[Cu32(H)20{S2P(O i Pr)2 }12 ]: The Largest Number of Hydrides Recorded in a Molecular Nanocluster by Neutron Diffraction
Abstract
An air- and moisture-stable nanoscale polyhydrido copper cluster [Cu32(H)20{S2P(O i Pr)2 }12 ] (1H) was synthesized and structurally characterized. The molecular structure of 1H exhibits a hexacapped pseudo-rhombohedral core of 14 Cu atoms sandwiched between two nestlike triangular cupola fragments of (2x9) Cu atoms in an elongated triangular gyrobicupola polyhedron. The discrete Cu32 cluster is stabilized by 12 dithiophosphate ligands and a record number of 20 hydride ligands, which were found by high-resolution neutron diffraction to exhibit tri-, tetra-, and pentacoordinated hydrides in capping and interstitial modes. We conclude that this result was further supported by a density functional theory investigation on the simplified model [Cu32(H)20(S2PH2)12].
- Authors:
-
- National Dong Hwa Univ., Shoufeng (Taiwan)
- Univ. de Rennes, Rennes (France). Inst. of Chemical Sciences
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Materials Division
- Academia Sinica Nankang, Taipei (Taiwan). Inst.of Chemistry
- Univ. of KwaZulu-Natal, Durban (South Africa). School of Chemistry and Physics,
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Ministry of Science and Technology of Taiwan
- OSTI Identifier:
- 1261439
- Grant/Contract Number:
- AC05-00OR22725; MOST 103-2113-M-259-003-MY3
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Volume: 21; Journal Issue: 23; Journal ID: ISSN 0947-6539
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; cluster compounds; copper; density functional calculations; hydrides; neutron diffraction; copper cluster; X-ray crystal structure; ligands
Citation Formats
Dhayal, Rajendra S., Liao, Jian-Hong, Kahlal, Samia, Wang, Xiaoping, Liu, Yu-Chiao, Chiang, Ming-Hsi, van Zyl, Werner E., Saillard, Jean-Yves, and Liu, C. W. [Cu32(H)20{S2P(O i Pr)2 }12 ]: The Largest Number of Hydrides Recorded in a Molecular Nanocluster by Neutron Diffraction. United States: N. p., 2015.
Web. doi:10.1002/chem.201501122.
Dhayal, Rajendra S., Liao, Jian-Hong, Kahlal, Samia, Wang, Xiaoping, Liu, Yu-Chiao, Chiang, Ming-Hsi, van Zyl, Werner E., Saillard, Jean-Yves, & Liu, C. W. [Cu32(H)20{S2P(O i Pr)2 }12 ]: The Largest Number of Hydrides Recorded in a Molecular Nanocluster by Neutron Diffraction. United States. https://doi.org/10.1002/chem.201501122
Dhayal, Rajendra S., Liao, Jian-Hong, Kahlal, Samia, Wang, Xiaoping, Liu, Yu-Chiao, Chiang, Ming-Hsi, van Zyl, Werner E., Saillard, Jean-Yves, and Liu, C. W. Mon .
"[Cu32(H)20{S2P(O i Pr)2 }12 ]: The Largest Number of Hydrides Recorded in a Molecular Nanocluster by Neutron Diffraction". United States. https://doi.org/10.1002/chem.201501122. https://www.osti.gov/servlets/purl/1261439.
