Characteristic Features of Water Dynamics in Restricted Geometries Investigated with Quasi-Elastic Neutron Scattering

Osti, Naresh C.; Mamontov, Eugene; Ramirez-cuesta, A.; Wesolowski, David J.; Diallo, S. O.

doi:10.1016/j.chemphys.2015.11.008

Title: Characteristic Features of Water Dynamics in Restricted Geometries Investigated with Quasi-Elastic Neutron Scattering

Journal Article · 09 December 2015 · Chemical Physics

DOI: https://doi.org/10.1016/j.chemphys.2015.11.008 · OSTI ID:1261371

Osti, Naresh C. ^[1]; Mamontov, Eugene ^[1]; Ramirez-cuesta, A. ^[1]; Wesolowski, David J. ^[1]; Diallo, S. O. ^[2]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Ames Lab., Ames, IA (United States)

Understanding the molecular behavior of water in spatially restricted environments is important to better understanding its role in many biological, chemical and geological processes. Here we examine the translational diffusion of water confined to a variety of substrates, from flat surfaces to nanoporous media, in the context of a recently proposed universal scaling law (Chiavazzo 2014) [1]. Using over a dozen previous neutron scattering results, we test the validity of this law, evaluating separately the influence of the hydration amount, and the effects of the size and morphology of the confining medium. Additionally, we investigate the effects of changing instrument resolutions and fitting models on the applicability of this law. Finally, we perform quasi-elastic neutron scattering measurements on water confined inside nanoporous silica to further evaluate this predictive law, in the temperature range 250≤T≤290 K.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1261371

Journal Information:: Chemical Physics, Journal Name: Chemical Physics Vol. 465-466; ISSN 0301-0104

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (37)

