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Title: Nucleophilic substitution reaction for post-functionalization of polyoxometalates

In this study, a hexamolybdate-based organic inorganic hybrid molecule containing a chloralkane fragment is synthesized and its Cl atom can be substituted by iodine and nitrate through nucleophilic substitution reactions in high yields, which provide a post-functionalization protocol to bring in various additional functional groups into polyoxometalate-based hybrid materials under mild conditions.
Authors:
 [1] ;  [2] ;  [3] ;  [3] ;  [3] ;  [4]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Tsinghua Univ., Beijing (People's Republic of China); Beijing Forestry Univ., Beijing (People's Republic of China)
  3. Tsinghua Univ., Beijing (People's Republic of China)
  4. Tsinghua Univ., Beijing (People's Republic of China); Peking Univ., Beijing (People's Republic of China)
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
New Journal of Chemistry
Additional Journal Information:
Journal Volume: 40; Journal Issue: 2; Journal ID: ISSN 1144-0546
Publisher:
Royal Society of Chemistry
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
OSTI Identifier:
1267049

Yin, Panchao, Li, Qiang, Zhang, Jin, Wang, Longsheng, Hao, Jian, and Wei, Yongge. Nucleophilic substitution reaction for post-functionalization of polyoxometalates. United States: N. p., Web. doi:10.1039/C5NJ01090J.
Yin, Panchao, Li, Qiang, Zhang, Jin, Wang, Longsheng, Hao, Jian, & Wei, Yongge. Nucleophilic substitution reaction for post-functionalization of polyoxometalates. United States. doi:10.1039/C5NJ01090J.
Yin, Panchao, Li, Qiang, Zhang, Jin, Wang, Longsheng, Hao, Jian, and Wei, Yongge. 2015. "Nucleophilic substitution reaction for post-functionalization of polyoxometalates". United States. doi:10.1039/C5NJ01090J. https://www.osti.gov/servlets/purl/1267049.
@article{osti_1267049,
title = {Nucleophilic substitution reaction for post-functionalization of polyoxometalates},
author = {Yin, Panchao and Li, Qiang and Zhang, Jin and Wang, Longsheng and Hao, Jian and Wei, Yongge},
abstractNote = {In this study, a hexamolybdate-based organic inorganic hybrid molecule containing a chloralkane fragment is synthesized and its Cl atom can be substituted by iodine and nitrate through nucleophilic substitution reactions in high yields, which provide a post-functionalization protocol to bring in various additional functional groups into polyoxometalate-based hybrid materials under mild conditions.},
doi = {10.1039/C5NJ01090J},
journal = {New Journal of Chemistry},
number = 2,
volume = 40,
place = {United States},
year = {2015},
month = {7}
}

Works referenced in this record:

A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals
journal, March 2010