@article{osti_1261439,
title = {[Cu32(H)20{S2P(O i Pr)2 }12 ]: The Largest Number of Hydrides Recorded in a Molecular Nanocluster by Neutron Diffraction},
author = {Dhayal, Rajendra S. and Liao, Jian-Hong and Kahlal, Samia and Wang, Xiaoping and Liu, Yu-Chiao and Chiang, Ming-Hsi and van Zyl, Werner E. and Saillard, Jean-Yves and Liu, C. W.},
abstractNote = {An air- and moisture-stable nanoscale polyhydrido copper cluster [Cu32(H)20{S2P(O i Pr)2 }12 ] (1H) was synthesized and structurally characterized. The molecular structure of 1H exhibits a hexacapped pseudo-rhombohedral core of 14 Cu atoms sandwiched between two nestlike triangular cupola fragments of (2x9) Cu atoms in an elongated triangular gyrobicupola polyhedron. The discrete Cu32 cluster is stabilized by 12 dithiophosphate ligands and a record number of 20 hydride ligands, which were found by high-resolution neutron diffraction to exhibit tri-, tetra-, and pentacoordinated hydrides in capping and interstitial modes. We conclude that this result was further supported by a density functional theory investigation on the simplified model [Cu32(H)20(S2PH2)12].},
doi = {10.1002/chem.201501122},
journal = {Chemistry - A European Journal},
number = 23,
volume = 21,
place = {United States},
year = {Mon Apr 20 00:00:00 EDT 2015},
month = {Mon Apr 20 00:00:00 EDT 2015}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Copper polyhydrides
journal, December 1985
- Lemmen, Timothy H.; Folting, Kirsten; Huffman, John C.
- Journal of the American Chemical Society, Vol. 107, Issue 25
Electron Transfer from Hexameric Copper Hydrides
journal, November 2013
- Eberhart, Michael S.; Norton, Jack R.; Zuzek, Ashley
- Journal of the American Chemical Society, Vol. 135, Issue 46
Ein thermisch stabiles Gold(III)-Hydrid: Synthese, Reaktivität und reduktive Kondensation als Weg zu Gold(II)-Komplexen
journal, September 2012
- Roşca, Dragoş-Adrian; Smith, Dan A.; Hughes, David L.
- Angewandte Chemie, Vol. 124, Issue 42
[Ag 7 (H){E 2 P(OR) 2 } 6 ] (E = Se, S): Precursors for the Fabrication of Silver Nanoparticles
journal, January 2013
- Liu, C. W.; Lin, Yan-Ru; Fang, Ching-Shiang
- Inorganic Chemistry, Vol. 52, Issue 4
Chinese Puzzle Molecule: A 15 Hydride, 28 Copper Atom Nanoball
journal, May 2014
- Edwards, Alison J.; Dhayal, Rajendra S.; Liao, Ping‐Kuei
- Angewandte Chemie, Vol. 126, Issue 28
Synthesis, Structure, and Alkyne Reactivity of a Dimeric (Carbene)copper(I) Hydride
journal, July 2004
- Mankad, Neal P.; Laitar, David S.; Sadighi, Joseph P.
- Organometallics, Vol. 23, Issue 14, p. 3369-3371
Au 20 Nanocluster Protected by Hemilabile Phosphines
journal, August 2012
- Wan, Xian-Kai; Lin, Zhi-Wei; Wang, Quan-Ming
- Journal of the American Chemical Society, Vol. 134, Issue 36
Total Structure and Electronic Properties of the Gold Nanocrystal Au 36 (SR) 24
journal, November 2012
- Zeng, Chenjie; Qian, Huifeng; Li, Tao
- Angewandte Chemie International Edition, Vol. 51, Issue 52
Facile Self-Assembly Synthesis and Characterization of Diselenophosphinato Octanuclear Cu I Clusters Inscribed in a Twelve-Vertex Selenium Polyhedron
journal, August 2012
- Liao, Ping-Kuei; Shi, De-Ren; Liao, Jian-Hong
- European Journal of Inorganic Chemistry, Vol. 2012, Issue 30
The gold–sulfur interface at the nanoscale
journal, May 2012
- Häkkinen, Hannu
- Nature Chemistry, Vol. 4, Issue 6
Phosphinothiolates as Ligands for Polyhydrido Copper Nanoclusters
journal, October 2014
- Huertos, Miguel A.; Cano, Israel; Bandeira, Nuno A. G.
- Chemistry - A European Journal, Vol. 20, Issue 49
Gold(I) Hydride Intermediate in Catalysis: Dehydrogenative Alcohol Silylation Catalyzed by Gold(I) Complex
journal, August 2009
- Ito, Hajime; Saito, Tomohisa; Miyahara, Takahiro
- Organometallics, Vol. 28, Issue 16
Synthesis, Structure and Gas-Phase Reactivity of a Silver Hydride Complex [Ag3{(PPh2)2CH2}3(μ3-H)(μ3-Cl)]BF4
journal, June 2013
- Zavras, Athanasios; Khairallah, George N.; Connell, Timothy U.
