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Title: Nanoscale mapping of heterogeneity of the polarization reversal in lead-free relaxor–ferroelectric ceramic composites

Abstract

Relaxor/ferroelectric ceramic/ceramic composites have shown to be promising in generating large electromechanical strain at moderate electric fields. However, the mechanisms of polarization and strain coupling between grains of different nature in the composites remain unclear. To rationalize the coupling mechanisms we performed advanced piezoresponse force microscopy (PFM) studies of 0.92BNT-0.06BT-0.02KNN/0.93BNT-0.07BT (ergodic/non-ergodic relaxor) composites. PFM is able to distinguish grains of different phases by characteristic domain patterns. Polarization switching has been probed locally, on a sub-grain scale. k-Means clustering analysis applied to arrays of local hysteresis loops reveals variations of polarization switching characteristics between the ergodic and non-ergodic relaxor grains. Here, we report a different set of switching parameters for grains in the composites as opposed to the pure phase samples. These results confirm ceramic/ceramic composites to be a viable approach to tailor the piezoelectric properties and optimize the macroscopic electromechanical characteristics.

Authors:
 [1];  [1];  [2];  [2];  [2];  [2];  [3];  [3];  [1]
  1. Univ. of Duisburg, Essen (Germany)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Technical Univ. of Darmstadt (Germany)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE; European Commission (EC)
OSTI Identifier:
1261507
Grant/Contract Number:  
AC05-00OR22725; 290158
Resource Type:
Accepted Manuscript
Journal Name:
Nanoscale
Additional Journal Information:
Journal Volume: 8; Journal Issue: 4; Journal ID: ISSN 2040-3364
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Gobeljic, D., Shvartsman, V. V., Belianinov, A., Okatan, B., Jesse, S., Kalinin, S. V., Groh, C., Rödel, J., and Lupascu, D. C. Nanoscale mapping of heterogeneity of the polarization reversal in lead-free relaxor–ferroelectric ceramic composites. United States: N. p., 2016. Web. doi:10.1039/c5nr05032d.
Gobeljic, D., Shvartsman, V. V., Belianinov, A., Okatan, B., Jesse, S., Kalinin, S. V., Groh, C., Rödel, J., & Lupascu, D. C. Nanoscale mapping of heterogeneity of the polarization reversal in lead-free relaxor–ferroelectric ceramic composites. United States. https://doi.org/10.1039/c5nr05032d
Gobeljic, D., Shvartsman, V. V., Belianinov, A., Okatan, B., Jesse, S., Kalinin, S. V., Groh, C., Rödel, J., and Lupascu, D. C. Tue . "Nanoscale mapping of heterogeneity of the polarization reversal in lead-free relaxor–ferroelectric ceramic composites". United States. https://doi.org/10.1039/c5nr05032d. https://www.osti.gov/servlets/purl/1261507.
@article{osti_1261507,
title = {Nanoscale mapping of heterogeneity of the polarization reversal in lead-free relaxor–ferroelectric ceramic composites},
author = {Gobeljic, D. and Shvartsman, V. V. and Belianinov, A. and Okatan, B. and Jesse, S. and Kalinin, S. V. and Groh, C. and Rödel, J. and Lupascu, D. C.},
abstractNote = {Relaxor/ferroelectric ceramic/ceramic composites have shown to be promising in generating large electromechanical strain at moderate electric fields. However, the mechanisms of polarization and strain coupling between grains of different nature in the composites remain unclear. To rationalize the coupling mechanisms we performed advanced piezoresponse force microscopy (PFM) studies of 0.92BNT-0.06BT-0.02KNN/0.93BNT-0.07BT (ergodic/non-ergodic relaxor) composites. PFM is able to distinguish grains of different phases by characteristic domain patterns. Polarization switching has been probed locally, on a sub-grain scale. k-Means clustering analysis applied to arrays of local hysteresis loops reveals variations of polarization switching characteristics between the ergodic and non-ergodic relaxor grains. Here, we report a different set of switching parameters for grains in the composites as opposed to the pure phase samples. These results confirm ceramic/ceramic composites to be a viable approach to tailor the piezoelectric properties and optimize the macroscopic electromechanical characteristics.},
doi = {10.1039/c5nr05032d},
journal = {Nanoscale},
number = 4,
volume = 8,
place = {United States},
year = {2016},
month = {1}
}

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Works referenced in this record:

