Nucleophilic substitution reaction for post-functionalization of polyoxometalates

Yin, Panchao; Li, Qiang; Zhang, Jin; Wang, Longsheng; Hao, Jian; Wei, Yongge

doi:10.1039/C5NJ01090J

Title: Nucleophilic substitution reaction for post-functionalization of polyoxometalates

Abstract

In this study, a hexamolybdate-based organic inorganic hybrid molecule containing a chloralkane fragment is synthesized and its Cl atom can be substituted by iodine and nitrate through nucleophilic substitution reactions in high yields, which provide a post-functionalization protocol to bring in various additional functional groups into polyoxometalate-based hybrid materials under mild conditions.

Authors:

Yin, Panchao ^[1]; Li, Qiang ^[2]; Zhang, Jin ^[3]; Wang, Longsheng ^[3]; Hao, Jian ^[3]; Wei, Yongge ^[4]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Tsinghua Univ., Beijing (People's Republic of China); Beijing Forestry Univ., Beijing (People's Republic of China)
Tsinghua Univ., Beijing (People's Republic of China)
Tsinghua Univ., Beijing (People's Republic of China); Peking Univ., Beijing (People's Republic of China)

Publication Date:: Mon Jul 06 00:00:00 EDT 2015

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1267049

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: New Journal of Chemistry

Additional Journal Information:: Journal Volume: 40; Journal Issue: 2; Journal ID: ISSN 1144-0546

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats


                    Yin, Panchao, Li, Qiang, Zhang, Jin, Wang, Longsheng, Hao, Jian, and Wei, Yongge. Nucleophilic substitution reaction for post-functionalization of polyoxometalates.  United States: N. p., 2015. 
Web.  doi:10.1039/C5NJ01090J.

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                    Yin, Panchao, Li, Qiang, Zhang, Jin, Wang, Longsheng, Hao, Jian, & Wei, Yongge. Nucleophilic substitution reaction for post-functionalization of polyoxometalates.  United States.  https://doi.org/10.1039/C5NJ01090J

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                    Yin, Panchao, Li, Qiang, Zhang, Jin, Wang, Longsheng, Hao, Jian, and Wei, Yongge. Mon .  
"Nucleophilic substitution reaction for post-functionalization of polyoxometalates".  United States.  https://doi.org/10.1039/C5NJ01090J.  https://www.osti.gov/servlets/purl/1267049.

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@article{osti_1267049,

  title        = {Nucleophilic substitution reaction for post-functionalization of polyoxometalates},

  author       = {Yin, Panchao and Li, Qiang and Zhang, Jin and Wang, Longsheng and Hao, Jian and Wei, Yongge},

  abstractNote = {In this study, a hexamolybdate-based organic inorganic hybrid molecule containing a chloralkane fragment is synthesized and its Cl atom can be substituted by iodine and nitrate through nucleophilic substitution reactions in high yields, which provide a post-functionalization protocol to bring in various additional functional groups into polyoxometalate-based hybrid materials under mild conditions.},

  doi          = {10.1039/C5NJ01090J},

  journal      = {New Journal of Chemistry},

  number       = 2,

  volume       = 40,

  place        = {United States},

  year         = {Mon Jul 06 00:00:00 EDT 2015},

  month        = {Mon Jul 06 00:00:00 EDT 2015}

}

Copy to clipboard

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https://doi.org/10.1039/C5NJ01090J

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Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications
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Title: Nucleophilic substitution reaction for post-functionalization of polyoxometalates

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Hybrid Organic–Inorganic Porphyrin–Polyoxometalate Complexes
journal, August 2008

Functionalisation of [Mo ₆ O ₁₉ ] ^2– with aromatic amines: synthesis and structure of a hexamolybdate building block with linear difunctionality
journal, January 1995

Coordination compounds of polyoxovanadates with a hexametalate core. Chemical and structural characterization of [VV6O13[(OCH2)3CR]2]2-, [VV6O11(OH)2[(OCH2)3CR]2], [VIV4VV2O9(OH)4[(OCH2)3CR]2]2-, and [VIV6O7(OH)6](OCH2)3CR]2]2-
journal, June 1992

Design and fabrication of memory devices based on nanoscale polyoxometalate clusters
journal, November 2014

Design and Synthesis of “Dumb-bell” and “Triangular” Inorganic-Organic Hybrid Nanopolyoxometalate Clusters and Their Characterisation through ESI-MS Analyses
journal, May 2011

Nanoscale polyoxometalate-based inorganic/organic hybrids
journal, May 2011

Organoimido-polyoxometalates as polymer pendants
journal, January 2000

Inorganic–Organic Hybrid Vesicles with Counterion- and pH-Controlled Fluorescent Properties
journal, September 2011

Introduction: PolyoxometalatesMulticomponent Molecular Vehicles To Probe Fundamental Issues and Practical Problems
journal, February 1998

A Coordination Network That Catalyzes O ₂ -Based Oxidations
journal, December 2007

Polyoxometalate-Incorporated Supramolecular Self-Assemblies: Structures and Functional Properties
journal, February 2011

Hydrolytically stable organic triester capped polyoxometalates with catalytic oxygenation activity of formula [RC(CH2O)3V3P2W15O59]6- (R = CH3, NO2, CH2OH)
journal, December 1993

An Easy Route to Monofunctionalized Organoimido Derivatives of the Lindqvist Hexamolybdate
journal, July 2004

A Double-Tailed Fluorescent Surfactant with a Hexavanadate Cluster as the Head Group
journal, February 2011

Supramolecular Metal Oxides: Programmed Hierarchical Assembly of a Protein-Sized 21 kDa [(C16H36N)19{H2NC(CH2O)3P2V3W15O59}4]5− Polyoxometalate Assembly
journal, May 2008

Noncovalently Connected Frameworks with Nanoscale Channels Assembled from a Tethered Polyoxometalate–Pyrene Hybrid
journal, May 2007

Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications
journal, January 2020