- Angewandte Chemie International Edition, Vol. 52, Issue 32, p. 8391-8394
Five-Coordinate Hydrogen: Neutron Diffraction Analysis of the Hydrido Cluster Complex [H2Rh13(CO)24]3-
journal, February 1997
- Bau, R.
- Science, Vol. 275, Issue 5303
Unexpected Reactivities of Cu 2 (diphosphine) 2 Complexes in Alcohol: Isolation, X-ray Crystal Structure, and Photoluminescent Properties of a Remarkably Stable [Cu 3 (diphosphine) 3 ( μ 3 -H)] 2+ Hydride Complex
journal, April 2005
- Mao, Zhong; Huang, Jie-Sheng; Che, Chi-Ming
- Journal of the American Chemical Society, Vol. 127, Issue 13
Stable Silver(I) Hydride Complexes Supported by Diselenophosphate Ligands
journal, January 2010
- Liu, C. W.; Chang, Hao-Wei; Sarkar, Bijay
- Inorganic Chemistry, Vol. 49, Issue 2
Electronic and Optical Properties of Chemically Modified Metal Nanoparticles and Molecularly Bridged Nanoparticle Arrays
journal, September 2000
- McConnell, Wyatt P.; Novak, James P.; Brousseau, Louis C.
- The Journal of Physical Chemistry B, Vol. 104, Issue 38
A dinuclear silver hydride and an umpolung reaction of CO2
journal, January 2013
- Tate, Brandon K.; Wyss, Chelsea M.; Bacsa, John
- Chemical Science, Vol. 4, Issue 8
Atomically precise gold nanocrystal molecules with surface plasmon resonance
journal, January 2012
- Qian, H.; Zhu, Y.; Jin, R.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 3
Hydrido Copper Clusters Supported by Dithiocarbamates: Oxidative Hydride Removal and Neutron Diffraction Analysis of [Cu 7 (H){S 2 C(aza-15-crown-5)} 6 ]
journal, June 2012
- Liao, Ping-Kuei; Fang, Ching-Shiang; Edwards, Alison J.
- Inorganic Chemistry, Vol. 51, Issue 12
Reduction of lactams and thiolactams by sodium borohydride. Application in the synthesis of some alkaloids
journal, September 1988
- Mandal, S. B.; Giri, V. S.; Sabeena, M. S.
- The Journal of Organic Chemistry, Vol. 53, Issue 18
Neutron diffraction structure analysis of a hexanuclear copper hydrido complex, H6Cu6[P(p-tolyl)3]6: an unexpected finding
journal, April 1989
- Stevens, Raymond C.; McLean, Malcolm R.; Bau, Robert
- Journal of the American Chemical Society, Vol. 111, Issue 9
Polyhedra in (inorganic) chemistry
journal, January 2005
- Alvarez, Santiago
- Dalton Transactions, Issue 13
Ultrastable silver nanoparticles
journal, September 2013
- Desireddy, Anil; Conn, Brian E.; Guo, Jingshu
- Nature, Vol. 501, Issue 7467
CuH-Catalyzed Reactions
journal, August 2008
- Deutsch, Carl; Krause, Norbert; Lipshutz, Bruce H.
- Chemical Reviews, Vol. 108, Issue 8
Preparation and crystallographic characterization of a hexameric triphenylphosphinecopper hydride cluster
journal, April 1971
- Bezman, Susan A.; Churchill, Melvyn R.; Osborn, John A.
- Journal of the American Chemical Society, Vol. 93, Issue 8
Near-IR Luminescence of Monolayer-Protected Metal Clusters
journal, January 2005
- Wang, Gangli; Huang, Tao; Murray, Royce W.
- Journal of the American Chemical Society, Vol. 127, Issue 3
High Hydride Count Rhodium Octahedra, [Rh 6 (PR 3 ) 6 H 12 ][BAr F 4 ] 2 : Synthesis, Structures, and Reversible Hydrogen Uptake under Mild Conditions
journal, May 2006
- Brayshaw, Simon K.; Ingleson, Michael J.; Green, Jennifer C.