A quasi-elastic neutron scattering study of the dynamics of supercritical water Beta, I. A.; Li, J. -C.; Bellissent-Funel, M. -C. Chemical Physics, Vol. 292, Issue 2-3 https://doi.org/10.1016/S0301-0104(03)00228-3	journal	August 2003
Dynamics of Biological Macromolecules: Not a Simple Slaving by Hydration Water Khodadadi, S.; Roh, J. H.; Kisliuk, A. Biophysical Journal, Vol. 98, Issue 7 https://doi.org/10.1016/j.bpj.2009.12.4284	journal	April 2010
Dynamics of Protein and its Hydration Water: Neutron Scattering Studies on Fully Deuterated GFP Nickels, Jonathan D.; O’Neill, Hugh; Hong, Liang Biophysical Journal, Vol. 103, Issue 7 https://doi.org/10.1016/j.bpj.2012.08.046	journal	October 2012
Mantid—Data analysis and visualization package for neutron scattering and μ SR experiments Arnold, O.; Bilheux, J. C.; Borreguero, J. M. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 764 https://doi.org/10.1016/j.nima.2014.07.029	journal	November 2014
The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms Barrett, Elliott P.; Joyner, Leslie G.; Halenda, Paul P. Journal of the American Chemical Society, Vol. 73, Issue 1 https://doi.org/10.1021/ja01145a126	journal	January 1951
Adsorption of Gases in Multimolecular Layers Brunauer, Stephen; Emmett, P. H.; Teller, Edward Journal of the American Chemical Society, Vol. 60, Issue 2, p. 309-319 https://doi.org/10.1021/ja01269a023	journal	February 1938
Neutron Scattering Study and Dynamic Properties of Hydrogen-Bonded Liquids in Mesoscopic Confinement. 2. The Zeolitic Water Case Crupi, Vincenza; Majolino, Domenico; Migliardo, Placido The Journal of Physical Chemistry B, Vol. 108, Issue 14 https://doi.org/10.1021/jp037171l	journal	April 2004
Neutron Scattering Study on Dynamics of Water Molecules in MCM-41. 2. Determination of Translational Diffusion Coefficient Takahara, Shuichi; Sumiyama, Naoya; Kittaka, Shigeharu The Journal of Physical Chemistry B, Vol. 109, Issue 22 https://doi.org/10.1021/jp046036l	journal	June 2005
Temperature-Dependent Dynamics of Water Confined in Nafion Membranes Paciaroni, A.; Casciola, M.; Cornicchi, E. The Journal of Physical Chemistry B, Vol. 110, Issue 28 https://doi.org/10.1021/jp0572176	journal	July 2006
Water Dynamics in Hardened Ordinary Portland Cement Paste or Concrete: From Quasielastic Neutron Scattering Bordallo, Heloisa N.; Aldridge, Laurence P.; Desmedt, Arnaud The Journal of Physical Chemistry B, Vol. 110, Issue 36 https://doi.org/10.1021/jp062922f	journal	September 2006
Water Dynamics in Graphite Oxide Investigated with Neutron Scattering Buchsteiner, Alexandra; Lerf, Anton; Pieper, Jörg The Journal of Physical Chemistry B, Vol. 110, Issue 45 https://doi.org/10.1021/jp0641132	journal	November 2006
Quasielastic Neutron Scattering Study of Water Dynamics in Hydrated Nafion Membranes Perrin, Jean-Christophe; Lyonnard, Sandrine; Volino, Ferdinand The Journal of Physical Chemistry C, Vol. 111, Issue 8 https://doi.org/10.1021/jp065039q	journal	January 2007
Quasi-Elastic Neutron Scattering Studies on Dynamics of Water Confined in Nanoporous Copper Rubeanate Hydrates Yamada, Takeshi; Yonamine, Ryo; Yamada, Teppei The Journal of Physical Chemistry B, Vol. 115, Issue 46 https://doi.org/10.1021/jp2029467	journal	November 2011
Impact of Pore Size and Pore Surface Composition on the Dynamics of Confined Water in Highly Ordered Porous Silica Briman, Ibrahim Matar; Rébiscoul, Diane; Diat, Olivier The Journal of Physical Chemistry C, Vol. 116, Issue 12 https://doi.org/10.1021/jp3001898	journal	March 2012
Impact of Hydrophilic Surfaces on Interfacial Water Dynamics Probed with NMR Spectroscopy Yoo, Hyok; Paranji, Rajan; Pollack, Gerald H. The Journal of Physical Chemistry Letters, Vol. 2, Issue 6 https://doi.org/10.1021/jz200057g	journal	February 2011
Dynamic Crossovers and Stepwise Solidification of Confined Water: A ² H NMR Study Sattig, M.; Vogel, M. The Journal of Physical Chemistry Letters, Vol. 5, Issue 1 https://doi.org/10.1021/jz402539r	journal	December 2013
Water Diffusion in Polymer-like Reverse Micelles. 2. Composition Dependence ^† Angelico, R.; Balinov, B.; Ceglie, A. Langmuir, Vol. 15, Issue 5 https://doi.org/10.1021/la9813782	journal	March 1999
Dynamics of supercooled water in confined geometry Bergman, R.; Swenson, J. Nature, Vol. 403, Issue 6767 https://doi.org/10.1038/35002027	journal	January 2000
Dynamics of water confined to reverse AOT micelles Spehr, Tinka Luise; Frick, Bernhard; Zamponi, Michaela Soft Matter, Vol. 7, Issue 12 https://doi.org/10.1039/c1sm05204g	journal	January 2011
Synthesis of highly ordered mesoporous materials from a layered polysilicate Inagaki, S.; Fukushima, Y.; Kuroda, K. Journal of the Chemical Society, Chemical Communications, Issue 8 https://doi.org/10.1039/c39930000680	journal	January 1993
Slow dynamics of water molecules on the surface of a globular protein Bellissent-Funel, Marie-Claire; Zanotti, Jean-Marc; Chen, Sow Hsin Faraday Discussions, Vol. 103 https://doi.org/10.1039/fd9960300281	journal	January 1996
Quasielastic neutron scattering of two-dimensional water in a vermiculite clay Swenson, J.; Bergman, R.; Howells, W. S. The Journal of Chemical Physics, Vol. 113, Issue 7 https://doi.org/10.1063/1.1305870	journal	August 2000
Fluid structure and transport properties of water inside carbon nanotubes Liu, Yingchun; Wang, Qi; Wu, Tao The Journal of Chemical Physics, Vol. 123, Issue 23 https://doi.org/10.1063/1.2131070	journal	December 2005
Dynamics of water confined in single- and double-wall carbon nanotubes Mamontov, E.; Burnham, C. J.; Chen, S. -H. The Journal of Chemical Physics, Vol. 124, Issue 19 https://doi.org/10.1063/1.2194020	journal	May 2006
Single particle dynamics of water confined in a hydrophobically modified MCM-41-S nanoporous matrix Faraone, Antonio; Liu, Kao-Hsiang; Mou, Chung-Yuan The Journal of Chemical Physics, Vol. 130, Issue 13 https://doi.org/10.1063/1.3097800	journal	April 2009
A time-of-flight backscattering spectrometer at the Spallation Neutron Source, BASIS Mamontov, E.; Herwig, K. W. Review of Scientific Instruments, Vol. 82, Issue 8 https://doi.org/10.1063/1.3626214	journal	August 2011
The violation of the Stokes-Einstein relation in supercooled water Chen, S. -H.; Mallamace, F.; Mou, C. -Y. Proceedings of the National Academy of Sciences, Vol. 103, Issue 35 https://doi.org/10.1073/pnas.0603253103	journal	August 2006
Dynamics of supercooled water in highly compacted clays studied by neutron scattering González Sánchez, Fátima; Jurányi, Fanni; Gimmi, Thomas Journal of Physics: Condensed Matter, Vol. 20, Issue 41 https://doi.org/10.1088/0953-8984/20/41/415102	journal	September 2008
Diffusion of water adsorbed in hydrotalcite: neutron scattering Study Mitra, S.; Pramanik, A.; Chakrabarty, D. Journal of Physics: Conference Series, Vol. 92 https://doi.org/10.1088/1742-6596/92/1/012167	journal	June 2007
Experimental determination of the nature of diffusive motions of water molecules at low temperatures Teixeira, J.; Bellissent-Funel, M. -C.; Chen, S. H. Physical Review A, Vol. 31, Issue 3 https://doi.org/10.1103/PhysRevA.31.1913	journal	March 1985
Single-particle dynamics of water molecules in confined space Bellissent-Funel, M. -C.; Chen, S. H.; Zanotti, J. -M. Physical Review E, Vol. 51, Issue 5 https://doi.org/10.1103/PhysRevE.51.4558	journal	May 1995
Neutron spectroscopy of water dynamics in NaX and NaA zeolites Kamitakahara, William A.; Wada, Noboru Physical Review E, Vol. 77, Issue 4 https://doi.org/10.1103/PhysRevE.77.041503	journal	April 2008
Dynamic behavior of hydration water in calcium-silicate-hydrate gel: A quasielastic neutron scattering spectroscopy investigation Li, Hua; Fratini, Emiliano; Chiang, Wei-Shan Physical Review E, Vol. 86, Issue 6 https://doi.org/10.1103/PhysRevE.86.061505	journal	December 2012
Slow Dynamics of Water Molecules in Supercooled States Gallo, P.; Sciortino, F.; Tartaglia, P. Physical Review Letters, Vol. 76, Issue 15 https://doi.org/10.1103/PhysRevLett.76.2730	journal	April 1996
Anomalously Soft Dynamics of Water in a Nanotube: A Revelation of Nanoscale Confinement Kolesnikov, Alexander I.; Zanotti, Jean-Marc; Loong, Chun-Keung Physical Review Letters, Vol. 93, Issue 3 https://doi.org/10.1103/PhysRevLett.93.035503	journal	July 2004
Status of experiments probing the dynamics of water in confinement Bellissent-Funel, M. -C. The European Physical Journal E, Vol. 12, Issue 1 https://doi.org/10.1140/epje/i2003-10023-9	journal	September 2003
DAVE: A Comprehensive Software Suite for the Reduction, Visualization, and Analysis of Low Energy Neutron Spectroscopic Data Azuah, Richard Tumanjong; Kneller, Larry R.; Qiu, Yiming Journal of Research of the National Institute of Standards and Technology, Vol. 114, Issue 6 https://doi.org/10.6028/jres.114.025	journal	November 2009

