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Title: Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media

For a novel class of polystyrene-based gel-type resins (SPACeR, SP), containing the large 1,4-bis (4-vinylphenoxy)benzene cross-linker, is introduced; SP-immobilized 1,5,7-triazabicyclo [4.4.0]dec-5-ene (TBD) and triethylamine (TEA) bases are synthesized and characterized in terms of their structural, thermal and morphological features, and their catalytic efficiency in a series of fundamental chemical transformations under solvent-free conditions is investigated.
Authors:
 [1] ;  [2] ;  [1] ;  [3] ;  [2] ;  [3] ;  [3] ;  [1] ;  [2] ;  [1]
  1. Univ. of Perugia (Italy)
  2. Hasselt Univ., Diepenbeek (Belgium)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
European Polymer Journal
Additional Journal Information:
Journal Volume: 73; Journal Issue: C; Journal ID: ISSN 0014-3057
Publisher:
Elsevier
Research Org:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE
OSTI Identifier:
1265889

Marrocchi, Assunta, Adriaensens, Peter, Bartollini, Elena, Barkakaty, Balaka, Carleer, Robert, Chen, Jihua, Hensley, Dale K., Petrucci, Chiara, Tassi, Marco, and Vaccaro, Luigi. Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media. United States: N. p., Web. doi:10.1016/j.eurpolymj.2015.10.002.
Marrocchi, Assunta, Adriaensens, Peter, Bartollini, Elena, Barkakaty, Balaka, Carleer, Robert, Chen, Jihua, Hensley, Dale K., Petrucci, Chiara, Tassi, Marco, & Vaccaro, Luigi. Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media. United States. doi:10.1016/j.eurpolymj.2015.10.002.
Marrocchi, Assunta, Adriaensens, Peter, Bartollini, Elena, Barkakaty, Balaka, Carleer, Robert, Chen, Jihua, Hensley, Dale K., Petrucci, Chiara, Tassi, Marco, and Vaccaro, Luigi. 2015. "Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media". United States. doi:10.1016/j.eurpolymj.2015.10.002. https://www.osti.gov/servlets/purl/1265889.
@article{osti_1265889,
title = {Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media},
author = {Marrocchi, Assunta and Adriaensens, Peter and Bartollini, Elena and Barkakaty, Balaka and Carleer, Robert and Chen, Jihua and Hensley, Dale K. and Petrucci, Chiara and Tassi, Marco and Vaccaro, Luigi},
abstractNote = {For a novel class of polystyrene-based gel-type resins (SPACeR, SP), containing the large 1,4-bis (4-vinylphenoxy)benzene cross-linker, is introduced; SP-immobilized 1,5,7-triazabicyclo [4.4.0]dec-5-ene (TBD) and triethylamine (TEA) bases are synthesized and characterized in terms of their structural, thermal and morphological features, and their catalytic efficiency in a series of fundamental chemical transformations under solvent-free conditions is investigated.},
doi = {10.1016/j.eurpolymj.2015.10.002},
journal = {European Polymer Journal},
number = C,
volume = 73,
place = {United States},
year = {2015},
month = {10}
}