- Journal of the American Chemical Society, Vol. 128, Issue 18
Bonding and Reactivity of a μ-Hydrido Dicopper Cation
journal, October 2013
- Wyss, Chelsea M.; Tate, Brandon K.; Bacsa, John
- Angewandte Chemie, Vol. 125, Issue 49
Phosphonate- and Ester-Substituted 2-Cyanoethylene-1,1-Dithiolate Clusters of Zinc: Aerial CO 2 Fixation and Unusual Binding Patterns
journal, April 2008
- Sarkar, Bijay; Liaw, Ben-Jie; Fang, Ching-Shiang
- Inorganic Chemistry, Vol. 47, Issue 7
Total Structure and Electronic Properties of the Gold Nanocrystal Au 36 (SR) 24
journal, November 2012
- Zeng, Chenjie; Qian, Huifeng; Li, Tao
- Angewandte Chemie, Vol. 124, Issue 52
"Coulomb Staircase" at Room Temperature in a Self-Assembled Molecular Nanostructure
journal, May 1996
- Andres, R. P.; Bein, T.; Dorogi, M.
- Science, Vol. 272, Issue 5266
Synthesis, structure, and spectroscopic properties of copper( II ) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper( II ) perchlorate
journal, January 1984
- Addison, Anthony W.; Rao, T. Nageswara; Reedijk, Jan
- J. Chem. Soc., Dalton Trans., Issue 7
Neutron Diffraction Studies of a Four-Coordinated Hydride in Near Square-Planar Geometry
journal, September 2014
- Liao, Jian-Hong; Dhayal, Rajendra Singh; Wang, Xiaoping
- Inorganic Chemistry, Vol. 53, Issue 20
Anion Encapsulation and Geometric Changes in Hepta- and Hexanuclear Copper(I) Dichalcogeno Clusters: A Theoretical and Experimental Investigation
journal, October 2013
- Latouche, Camille; Kahlal, Samia; Lin, Yan-Ru
- Inorganic Chemistry, Vol. 52, Issue 22
A Copper(I) Homocubane Collapses to a Tetracapped Tetrahedron Upon Hydride Insertion
journal, September 2011
- Liao, Ping-Kuei; Liu, Kuan-Guan; Fang, Ching-Shiang
- Inorganic Chemistry, Vol. 50, Issue 17
[Ag 21 {S 2 P(O i Pr) 2 } 12 ] + : An Eight-Electron Superatom
journal, January 2015
- Dhayal, Rajendra S.; Liao, Jian-Hong; Liu, Yu-Chiao
- Angewandte Chemie International Edition, Vol. 54, Issue 12
Reactions of a Stable Monomeric Gold(I) Hydride Complex
journal, November 2008
- Tsui, Emily Y.; Müller, Peter; Sadighi, Joseph P.
- Angewandte Chemie, Vol. 120, Issue 46
An eleven-vertex deltahedron with hexacapped trigonal bipyramidal geometry
journal, January 2011
- Liu, C. W.; Liao, Ping-Kuei; Fang, Ching-Shiang
- Chemical Communications, Vol. 47, Issue 20
Functional gold nanoparticles for recognition and catalysis
journal, January 2004
- Pasquato, Lucia; Pengo, Paolo; Scrimin, Paolo
- Journal of Materials Chemistry, Vol. 14, Issue 24
Cationic Dimetallic Gold Hydride Complex Stabilized by a Xantphos-Phosphole ligand: Synthesis, X-ray Crystal Structure, and Density Functional Theory Study
journal, September 2009
- Escalle, Aurélie; Mora, Guilhem; Gagosz, Fabien
- Inorganic Chemistry, Vol. 48, Issue 17
Facile Entrapment of a Hydride inside the Tetracapped Tetrahedral Cu I 8 Cage Inscribed in a S 12 Icosahedral Framework
journal, May 2009
- Liao, Ping-Kuei; Sarkar, Bijay; Chang, Hao-Wei
- Inorganic Chemistry, Vol. 48, Issue 9
Facile Insertion of Carbon Dioxide into Cu 2 (μ-H) Dinuclear Units Supported by Tetraphosphine Ligands
journal, September 2014
- Nakamae, Kanako; Kure, Bunsho; Nakajima, Takayuki
- Chemistry - An Asian Journal, Vol. 9, Issue 11
