Self-heating and failure in scalable graphene devices
Abstract
Self-heating induced failure of graphene devices synthesized from both chemical vapor deposition (CVD) and epitaxial means is compared using a combination of infrared thermography and Raman imaging. Despite a larger thermal resistance, CVD devices dissipate >3x the amount of power before failure than their epitaxial counterparts. Furthermore, the discrepancy arises due to morphological irregularities implicit to the graphene synthesis method that induce localized heating. Morphology, rather than thermal resistance, therefore dictates power handling limits in graphene devices.
- Authors:
-
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1262367
- Alternate Identifier(s):
- OSTI ID: 1338306
- Report Number(s):
- SAND-2016-3093J; SAND-2015-10741J
Journal ID: ISSN 2045-2322; srep26457
- Grant/Contract Number:
- AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 6; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; electronic properties and devices; synthesis and processing; 36 MATERIALS SCIENCE
Citation Formats
Beechem, Thomas E., Shaffer, Ryan A., Nogan, John, Ohta, Taisuke, Hamilton, Allister B., McDonald, Anthony E., and Howell, Stephen W.. Self-heating and failure in scalable graphene devices. United States: N. p., 2016.
Web. doi:10.1038/srep26457.
Beechem, Thomas E., Shaffer, Ryan A., Nogan, John, Ohta, Taisuke, Hamilton, Allister B., McDonald, Anthony E., & Howell, Stephen W.. Self-heating and failure in scalable graphene devices. United States. https://doi.org/10.1038/srep26457
Beechem, Thomas E., Shaffer, Ryan A., Nogan, John, Ohta, Taisuke, Hamilton, Allister B., McDonald, Anthony E., and Howell, Stephen W.. Thu .
"Self-heating and failure in scalable graphene devices". United States. https://doi.org/10.1038/srep26457. https://www.osti.gov/servlets/purl/1262367.
@article{osti_1262367,
title = {Self-heating and failure in scalable graphene devices},
author = {Beechem, Thomas E. and Shaffer, Ryan A. and Nogan, John and Ohta, Taisuke and Hamilton, Allister B. and McDonald, Anthony E. and Howell, Stephen W.},
abstractNote = {Self-heating induced failure of graphene devices synthesized from both chemical vapor deposition (CVD) and epitaxial means is compared using a combination of infrared thermography and Raman imaging. Despite a larger thermal resistance, CVD devices dissipate >3x the amount of power before failure than their epitaxial counterparts. Furthermore, the discrepancy arises due to morphological irregularities implicit to the graphene synthesis method that induce localized heating. Morphology, rather than thermal resistance, therefore dictates power handling limits in graphene devices.},
doi = {10.1038/srep26457},
journal = {Scientific Reports},
number = ,
volume = 6,
place = {United States},
year = {2016},
month = {6}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 19 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Ultrahigh electron mobility in suspended graphene
journal, June 2008
- Bolotin, K. I.; Sikes, K. J.; Jiang, Z.
- Solid State Communications, Vol. 146, Issue 9-10, p. 351-355
Thermal properties of graphene: Fundamentals and applications
journal, November 2012
- Pop, Eric; Varshney, Vikas; Roy, Ajit K.
- MRS Bulletin, Vol. 37, Issue 12
A roadmap for graphene
journal, October 2012
- Novoselov, K. S.; Fal′ko, V. I.; Colombo, L.
- Nature, Vol. 490, Issue 7419
Roll-to-roll production of 30-inch graphene films for transparent electrodes
journal, June 2010
- Bae, Sukang; Kim, Hyeongkeun; Lee, Youngbin
- Nature Nanotechnology, Vol. 5, Issue 8, p. 574-578
Wafer-Scale Graphene Integrated Circuit
journal, June 2011
- Lin, Y. -M.; Valdes-Garcia, A.; Han, S. -J.
- Science, Vol. 332, Issue 6035
Towards wafer-size graphene layers by atmospheric pressure graphitization of silicon carbide
journal, February 2009
- Emtsev, Konstantin V.; Bostwick, Aaron; Horn, Karsten
- Nature Materials, Vol. 8, Issue 3
Large-Area Graphene Single Crystals Grown by Low-Pressure Chemical Vapor Deposition of Methane on Copper
journal, March 2011
- Li, Xuesong; Magnuson, Carl W.; Venugopal, Archana
- Journal of the American Chemical Society, Vol. 133, Issue 9, p. 2816-2819
Role of carbon surface diffusion on the growth of epitaxial graphene on SiC
journal, March 2010
- Ohta, Taisuke; Bartelt, N. C.; Nie, Shu
- Physical Review B, Vol. 81, Issue 12
Atomic-scale transport in epitaxial graphene
journal, November 2011
- Ji, Shuai-Hua; Hannon, J. B.; Tromp, R. M.
