Advancing polymers of intrinsic microporosity by mechanochemistry

Zhang, Pengfei; Jiang, Xueguang; Wan, Shun; Dai, Sheng

doi:10.1039/C4TA07196D

Title: Advancing polymers of intrinsic microporosity by mechanochemistry

Abstract

Herein, we report a fast (15 min) and solvent-free mechanochemical approach to construct polymers of intrinsic microporosity (PIMs) with high molecular mass and low polydispersity by solid grinding. The enhanced reaction efficiency results from the instantaneous frictional heating and continuous exposure of active sites within those solid reactants.

Authors:

Zhang, Pengfei ^[1]; Jiang, Xueguang ^[2]; Wan, Shun ^[1]; Dai, Sheng ^[3]

Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Publication Date:: Fri Feb 20 00:00:00 EST 2015

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1265468

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Materials Chemistry. A

Additional Journal Information:: Journal Volume: 3; Journal Issue: 13; Journal ID: ISSN 2050-7488

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Zhang, Pengfei, Jiang, Xueguang, Wan, Shun, and Dai, Sheng. Advancing polymers of intrinsic microporosity by mechanochemistry.  United States: N. p., 2015. 
Web.  doi:10.1039/C4TA07196D.

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                    Zhang, Pengfei, Jiang, Xueguang, Wan, Shun, & Dai, Sheng. Advancing polymers of intrinsic microporosity by mechanochemistry.  United States.  https://doi.org/10.1039/C4TA07196D

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                    Zhang, Pengfei, Jiang, Xueguang, Wan, Shun, and Dai, Sheng. Fri .  
"Advancing polymers of intrinsic microporosity by mechanochemistry".  United States.  https://doi.org/10.1039/C4TA07196D.  https://www.osti.gov/servlets/purl/1265468.

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@article{osti_1265468,

  title        = {Advancing polymers of intrinsic microporosity by mechanochemistry},

  author       = {Zhang, Pengfei and Jiang, Xueguang and Wan, Shun and Dai, Sheng},

  abstractNote = {Herein, we report a fast (15 min) and solvent-free mechanochemical approach to construct polymers of intrinsic microporosity (PIMs) with high molecular mass and low polydispersity by solid grinding. The enhanced reaction efficiency results from the instantaneous frictional heating and continuous exposure of active sites within those solid reactants.},

  doi          = {10.1039/C4TA07196D},

  journal      = {Journal of Materials Chemistry. A},

  number       = 13,

  volume       = 3,

  place        = {United States},

  year         = {Fri Feb 20 00:00:00 EST 2015},

  month        = {Fri Feb 20 00:00:00 EST 2015}

}

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Works referenced in this record:

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Linear High Molecular Weight Ladder Polymer via Fast Polycondensation of 5,5′,6,6′-Tetrahydroxy-3,3,3′,3′-tetramethylspirobisindane with 1,4-Dicyanotetrafluorobenzene
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Supramolecular Catalysis in the Organic Solid State through Dry Grinding
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Sokolov, Anatoliy N.; Bučar, Dejan-Krešimir; Baltrusaitis, Jonas
Angewandte Chemie, Vol. 122, Issue 25
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Works referencing / citing this record:

Entropy‐Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO ₂ Fixation
journal, March 2019

Xu, Wei; Chen, Hao; Jie, Kecheng
Angewandte Chemie, Vol. 131, Issue 15
DOI: 10.1002/ange.201900787

Entropy-Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO ₂ Fixation
journal, March 2019