A Nanospheric Polyhydrido Copper Cluster of Elongated Triangular Orthobicupola Array: Liberation of H 2 from Solar Energy
journal, March 2013
- Dhayal, Rajendra S.; Liao, Jian-Hong; Lin, Yan-Ru
- Journal of the American Chemical Society, Vol. 135, Issue 12
Chinese Puzzle Molecule: A 15 Hydride, 28 Copper Atom Nanoball
journal, May 2014
- Edwards, Alison J.; Dhayal, Rajendra S.; Liao, Ping-Kuei
- Angewandte Chemie International Edition, Vol. 53, Issue 28
Mixed solvents containing methanol as useful reaction media for unique chemoselective reductions within lithium borohydride
journal, October 1986
- Soai, Kenso; Ookawa, Atsuhiro
- The Journal of Organic Chemistry, Vol. 51, Issue 21
Synthesis of a Room-Temperature-Stable Dimeric Copper(I) Hydride
journal, October 2010
- Frey, Guido D.; Donnadieu, Bruno; Soleilhavoup, Michele
- Chemistry - An Asian Journal, Vol. 6, Issue 2
A Thermally Stable Gold(III) Hydride: Synthesis, Reactivity, and Reductive Condensation as a Route to Gold(II) Complexes
journal, September 2012
- Roşca, Dragoş-Adrian; Smith, Dan A.; Hughes, David L.
- Angewandte Chemie International Edition, Vol. 51, Issue 42
Bonding and Reactivity of a μ-Hydrido Dicopper Cation
journal, October 2013
- Wyss, Chelsea M.; Tate, Brandon K.; Bacsa, John
- Angewandte Chemie International Edition, Vol. 52, Issue 49
Correlating the Crystal Structure of A Thiol-Protected Au25 Cluster and Optical Properties
journal, May 2008
- Zhu, Manzhou; Aikens, Christine M.; Hollander, Frederick J.
- Journal of the American Chemical Society, Vol. 130, Issue 18, p. 5883-5885
Anion-templated syntheses of octanuclear silver clusters from a silver dithiophosphate chain
journal, January 2010
- Liu, C. W.; Chang, How-Wei; Fang, Ching-Shiang
- Chemical Communications, Vol. 46, Issue 25
Synthesis of Small Atomic Copper Clusters in Microemulsions
journal, July 2009
- Vázquez-Vázquez, Carlos; Bañobre-López, Manuel; Mitra, Atanu
- Langmuir, Vol. 25, Issue 14
Reactions of a Stable Monomeric Gold(I) Hydride Complex
journal, November 2008
- Tsui, Emily Y.; Müller, Peter; Sadighi, Joseph P.
- Angewandte Chemie International Edition, Vol. 47, Issue 46
Convex Polyhedra with Regular Faces
journal, January 1966
- Johnson, Norman W.
- Canadian Journal of Mathematics, Vol. 18
Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 A Resolution
journal, October 2007
- Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.
- Science, Vol. 318, Issue 5849
Crystal Structure of the Gold Nanoparticle [N(C 8 H 17 ) 4 ][Au 25 (SCH 2 CH 2 Ph) 18 ]
journal, March 2008
- Heaven, Michael W.; Dass, Amala; White, Peter S.
- Journal of the American Chemical Society, Vol. 130, Issue 12
Hydride-mediated homogeneous catalysis. Catalytic reduction of .alpha.,.beta.-unsaturated ketones using [(Ph3P)CuH]6 and H2
journal, November 1989
- Mahoney, Wayne S.; Stryker, Jeffrey M.
- Journal of the American Chemical Society, Vol. 111, Issue 24
Total Structure Determination of Thiolate-Protected Au 38 Nanoparticles
journal, June 2010
- Qian, Huifeng; Eckenhoff, William T.; Zhu, Yan
- Journal of the American Chemical Society, Vol. 132, Issue 24
Synthesis, Structure and Gas-Phase Reactivity of a Silver Hydride Complex [Ag 3 {(PPh 2 ) 2 CH 2 } 3 (μ 3 -H)(μ 3 -Cl)]BF 4
journal, June 2013
- Zavras, Athanasios; Khairallah, George N.; Connell, Timothy U.