- Nature Materials, Vol. 11, Issue 2
Cross-sectional imaging of individual layers and buried interfaces of graphene-based heterostructures and superlattices
journal, July 2012
- Haigh, S. J.; Gholinia, A.; Jalil, R.
- Nature Materials, Vol. 11, Issue 9
Rotational Disorder in Twisted Bilayer Graphene
journal, January 2014
- Beechem, Thomas E.; Ohta, Taisuke; Diaconescu, Bogdan
- ACS Nano, Vol. 8, Issue 2
Correlating Raman Spectral Signatures with Carrier Mobility in Epitaxial Graphene: A Guide to Achieving High Mobility on the Wafer Scale
journal, August 2009
- Robinson, Joshua A.; Wetherington, Maxwell; Tedesco, Joseph L.
- Nano Letters, Vol. 9, Issue 8
Strain and charge carrier coupling in epitaxial graphene
journal, December 2011
- Schmidt, Diedrich A.; Ohta, Taisuke; Beechem, Thomas E.
- Physical Review B, Vol. 84, Issue 23
Imaging, Simulation, and Electrostatic Control of Power Dissipation in Graphene Devices
journal, December 2010
- Bae, Myung-Ho; Ong, Zhun-Yong; Estrada, David
- Nano Letters, Vol. 10, Issue 12
Scaling of High-Field Transport and Localized Heating in Graphene Transistors
journal, September 2011
- Bae, Myung-Ho; Islam, Sharnali; Dorgan, Vincent E.
- ACS Nano, Vol. 5, Issue 10
Thermal emission from large area chemical vapor deposited graphene devices
journal, September 2013
- Luxmoore, I. J.; Adlem, C.; Poole, T.
- Applied Physics Letters, Vol. 103, Issue 13
Low-Frequency Acoustic Phonon Temperature Distribution in Electrically Biased Graphene
journal, January 2011
- Jo, Insun; Hsu, I-Kai; Lee, Yong J.
- Nano Letters, Vol. 11, Issue 1
Direct observation of resistive heating at graphene wrinkles and grain boundaries
journal, October 2014
- Grosse, Kyle L.; Dorgan, Vincent E.; Estrada, David
- Applied Physics Letters, Vol. 105, Issue 14
Thermally Limited Current Carrying Ability of Graphene Nanoribbons
journal, June 2011
- Liao, Albert D.; Wu, Justin Z.; Wang, Xinran
- Physical Review Letters, Vol. 106, Issue 25
Determination of the thermal diffusivity and conductivity of monocrystalline silicon carbide (300-2300 K)
journal, January 1997
- Nilsson, Ove; Mehling, Harald; Horn, Ronny
- High Temperatures-High Pressures, Vol. 29, Issue 1
Assessment of stress contributions in GaN high electron mobility transistors of differing substrates using Raman spectroscopy
journal, December 2009
- Beechem, Thomas; Christensen, Adam; Green, D. S.
- Journal of Applied Physics, Vol. 106, Issue 11
Thermal contact resistance between graphene and silicon dioxide
journal, October 2009
- Chen, Z.; Jang, W.; Bao, W.
- Applied Physics Letters, Vol. 95, Issue 16
Heat Conduction across Monolayer and Few-Layer Graphenes
journal, November 2010
- Koh, Yee Kan; Bae, Myung-Ho; Cahill, David G.
- Nano Letters, Vol. 10, Issue 11, p. 4363-4368
Measurement of the thermal conductance of the graphene/SiO2 interface
journal, November 2010
- Mak, Kin Fai; Lui, Chun Hung; Heinz, Tony F.
- Applied Physics Letters, Vol. 97, Issue 22
Manipulating Thermal Conductance at Metal–Graphene Contacts via Chemical Functionalization
journal, January 2012
- Hopkins, Patrick E.; Baraket, Mira; Barnat, Edward V.
- Nano Letters, Vol. 12, Issue 2
Analysis of heat dissipation of epitaxial graphene devices on SiC
journal, November 2014
- Lee, Kangmu; Moon, Jeong-Sun; Oh, Thomas
- Solid-State Electronics, Vol. 101
Quasi-Free-Standing Epitaxial Graphene on SiC Obtained by Hydrogen Intercalation
journal, December 2009
- Riedl, C.; Coletti, C.; Iwasaki, T.
- Physical Review Letters, Vol. 103, Issue 24
Magnetotransport Properties of Quasi-Free-Standing Epitaxial Graphene Bilayer on SiC: Evidence for Bernal Stacking
journal, September 2011
- Lee, Kayoung; Kim, Seyoung; Points, M. S.
