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Title: The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe 3P 5SiO 19

We report the synthesis, structure, and electrochemistry of the first Na +-ion cathode with two distinct types of polyanions: Fe 3P 5SiO 19. The Fe-based cathode has a reversible capacity of ca. 70 mAh g -1; ca. 1.7 Na + ions per formula can be inserted/extracted at an average voltage of 2.5 V versus Na +/Na.
Authors:
 [1] ;  [2] ;  [1]
  1. Univ. of Texas at Austin, Austin, TX (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Science Division
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 51; Journal Issue: 52; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
Sponsoring Org:
USDOE: NSF
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1261442

Kan, W. H., Huq, A., and Manthiram, A.. The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19. United States: N. p., Web. doi:10.1039/C5CC03070F.
Kan, W. H., Huq, A., & Manthiram, A.. The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19. United States. doi:10.1039/C5CC03070F.
Kan, W. H., Huq, A., and Manthiram, A.. 2015. "The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19". United States. doi:10.1039/C5CC03070F. https://www.osti.gov/servlets/purl/1261442.
@article{osti_1261442,
title = {The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19},
author = {Kan, W. H. and Huq, A. and Manthiram, A.},
abstractNote = {We report the synthesis, structure, and electrochemistry of the first Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19. The Fe-based cathode has a reversible capacity of ca. 70 mAh g-1; ca. 1.7 Na+ ions per formula can be inserted/extracted at an average voltage of 2.5 V versus Na+/Na.},
doi = {10.1039/C5CC03070F},
journal = {ChemComm},
number = 52,
volume = 51,
place = {United States},
year = {2015},
month = {5}
}

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Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
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