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Structure and Dynamics of Confined C-O-H Fluids Relevant to the Subsurface: Application of Magnetic Resonance, Neutron Scattering, and Molecular Dynamics Simulations Gautam, Siddharth S.; Ok, Salim; Cole, David R. Frontiers in Earth Science, Vol. 5 https://doi.org/10.3389/feart.2017.00043	journal	June 2017
Computational Insights into Materials and Interfaces for Capacitive Energy Storage Zhan, Cheng; Lian, Cheng; Zhang, Yu Advanced Science, Vol. 4, Issue 7 https://doi.org/10.1002/advs.201700059	journal	April 2017
Soft biomimetic nanoconfinement promotes amorphous water over ice Salvati Manni, Livia; Assenza, Salvatore; Duss, Michael Nature Nanotechnology, Vol. 14, Issue 6 https://doi.org/10.1038/s41565-019-0415-0	journal	April 2019
In Vivo Water Dynamics in Shewanella oneidensis Bacteria at High Pressure Foglia, Fabrizia; Hazael, Rachael; Meersman, Filip Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-44704-3	journal	June 2019
Insights into the thermal and chemical stability of multilayered V ₂ CT _x MXene Thakur, Raj; VahidMohammadi, Armin; Moncada, Jorge Nanoscale, Vol. 11, Issue 22 https://doi.org/10.1039/c9nr03020d	journal	January 2019
Microscopic dynamics in room-temperature ionic liquids confined in materials for supercapacitor applications Osti, Naresh C.; Mamontov, Eugene Sustainable Energy & Fuels, Vol. 4, Issue 4 https://doi.org/10.1039/c9se00829b	journal	January 2020
Vibrational dynamics of confined supercooled water Stefanutti, E.; Bove, L. E.; Alabarse, F. G. The Journal of Chemical Physics, Vol. 150, Issue 22 https://doi.org/10.1063/1.5094147	journal	June 2019
Thermal transport phenomena in nanoparticle suspensions Cardellini, Annalisa; Fasano, Matteo; Bozorg Bigdeli, Masoud Journal of Physics: Condensed Matter, Vol. 28, Issue 48 https://doi.org/10.1088/0953-8984/28/48/483003	journal	October 2016
Influence of metal ions intercalation on the vibrational dynamics of water confined between MXene layers Osti, Naresh C.; Naguib, Michael; Ganeshan, Karthik Physical Review Materials, Vol. 1, Issue 6 https://doi.org/10.1103/physrevmaterials.1.065406	journal	November 2017
Cation Molecular Structure Affects Mobility and Transport of Electrolytes in Porous Carbons Osti, Naresh C.; Dyatkin, Boris; Gallegos, Alejandro Journal of The Electrochemical Society, Vol. 166, Issue 4 https://doi.org/10.1149/2.0131904jes	journal	January 2019
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