Xu, Wei; Chen, Hao; Jie, Kecheng
Angewandte Chemie International Edition, Vol. 58, Issue 15
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Mechanochemical Synthesis of Ruthenium Cluster@Ordered Mesoporous Carbon Catalysts by Synergetic Dual Templates
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Wang, Li; Zhao, Jiahua; Zhang, Pengfei
Chemistry – A European Journal, Vol. 25, Issue 36
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The Effect of Thermal Treatment on the Hydrogen‐Storage Properties of PIM‐1
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Ramimoghadam, Donya; Boyd, Sue E.; Brown, Christopher L.
ChemPhysChem, Vol. 20, Issue 12
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The synthesis of polymers of intrinsic microporosity (PIMs)
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McKeown, Neil B.
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Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability
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Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly
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Zhou, Min; Zhao, Jiahua; Zhang, Pengfei
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A facile preparation strategy of polycaprolactone (PCL)-based biodegradable polyurethane elastomer with a highly efficient shape memory effect
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Luo, Qing; Chen, Jing; Gnanasekar, Pitchaimari
New Journal of Chemistry, Vol. 44, Issue 3
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Hydrogen uptake properties of a nanoporous PIM-1–polyaniline nanocomposite polymer
journal, January 2019

Ramimoghadam, Donya; Brown, Christopher L.; Boyd, Sue E.
Journal of Materials Chemistry A, Vol. 7, Issue 39
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Title: Advancing polymers of intrinsic microporosity by mechanochemistry

Abstract

Citation Formats

Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage journal, January 2006

Design and Preparation of Porous Polymers journal, April 2012

Exploitation of Intrinsic Microporosity in Polymer-Based Materials journal, June 2010

Soluble Porous Coordination Polymers by Mechanochemistry: From Metal-Containing Films/Membranes to Active Catalysts for Aerobic Oxidation journal, November 2014

Mechanochemical Synthesis of Chemically Stable Isoreticular Covalent Organic Frameworks journal, March 2013

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Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials journal, January 2004

Ball milling in organic synthesis: solutions and challenges journal, January 2011

Recent Development of Hypercrosslinked Microporous Organic Polymers journal, January 2013

New opportunities for materials synthesis using mechanochemistry journal, January 2010

Chemically Stable Multilayered Covalent Organic Nanosheets from Covalent Organic Frameworks via Mechanical Delamination journal, November 2013

Mechanochemistry: opportunities for new and cleaner synthesis journal, January 2012

Covalent organic frameworks journal, January 2012

Linear High Molecular Weight Ladder Polymers by Optimized Polycondensation of Tetrahydroxytetramethylspirobisindane and 1,4-Dicyanotetrafluorobenzene † journal, October 2008

Supramolecular concepts and new techniques in mechanochemistry: cocrystals, cages, rotaxanes, open metal–organic frameworks journal, January 2012

Supramolecular Catalysis in the Organic Solid State through Dry Grinding journal, May 2010

Conjugated porous polymers for energy applications journal, January 2012

Solvent-Free Synthesis of Silicoaluminophosphate Zeolites journal, July 2013

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Solution-Processed, Organophilic Membrane Derived from a Polymer of Intrinsic Microporosity journal, March 2004

Nanoporous organic polymer networks journal, April 2012

Mechanochemistry: The Mechanical Activation of Covalent Bonds journal, August 2005

Linear High Molecular Weight Ladder Polymer via Fast Polycondensation of 5,5′,6,6′-Tetrahydroxy-3,3,3′,3′-tetramethylspirobisindane with 1,4-Dicyanotetrafluorobenzene journal, May 2008

Synthesis and Gas Transport Properties of Hydroxyl-Functionalized Polyimides with Intrinsic Microporosity journal, April 2012

Green Routes for Synthesis of Zeolites journal, November 2013

Real-time and in situ monitoring of mechanochemical milling reactions journal, December 2012

Catalytic oxidation of sulphide ions using a novel microporous cobalt phthalocyanine network polymer in aqueous solution journal, April 2009

Mechanochemistry: The Mechanical Activation of Covalent Bonds journal, October 2005

Supramolecular Catalysis in the Organic Solid State through Dry Grinding journal, May 2010

Polymers of Intrinsic Microporosity (PIMs): Organic Materials for Membrane Separations, Heterogeneous Catalysis and Hydrogen Storage journal, November 2006

Solvent-Free Synthesis of Metal Complexes journal, August 2007

Entropy‐Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO 2 Fixation journal, March 2019

Entropy-Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO 2 Fixation journal, March 2019

Mechanochemical Synthesis of Ruthenium Cluster@Ordered Mesoporous Carbon Catalysts by Synergetic Dual Templates journal, May 2019

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journal, April 2012

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