Piezoelectric actuators 2006: Expansion from IT/robotics to ecological/energy applications
journal, July 2007


Dynamics of ferroelastic domains in ferroelectric thin films
journal, December 2002

  • Nagarajan, V.; Roytburd, A.; Stanishevsky, A.
  • Nature Materials, Vol. 2, Issue 1
  • DOI: 10.1038/nmat800

The influence of microstructure on the properties of ferroelectric ceramics
journal, April 1990


Transferring lead-free piezoelectric ceramics into application
journal, June 2015


Giant strain in lead-free piezoceramics Bi0.5Na0.5TiO3–BaTiO3–K0.5Na0.5NbO3 system
journal, September 2007

  • Zhang, Shan-Tao; Kounga, Alain Brice; Aulbach, Emil
  • Applied Physics Letters, Vol. 91, Issue 11
  • DOI: 10.1063/1.2783200

Perspective on the Development of Lead-free Piezoceramics
journal, June 2009


Origin of the large strain response in (K0.5Na0.5)NbO3-modified (Bi0.5Na0.5)TiO3–BaTiO3 lead-free piezoceramics
journal, May 2009

  • Jo, Wook; Granzow, Torsten; Aulbach, Emil
  • Journal of Applied Physics, Vol. 105, Issue 9
  • DOI: 10.1063/1.3121203

Electric field-induced deformation behavior in mixed Bi 0.5 Na 0.5 TiO 3 and Bi 0.5 (Na 0.75 K 0.25 ) 0.5 TiO 3 -BiAlO 3
journal, August 2011

  • Lee, Dae Su; Lim, Dong Hwan; Kim, Min Soo
  • Applied Physics Letters, Vol. 99, Issue 6
  • DOI: 10.1063/1.3621878

Gigantic Electrostrain in Duplex Structured Alkaline Niobates
journal, August 2012

  • Choi, Si-Young; Jeong, Soon-Jong; Lee, Dae-Su
  • Chemistry of Materials, Vol. 24, Issue 17
  • DOI: 10.1021/cm301324h

Electric field induced polarization and strain of Bi-based ceramic composites
journal, December 2012

  • Su Lee, Dae; Jong Jeong, Soon; Soo Kim, Min
  • Journal of Applied Physics, Vol. 112, Issue 12
  • DOI: 10.1063/1.4770372

Relaxor/Ferroelectric Composites: A Solution in the Quest for Practically Viable Lead-Free Incipient Piezoceramics
journal, September 2013

  • Groh, Claudia; Franzbach, Daniel J.; Jo, Wook
  • Advanced Functional Materials, Vol. 24, Issue 3
  • DOI: 10.1002/adfm.201302102

Tailoring Strain Properties of (0.94− x )Bi 1/2 Na 1/2 TiO 3 -0.06BaTiO 3 - x K 0.5 Na 0.5 NbO 3 Ferroelectric/Relaxor Composites
journal, January 2014

  • Groh, Claudia; Jo, Wook; Rödel, Jürgen
  • Journal of the American Ceramic Society, Vol. 97, Issue 5
  • DOI: 10.1111/jace.12783

Tailoring of unipolar strain in lead-free piezoelectrics using the ceramic/ceramic composite approach
journal, March 2014

  • Khansur, Neamul H.; Groh, Claudia; Jo, Wook
  • Journal of Applied Physics, Vol. 115, Issue 12
  • DOI: 10.1063/1.4869786

Large Strain in Relaxor/Ferroelectric Composite Lead-Free Piezoceramics
journal, April 2015

  • Zhang, Haibo; Groh, Claudia; Zhang, Qi
  • Advanced Electronic Materials, Vol. 1, Issue 6
  • DOI: 10.1002/aelm.201500018

Local polarization dynamics in ferroelectric materials
journal, April 2010

  • Kalinin, Sergei V.; Morozovska, Anna N.; Chen, Long Qing
  • Reports on Progress in Physics, Vol. 73, Issue 5, Article No. 056502
  • DOI: 10.1088/0034-4885/73/5/056502

WSXM : A software for scanning probe microscopy and a tool for nanotechnology
journal, January 2007

  • Horcas, I.; Fernández, R.; Gómez-Rodríguez, J. M.
  • Review of Scientific Instruments, Vol. 78, Issue 1
  • DOI: 10.1063/1.2432410