- Nano Letters, Vol. 11, Issue 9
Enhanced Current Drivability of CVD Graphene Interconnect in Oxygen-Deficient Environment
journal, November 2011
- Kang, Chang Goo; Lee, Sang Kyung; Lee, Young Gon
- IEEE Electron Device Letters, Vol. 32, Issue 11
Breakdown current density of graphene nanoribbons
journal, June 2009
- Murali, Raghunath; Yang, Yinxiao; Brenner, Kevin
- Applied Physics Letters, Vol. 94, Issue 24
Structural evolution of graphene in air at the electrical breakdown limit
journal, April 2016
- Son, Jangyup; Choi, Minkyung; Choi, Heechae
- Carbon, Vol. 99
Current Saturation and Electrical Breakdown in Multiwalled Carbon Nanotubes
journal, April 2001
- Collins, Philip G.; Hersam, M.; Arnold, M.
- Physical Review Letters, Vol. 86, Issue 14
Graphene Oxidation: Thickness-Dependent Etching and Strong Chemical Doping
journal, July 2008
- Liu, Li; Ryu, Sunmin; Tomasik, Michelle R.
- Nano Letters, Vol. 8, Issue 7
Criteria for Cross-Plane Dominated Thermal Transport in Multilayer Thin Film Systems During Modulated Laser Heating
journal, May 2010
- Hopkins, Patrick E.; Serrano, Justin R.; Phinney, Leslie M.
- Journal of Heat Transfer, Vol. 132, Issue 8
Structural degradation of thermal on Si by high-temperature annealing: Defect generation
journal, July 2002
- Stesmans, A.; Nouwen, B.; Afanas’ev, V. V.
- Physical Review B, Vol. 66, Issue 4
Void and Nanostructure Formations during Thermal Decomposition of 20-nm-Thick Silicon Oxide Layer on Si(100)
journal, March 2013
- Enta, Yoshiharu; Ogawa, Kano; Nagai, Takayuki
- Japanese Journal of Applied Physics, Vol. 52, Issue 3R
SiO diffusion during thermal decomposition of SiO 2
journal, May 1990
- Sasse, H. ‐E.; König, U.
- Journal of Applied Physics, Vol. 67, Issue 10
High-Temperature Si Decomposition at the Si /Si Interface
journal, November 1985
- Tromp, R.; Rubloff, G. W.; Balk, P.
- Physical Review Letters, Vol. 55, Issue 21
Opening carbon nanotubes with oxygen and implications for filling
journal, April 1993
- Ajayan, P. M.; Ebbesen, T. W.; Ichihashi, T.
- Nature, Vol. 362, Issue 6420
Dielectric characteristics of Al2O3–HfO2 nanolaminates on Si(100)
journal, August 2002
- Cho, M. -H.; Roh, Y. S.; Whang, C. N.
- Applied Physics Letters, Vol. 81, Issue 6
Thermal Stability of a Thin HfO 2 /Ultrathin SiO 2 /Si Structure: Interfacial Si Oxidation and Silicidation
journal, February 2003
- Miyata, Noriyuki; Ichikawa, Masakazu; Nabatame, Toshihide
- Japanese Journal of Applied Physics, Vol. 42, Issue Part 2, No. 2B
Interfacial reaction depending on the stack structure of Al2O3 and HfO2 during film growth and postannealing
journal, November 2004
- Cho, M. -H.; Chung, K. B.; Chang, H. S.
- Applied Physics Letters, Vol. 85, Issue 18
Growth from below: bilayer graphene on copper by chemical vapor deposition
journal, September 2012
- Nie, Shu; Wu, Wei; Xing, Shirui
- New Journal of Physics, Vol. 14, Issue 9
Wafer-Scale Growth of Single-Crystal Monolayer Graphene on Reusable Hydrogen-Terminated Germanium
journal, April 2014
- Lee, J.-H.; Lee, E. K.; Joo, W.-J.
- Science, Vol. 344, Issue 6181, p. 286-289
The Role of Surface Oxygen in the Growth of Large Single-Crystal Graphene on Copper
journal, October 2013
- Hao, Y.; Bharathi, M. S.; Wang, L.
- Science, Vol. 342, Issue 6159
Long-range atomic ordering and variable interlayer interactions in two overlapping graphene lattices with stacking misorientations
journal, February 2012
- Ohta, Taisuke; Beechem, Thomas E.; Robinson, Jeremy T.
