Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage
Abstract
Abstract Herein we develop a chemical etching method to produce porous two‐dimensional (2D) Ti 3 C 2 T x MXenes at room temperature in aqueous solutions. The as‐produced porous Ti 3 C 2 T x (p‐Ti 3 C 2 T x ) have larger specific surface areas and more open structures than their pristine counterparts, and can be fabricated into flexible films with, or without, the addition of carbon nanotubes (CNTs). The as‐fabricated p‐Ti 3 C 2 T x /CNT films showed significantly improved lithium ion storage capabilities compared to pristine Ti 3 C 2 T x based films, with a very high capacity of ≈1250 mAh g −1 at 0.1 C, excellent cycling stability, and good rate performance (330 mAh g −1 at 10 C). Using the same chemical etching method, we also made porous Nb 2 CT x and V 2 CT x MXenes. Therefore, this study provides a simple, yet effective, procedure to introduce pores into MXenes and possibly other 2D sheets that in turn, can enhance their electrochemical properties.
- Authors:
-
- Drexel Univ., Philadelphia, PA (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1261374
- Alternate Identifier(s):
- OSTI ID: 1401647
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemElectroChem
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 5; Journal ID: ISSN 2196-0216
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Ren, Chang E., Zhao, M-Q, Makaryan, Taron, Halim, Joseph, Boota, M., Kota, Sankalp, Anasori, Babak, Barsoum, M W, and Gogotsi, Yury. Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage. United States: N. p., 2016.
Web. doi:10.1002/celc.201600059.
Ren, Chang E., Zhao, M-Q, Makaryan, Taron, Halim, Joseph, Boota, M., Kota, Sankalp, Anasori, Babak, Barsoum, M W, & Gogotsi, Yury. Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage. United States. https://doi.org/10.1002/celc.201600059
Ren, Chang E., Zhao, M-Q, Makaryan, Taron, Halim, Joseph, Boota, M., Kota, Sankalp, Anasori, Babak, Barsoum, M W, and Gogotsi, Yury. Tue .
"Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage". United States. https://doi.org/10.1002/celc.201600059. https://www.osti.gov/servlets/purl/1261374.
@article{osti_1261374,
title = {Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage},
author = {Ren, Chang E. and Zhao, M-Q and Makaryan, Taron and Halim, Joseph and Boota, M. and Kota, Sankalp and Anasori, Babak and Barsoum, M W and Gogotsi, Yury},
abstractNote = {Abstract Herein we develop a chemical etching method to produce porous two‐dimensional (2D) Ti 3 C 2 T x MXenes at room temperature in aqueous solutions. The as‐produced porous Ti 3 C 2 T x (p‐Ti 3 C 2 T x ) have larger specific surface areas and more open structures than their pristine counterparts, and can be fabricated into flexible films with, or without, the addition of carbon nanotubes (CNTs). The as‐fabricated p‐Ti 3 C 2 T x /CNT films showed significantly improved lithium ion storage capabilities compared to pristine Ti 3 C 2 T x based films, with a very high capacity of ≈1250 mAh g −1 at 0.1 C, excellent cycling stability, and good rate performance (330 mAh g −1 at 10 C). Using the same chemical etching method, we also made porous Nb 2 CT x and V 2 CT x MXenes. Therefore, this study provides a simple, yet effective, procedure to introduce pores into MXenes and possibly other 2D sheets that in turn, can enhance their electrochemical properties.},
doi = {10.1002/celc.201600059},
journal = {ChemElectroChem},
number = 5,
volume = 3,
place = {United States},
year = {Tue Feb 16 00:00:00 EST 2016},
month = {Tue Feb 16 00:00:00 EST 2016}
}
Web of Science
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