Low-Temperature Synthesis, Structural Characterization, and Electrochemistry of Ni-Rich Spinel-like LiNi2–yMnyO4 (0.4 ≤ y ≤ 1)
Abstract
The thermal conversion of chemically delithiated layered Li0.5Ni1–yMnyO2 (0.2 ≤ y ≤ 0.5) into spinel-like LiNi2–yMnyO4 (0.4 ≤ y ≤ 1) has been systematically investigated in this paper. The formed spinel-like phases are metastable and cannot be accessed by a conventional high-temperature solid-state method. The layered-to-spinel transformation mechanism has been studied by the Rietveld refinement of in situ neutron diffraction as a function of temperature (25–300 °C). In particular, the ionic diffusion of Li and M ions is quantified at different temperatures. Electrochemistry of the metastable spinel-like phases obtained has been studied in lithium-ion cells. A bond valence sum map has been performed to understand the ionic diffusion of lithium ions in the Ni-rich layered, spinel, and rock-salt structures. Finally, the study can aid the understanding of the possible phases that could be formed during the cycling of Ni-rich layered oxide cathodes.
- Authors:
-
- Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program. Texas Materials Inst.
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Science Division
- Publication Date:
- Research Org.:
- Univ. of Texas, Austin, TX (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Welch Foundation (United States)
- OSTI Identifier:
- 1261485
- Grant/Contract Number:
- AC05-00OR22725; AC02-06CH11357; DMR-1122603
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry of Materials
- Additional Journal Information:
- Journal Volume: 27; Journal Issue: 22; Journal ID: ISSN 0897-4756
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Kan, Wang Hay, Huq, Ashfia, and Manthiram, Arumugam. Low-Temperature Synthesis, Structural Characterization, and Electrochemistry of Ni-Rich Spinel-like LiNi2–yMnyO4 (0.4 ≤ y ≤ 1). United States: N. p., 2015.
Web. doi:10.1021/acs.chemmater.5b03360.
Kan, Wang Hay, Huq, Ashfia, & Manthiram, Arumugam. Low-Temperature Synthesis, Structural Characterization, and Electrochemistry of Ni-Rich Spinel-like LiNi2–yMnyO4 (0.4 ≤ y ≤ 1). United States. https://doi.org/10.1021/acs.chemmater.5b03360
Kan, Wang Hay, Huq, Ashfia, and Manthiram, Arumugam. Wed .
"Low-Temperature Synthesis, Structural Characterization, and Electrochemistry of Ni-Rich Spinel-like LiNi2–yMnyO4 (0.4 ≤ y ≤ 1)". United States. https://doi.org/10.1021/acs.chemmater.5b03360. https://www.osti.gov/servlets/purl/1261485.
@article{osti_1261485,
title = {Low-Temperature Synthesis, Structural Characterization, and Electrochemistry of Ni-Rich Spinel-like LiNi2–yMnyO4 (0.4 ≤ y ≤ 1)},
author = {Kan, Wang Hay and Huq, Ashfia and Manthiram, Arumugam},
abstractNote = {The thermal conversion of chemically delithiated layered Li0.5Ni1–yMnyO2 (0.2 ≤ y ≤ 0.5) into spinel-like LiNi2–yMnyO4 (0.4 ≤ y ≤ 1) has been systematically investigated in this paper. The formed spinel-like phases are metastable and cannot be accessed by a conventional high-temperature solid-state method. The layered-to-spinel transformation mechanism has been studied by the Rietveld refinement of in situ neutron diffraction as a function of temperature (25–300 °C). In particular, the ionic diffusion of Li and M ions is quantified at different temperatures. Electrochemistry of the metastable spinel-like phases obtained has been studied in lithium-ion cells. A bond valence sum map has been performed to understand the ionic diffusion of lithium ions in the Ni-rich layered, spinel, and rock-salt structures. Finally, the study can aid the understanding of the possible phases that could be formed during the cycling of Ni-rich layered oxide cathodes.},
doi = {10.1021/acs.chemmater.5b03360},
journal = {Chemistry of Materials},
number = 22,
volume = 27,
place = {United States},
year = {Wed Oct 28 00:00:00 EDT 2015},
month = {Wed Oct 28 00:00:00 EDT 2015}
}
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Works referencing / citing this record:
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