Dynamic piezoresponse force microscopy: Spatially resolved probing of polarization dynamics in time and voltage domains
journal, September 2012

  • Kumar, A.; Ehara, Y.; Wada, A.
  • Journal of Applied Physics, Vol. 112, Issue 5
  • DOI: 10.1063/1.4746080

Ferroelectric domain structure of PbZr 0.35 Ti 0.65 O 3 single crystals by piezoresponse force microscopy
journal, September 2011

  • Bdikin, I. K.; Pérez, J. A.; Coondoo, I.
  • Journal of Applied Physics, Vol. 110, Issue 5
  • DOI: 10.1063/1.3623768

Nanopolar structures and local ferroelectricity of Sr0.61Ba0.39Nb2O6 relaxor crystal across Curie temperature by piezoresponse force microscopy
journal, December 2009

  • Liu, X. Y.; Liu, Y. M.; Takekawa, S.
  • Journal of Applied Physics, Vol. 106, Issue 12
  • DOI: 10.1063/1.3273481

Nanoscale domain growth dynamics of ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) thin films
journal, January 2010

  • Kim, Yunseok; Kim, Wooyoung; Choi, Hyunwoo
  • Applied Physics Letters, Vol. 96, Issue 1
  • DOI: 10.1063/1.3290247

Deep Data Analysis of Conductive Phenomena on Complex Oxide Interfaces: Physics from Data Mining
journal, May 2014

  • Strelcov, Evgheni; Belianinov, Alexei; Hsieh, Ying-Hui
  • ACS Nano, Vol. 8, Issue 6
  • DOI: 10.1021/nn502029b

Classification of laminate domain patterns in ferroelectrics
journal, May 2011


Mesoscale Domains and Nature of the Relaxor State by Piezoresponse Force Microscopy
journal, July 2013


Surface Domain Structures and Mesoscopic Phase Transition in Relaxor Ferroelectrics
journal, April 2011

  • Kholkin, Andrei; Morozovska, Anna; Kiselev, Dmitry
  • Advanced Functional Materials, Vol. 21, Issue 11
  • DOI: 10.1002/adfm.201002582

The anomalous skin effect in single crystal relaxor ferroelectric PZN- x PT and PMN- x PT
journal, January 2006


Evolution of the Polar Structure in Relaxor Ferroelectrics Close to the Curie Temperature Studied by Piezoresponse Force Microscopy
journal, November 2008


Macroscopic and local piezoelectric properties of Pb(Mg 1/3 Nb 2/3 )O 3 -PbTiO 3 single crystals exhibiting giant piezoelectric response
journal, May 2013

  • Shvartsman, V. V.; Kholkin, A. L.; Raevski, I. P.
  • Journal of Applied Physics, Vol. 113, Issue 18
  • DOI: 10.1063/1.4801964

Real space mapping of polarization dynamics and hysteresis loop formation in relaxor-ferroelectric PbMg1/3Nb2/3O3–PbTiO3 solid solutions
journal, August 2010

  • Rodriguez, B. J.; Jesse, S.; Morozovska, A. N.
  • Journal of Applied Physics, Vol. 108, Issue 4
  • DOI: 10.1063/1.3474961

Works referencing / citing this record:

Tailoring the strain performance of lead-free relaxor/ferroelectric-layered composites
journal, January 2020


Switching properties of epitaxial La 0.5 Sr 0.5 CoO 3 /Na 0.5 Bi 0.5 TiO 3 /La 0.5 Sr 0.5 CoO 3 ferroelectric capacitor
journal, January 2018

  • Song, J. M.; Luo, L. H.; Dai, X. H.
  • RSC Advances, Vol. 8, Issue 8
  • DOI: 10.1039/c7ra12575e

Electrostatic contribution to hysteresis loop in piezoresponse force microscopy
journal, April 2019

  • Qiao, Huimin; Seol, Daehee; Sun, Changhyo
  • Applied Physics Letters, Vol. 114, Issue 15
  • DOI: 10.1063/1.5090591

Investigations of ferroelectric polycrystalline bulks and thick films using piezoresponse force microscopy
journal, March 2019

  • Uršič, Hana; Prah, Uroš
  • Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 475, Issue 2223
  • DOI: 10.1098/rspa.2018.0782

Structure and Electrical Properties of Na0.5Bi0.5TiO3 Epitaxial Films with (110) Orientation
journal, October 2019