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Title: Carbonaceous nanowire supports for polymer electrolyte membrane fuel cells

Here, carbohydrate-dye combinations were used to form ionically-linked soft templates for the formation of polypyrrole nanowire networks. High yields of nanostructured products were obtained using small amounts of low-cost carbohydrate and dye template materials, the majority of which remained encapsulated within the nanowires. Varying the concentration and the two-part ratio of the templates influenced the length and diameter of the nanofiber segments within the nanowire network. Pyrolysis of the nanowires yielded carbonaceous fibers containing nitrogen heteroatoms, as well as convoluted graphitic domains, well suited for supporting Pt nanoparticles. The resulting high density of nucleation sites enabled the formation of well dispersed, smaller Pt particles compared to commercial catalysts, despite significantly higher support surface loadings.
Authors:
 [1] ;  [2] ;  [3] ;  [3] ;  [4]
  1. Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemical and Biological Engineering
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  3. Ballard Power Systems, Burnaby, BC (Canada)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences
Publication Date:
Report Number(s):
LA-UR-17-21792
Journal ID: ISSN 0013-4651
Grant/Contract Number:
AC05-00OR22725; AC52-06NA25396
Type:
Accepted Manuscript
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 163; Journal Issue: 2; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Research Org:
Univ. of New Mexico, Albuquerque, NM (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Fuel Cell Technologies Office (EE-3F)
Contributing Orgs:
Ballard Power Systems, Burnaby, BC (Canada)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; carbon; catalysts; electrocatalysts; fuel cells; nanowires; PEMFC; Pt catalysts
OSTI Identifier:
1267064
Alternate Identifier(s):
OSTI ID: 1357135