- Physical Review B, Vol. 85, Issue 7
Observation of the integer quantum Hall effect in high quality, uniform wafer-scale epitaxial graphene films
journal, December 2010
- Pan, Wei; Howell, Stephen W.; Ross, Anthony Joseph
- Applied Physics Letters, Vol. 97, Issue 25
Large-Area Graphene Single Crystals Grown by Low-Pressure Chemical Vapor Deposition of Methane on Copper
journal, March 2011
- Li, Xuesong; Magnuson, Carl W.; Venugopal, Archana
- Journal of the American Chemical Society, Vol. 133, Issue 9, p. 2816-2819
Imaging, Simulation, and Electrostatic Control of Power Dissipation in Graphene Devices
journal, December 2010
- Bae, Myung-Ho; Ong, Zhun-Yong; Estrada, David
- Nano Letters, Vol. 10, Issue 12
Low-Frequency Acoustic Phonon Temperature Distribution in Electrically Biased Graphene
journal, January 2011
- Jo, Insun; Hsu, I-Kai; Lee, Yong J.
- Nano Letters, Vol. 11, Issue 1
Scaling of High-Field Transport and Localized Heating in Graphene Transistors
journal, September 2011
- Bae, Myung-Ho; Islam, Sharnali; Dorgan, Vincent E.
- ACS Nano, Vol. 5, Issue 10
Rotational Disorder in Twisted Bilayer Graphene
journal, January 2014
- Beechem, Thomas E.; Ohta, Taisuke; Diaconescu, Bogdan
- ACS Nano, Vol. 8, Issue 2
A roadmap for graphene
journal, October 2012
- Novoselov, K. S.; Fal′ko, V. I.; Colombo, L.
- Nature, Vol. 490, Issue 7419
A decade of R2R graphene manufacturing
journal, October 2021
- Bubnova, Olga
- Nature Nanotechnology, Vol. 16, Issue 10
Thermal emission from large area chemical vapor deposited graphene devices
journal, September 2013
- Luxmoore, I. J.; Adlem, C.; Poole, T.
- Applied Physics Letters, Vol. 103, Issue 13
Electronic transport at monolayer-bilayer junctions in epitaxial graphene on SiC
journal, December 2012
- Giannazzo, F.; Deretzis, I.; La Magna, A.
- Physical Review B, Vol. 86, Issue 23
Raman Spectrum of Graphene and Graphene Layers
journal, October 2006
- Ferrari, A. C.; Meyer, J. C.; Scardaci, V.
- Physical Review Letters, Vol. 97, Issue 18, Article No. 187401
Wafer-Scale Graphene Integrated Circuit
journal, June 2011
- Lin, Y. -M.; Valdes-Garcia, A.; Han, S. -J.
- Science, Vol. 332, Issue 6035
Wafer-Scale Growth of Single-Crystal Monolayer Graphene on Reusable Hydrogen-Terminated Germanium
journal, April 2014
- Lee, J.-H.; Lee, E. K.; Joo, W.-J.
- Science, Vol. 344, Issue 6181, p. 286-289
Current Saturation and Electrical Breakdown in Multiwalled Carbon Nanotubes
text, January 2001
- Arnold, M.; Avouris, Ph.; Collins, Philip G.
- The American Physical Society
Graphene Oxidation: Thickness Dependent Etching and Strong Chemical Doping
text, January 2008
- Liu, Li; Ryu, Sunmin; Tomasik, Michelle R.
- arXiv
Heat Conduction across Monolayer and Few-Layer Graphenes
text, January 2010
- Koh, Yee Kan; Bae, Myung-Ho; Cahill, David G.
- arXiv
Thermally-Limited Current Carrying Ability of Graphene Nanoribbons
text, January 2011
- Liao, Albert D.; Wu, Justin Z.; Wang, Xinran
- arXiv
Works referencing / citing this record:
Electrical Transport and Power Dissipation in Aerosol-Jet-Printed Graphene Interconnects
journal, July 2018
- Pandhi, Twinkle; Kreit, Eric; Aga, Roberto
- Scientific Reports, Vol. 8, Issue 1
Nanoscale electro-thermal interactions in AlGaN/GaN high electron mobility transistors
journal, January 2020
- Chatterjee, Bikramjit; Dundar, Canberk; Beechem, Thomas E.
- Journal of Applied Physics, Vol. 127, Issue 4
Nonequilibrium excitations and transport of Dirac electrons in electric-field-driven graphene
journal, May 2018
- Li, Jiajun; Han, Jong E.
- Physical Review B, Vol. 97, Issue 20
Imaging of local structures affecting electrical transport properties of large graphene sheets by lock-in thermography
journal, February 2019
- Nakajima, H.; Morimoto, T.; Okigawa, Y.
- Science Advances, Vol. 5, Issue 2
Electrical Transport and Power Dissipation in Aerosol-Jet-Printed Graphene Interconnects
journal, July 2018
- Pandhi, Twinkle; Kreit, Eric; Aga, Roberto
- Scientific Reports, Vol. 8, Issue 1
Imaging of local structures affecting electrical transport properties of large graphene sheets by lock-in thermography
journal, February 2019
- Nakajima, H.; Morimoto, T.; Okigawa, Y.
- Science Advances, Vol. 5, Issue 2