    • DOI: 10.17863/cam.7594

    Defect-induced local variation of crystal phase transition temperature in metal-halide perovskites
    journal, June 2017

    Atomic scale insights into structure instability and decomposition pathway of methylammonium lead iodide perovskite
    journal, November 2018

    An Emerging Visible-Light Organic–Inorganic Hybrid Perovskite for Photocatalytic Applications
    journal, January 2020

    • Bresolin, Bianca-Maria; Ben Hammouda, Samia; Sillanpää, Mika
    • Nanomaterials, Vol. 10, Issue 1
    • DOI: 10.3390/nano10010115

    Light-induced picosecond rotational disordering of the inorganic sublattice in hybrid perovskites
    text, January 2017

    • Wu, Xiaoxi; Tan, Liang Z.; Shen, Xiaozhe
    • Columbia University
    • DOI: 10.7916/d8sr0bbc
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