- Angewandte Chemie, Vol. 125, Issue 32
Octanuclear Copper(I) Clusters Inscribed in a Se 12 Icosahedron: Anion-Induced Modulation of the Core Size and Symmetry
journal, August 2009
- Liu, C. W.; Sarkar, Bijay; Huang, Yao-Jheng
- Journal of the American Chemical Society, Vol. 131, Issue 31
Synthesis of thiol-derivatised gold nanoparticles in a two-phase Liquid–Liquid system
journal, January 1994
- Brust, Mathias; Walker, Merryl; Bethell, Donald
- J. Chem. Soc., Chem. Commun., Vol. 0, Issue 7
A copper-(.mu.2-hydrogen) bond can be stronger than an intramolecular phosphorus .fwdarw. copper bond. Synthesis and structure of di-.mu.-hydridobis[.eta.2-1,1,1-tris(diphenylphosphinomethyl)ethane]dicopper
journal, July 1986
- Goeden, Gary V.; Huffman, John C.; Caulton, Kenneth G.
- Inorganic Chemistry, Vol. 25, Issue 15
Phosphinothiolates as Ligands for Polyhydrido Copper Nanoclusters
journal, October 2014
- Huertos, Miguel A.; Cano, Israel; Bandeira, Nuno A. G.
- Chemistry - A European Journal, Vol. 20, Issue 49
Works referencing / citing this record:
Development of Copper Nanoclusters for In Vitro and In Vivo Theranostic Applications
journal, January 2020
- Lai, Wing‐Fu; Wong, Wing‐Tak; Rogach, Andrey L.
- Advanced Materials, Vol. 32, Issue 9
Ether‐Soluble Cu 53 Nanoclusters as an Effective Precursor of High‐Quality CuI Films for Optoelectronic Applications
journal, December 2018
- Yuan, Peng; Chen, Ruihao; Zhang, Xiaomin
- Angewandte Chemie
Facially Dispersed Polyhydride Cu 9 and Cu 16 Clusters Comprising Apex‐Truncated Supertetrahedral and Square‐Face‐Capped Cuboctahedral Copper Frameworks
journal, December 2019
- Nakamae, Kanako; Nakajima, Takayuki; Ura, Yasuyuki
- Angewandte Chemie, Vol. 132, Issue 6
Diselenophosphate-Induced Conversion of an Achiral [Cu 20 H 11 {S 2 P(O i Pr) 2 } 9 ] into a Chiral [Cu 20 H 11 {Se 2 P(O i Pr) 2 } 9 ] Polyhydrido Nanocluster
journal, September 2015
- Dhayal, Rajendra S.; Liao, Jian-Hong; Wang, Xiaoping
- Angewandte Chemie International Edition, Vol. 54, Issue 46
[Cu 13 {S 2 CN n Bu 2 } 6 (acetylide) 4 ] + : A Two-Electron Superatom
journal, October 2016
- Chakrahari, Kiran Kumarvarma; Liao, Jian-Hong; Kahlal, Samia
- Angewandte Chemie International Edition, Vol. 55, Issue 47
Molecular Magnesium Hydrides
journal, December 2017
- Mukherjee, Debabrata; Okuda, Jun
- Angewandte Chemie International Edition, Vol. 57, Issue 6
Ether-Soluble Cu 53 Nanoclusters as an Effective Precursor of High-Quality CuI Films for Optoelectronic Applications
journal, December 2018
- Yuan, Peng; Chen, Ruihao; Zhang, Xiaomin
- Angewandte Chemie International Edition, Vol. 58, Issue 3
Synthesis of Bimetallic Copper-Rich Nanoclusters Encapsulating a Linear Palladium Dihydride Unit
journal, March 2019
- Chakrahari, Kiran Kumarvarma; Silalahi, Rhone P. Brocha; Chiu, Tzu-Hao
- Angewandte Chemie International Edition, Vol. 58, Issue 15
[Ag 20 {S 2 P(OR) 2 } 12 ]: A Superatom Complex with a Chiral Metallic Core and High Potential for Isomerism
journal, June 2016
- Dhayal, Rajendra S.; Lin, Yan-Ru; Liao, Jian-Hong
- Chemistry - A European Journal, Vol. 22, Issue 29
A Fluxional Cu 8 H 6 Cluster Supported by Bis(diphenylphosphino)methane and its Facile Reaction with CO 2
journal, May 2017
- Nakamae, Kanako; Tanaka, Miho; Kure, Bunsho
- Chemistry - A European Journal, Vol. 23, Issue 40
Synthesis and X-Ray Crystallographic Characterisation of Frustum-Shaped Ligated [Cu 18 H 16 (DPPE) 6 ] 2+ and [Cu 16 H 14 (DPPA) 6 ] 2+ Nanoclusters and Studies on Their H 2 Evolution Reactions
journal, January 2018
- Li, Jiaye; Ma, Howard Z.; Reid, Gavin E.
- Chemistry - A European Journal, Vol. 24, Issue 9
Hexadecanuclear Copper Monothiocarbonates: An Emissive Cluster Building Block: Hexadecanuclear Copper Monothiocarbonates: An Emissive Cluster Building Block
journal, April 2017
- Gupta, Arvind K.; Kishore, Pilli V. V. N.; Liao, Jian-Hong
- European Journal of Inorganic Chemistry, Vol. 2017, Issue 13
Neutron Instruments for Research in Coordination Chemistry: Neutron Instruments for Research in Coordination Chemistry
journal, January 2019
- Xue, Zi-Ling; Ramirez-Cuesta, Anibal J.; Brown, Craig M.
- European Journal of Inorganic Chemistry, Vol. 2019, Issue 8
Synthesis, Structural Characterization, and H 2 Evolution Study of a Spheroid-Shape Hydride-Rich Copper Nanocluster
journal, March 2018
- Dhayal, Rajendra S.; Chen, Hsuan-Ping; Liao, Jian-Hong
- ChemistrySelect, Vol. 3, Issue 13
Heterodimetallic Ferrocenyl Dithiophosphonate Complexes of Nickel(II), Zinc(II) and Cadmium(II) as Sensitizers for TiO 2 ‐Based Dye‐Sensitized Solar Cells
journal, July 2019
- Ajayi, Tomilola J.; Ollengo, Moses; le Roux, Lukas
- ChemistrySelect, Vol. 4, Issue 25
Hydride Induced Formation and Optical Properties of Tetrahedral [Cu4(μ4-H)(μ2-X)2(PPh2Py)4]+ Clusters (X = Cl, Br; Py = pyridyl)
journal, March 2018
- Nie, Hong-Hong; Han, Ying-Zi; Tang, Zichao
- Journal of Cluster Science, Vol. 29, Issue 5
Copper hydride clusters in energy storage and conversion
journal, January 2019
- Dhayal, Rajendra S.; van Zyl, Werner E.; Liu, C. W.
- Dalton Transactions, Vol. 48, Issue 11
Diselenophosphate-Induced Conversion of an Achiral [Cu 20 H 11 {S 2 P(O i Pr) 2 } 9 ] into a Chiral [Cu 20 H 11 {Se 2 P(O i Pr) 2 } 9 ] Polyhydrido Nanocluster
journal, September 2015
- Dhayal, Rajendra S.; Liao, Jian-Hong; Wang, Xiaoping
- Angewandte Chemie, Vol. 127, Issue 46
Synthesis of Bimetallic Copper‐Rich Nanoclusters Encapsulating a Linear Palladium Dihydride Unit
journal, March 2019
- Chakrahari, Kiran Kumarvarma; Silalahi, Rhone P. Brocha; Chiu, Tzu‐Hao
- Angewandte Chemie, Vol. 131, Issue 15
Facially Dispersed Polyhydride Cu 9 and Cu 16 Clusters Comprising Apex‐Truncated Supertetrahedral and Square‐Face‐Capped Cuboctahedral Copper Frameworks
journal, February 2020
- Nakamae, Kanako; Nakajima, Takayuki; Ura, Yasuyuki
- Angewandte Chemie International Edition, Vol. 59, Issue 6
Figures / Tables found in this record: