Transition metal redox and Mn disproportional reaction in LiMn0.5Fe0.5PO4 electrodes cycled with aqueous electrolyte

Zhuo, Zengqing; Hu, Jiangtao; Duan, Yandong; Yang, Wanli; Pan, Feng

doi:10.1063/1.4958639

Title: Transition metal redox and Mn disproportional reaction in LiMn0.5Fe0.5PO4 electrodes cycled with aqueous electrolyte

Authors:

Zhuo, Zengqing ^[1]; Hu, Jiangtao ^[2]; Duan, Yandong ^[2]; Yang, Wanli ^[3]; Pan, Feng ^[2]

School of Advanced Materials, Peking University, Shenzhen Graduate School, Shenzhen 518055, People's Republic of China, Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720, USA
School of Advanced Materials, Peking University, Shenzhen Graduate School, Shenzhen 518055, People's Republic of China
Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720, USA

Publication Date:: Mon Jul 11 00:00:00 EDT 2016

Sponsoring Org.:: USDOE

OSTI Identifier:: 1261220

Grant/Contract Number:: No. DE-AC02-05CH11231

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Applied Physics Letters

Additional Journal Information:: Journal Name: Applied Physics Letters Journal Volume: 109 Journal Issue: 2; Journal ID: ISSN 0003-6951

Publisher:: American Institute of Physics

Country of Publication:: United States

Language:: English

Citation Formats


                    Zhuo, Zengqing, Hu, Jiangtao, Duan, Yandong, Yang, Wanli, and Pan, Feng. Transition metal redox and Mn disproportional reaction in LiMn0.5Fe0.5PO4 electrodes cycled with aqueous electrolyte.  United States: N. p., 2016. 
Web.  doi:10.1063/1.4958639.

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                    Zhuo, Zengqing, Hu, Jiangtao, Duan, Yandong, Yang, Wanli, & Pan, Feng. Transition metal redox and Mn disproportional reaction in LiMn0.5Fe0.5PO4 electrodes cycled with aqueous electrolyte.  United States.  https://doi.org/10.1063/1.4958639

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                    Zhuo, Zengqing, Hu, Jiangtao, Duan, Yandong, Yang, Wanli, and Pan, Feng. Mon .  
"Transition metal redox and Mn disproportional reaction in LiMn0.5Fe0.5PO4 electrodes cycled with aqueous electrolyte".  United States.  https://doi.org/10.1063/1.4958639.

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@article{osti_1261220,

  title        = {Transition metal redox and Mn disproportional reaction in LiMn0.5Fe0.5PO4 electrodes cycled with aqueous electrolyte},

  author       = {Zhuo, Zengqing and Hu, Jiangtao and Duan, Yandong and Yang, Wanli and Pan, Feng},

  abstractNote = {},

  doi          = {10.1063/1.4958639},

  journal      = {Applied Physics Letters},

  number       = 2,

  volume       = 109,

  place        = {United States},

  year         = {Mon Jul 11 00:00:00 EDT 2016},

  month        = {Mon Jul 11 00:00:00 EDT 2016}

}

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Title: Transition metal redox and Mn disproportional reaction in LiMn0.5Fe0.5PO4 electrodes cycled with aqueous electrolyte

Citation Formats

Mechanism of the Delithiation/Lithiation Process in LiFe 0.4 Mn 0.6 PO 4 : in Situ and ex Situ Investigations on Long-Range and Local Structures journal, April 2015

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LiMn 0.8 Fe 0.2 PO 4 : An Advanced Cathode Material for Rechargeable Lithium Batteries journal, October 2009

Rhombohedral Prussian White as Cathode for Rechargeable Sodium-Ion Batteries journal, February 2015

LiMn1−xFexPO4 Nanorods Grown on Graphene Sheets for Ultrahigh-Rate-Performance Lithium Ion Batteries journal, June 2011

Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides journal, May 2013

Extended Solid Solutions and Coherent Transformations in Nanoscale Olivine Cathodes journal, February 2014

Resonant inelastic X-ray scattering and X-ray absorption spectroscopy on the cathode materials LiMnPO4 and LiMn0.9Fe0.1PO4––a comparative study journal, January 2011

Structural Fatigue in Spinel Electrodes in High Voltage (4 V) Li/Li[sub x]Mn[sub 2]O[sub 4] Cells journal, January 1999

Direct evidence of gradient Mn(II) evolution at charged states in LiNi0.5Mn1.5O4 electrodes with capacity fading journal, January 2015

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Effect of Structure on the Fe[sup 3+]∕Fe[sup 2+] Redox Couple in Iron Phosphates journal, January 1997

Elucidating the Nature of Pseudo Jahn–Teller Distortions in Li x MnPO 4 : Combining Density Functional Theory with Soft and Hard X-ray Spectroscopy journal, May 2013

Resonant photoemission spectroscopy of the cathode material LixMn0.5Fe0.5PO4 for lithium-ion battery journal, March 2013

Phase Transformation and Lithiation Effect on Electronic Structure of Li x FePO 4 : An In-Depth Study by Soft X-ray and Simulations journal, August 2012

The Electrode/Electrolyte Reactivity of LiFe 0.33 Mn 0.67 PO 4 Compared to LiFePO 4 journal, December 2012

Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries journal, April 1997

Key electronic states in lithium battery materials probed by soft X-ray spectroscopy journal, October 2013

Solvothermal Synthesis of LiMn 1– x Fe x PO 4 Cathode Materials: A Study of Reaction Mechanisms by Time-Resolved in Situ Synchrotron X-ray Diffraction journal, January 2015

Enhancing the High-Voltage Cycling Performance of LiNi 0.5 Mn 0.3 Co 0.2 O 2 by Retarding Its Interfacial Reaction with an Electrolyte by Atomic-Layer-Deposited Al 2 O 3 journal, November 2015

Mechanism of the Delithiation/Lithiation Process in LiFe _0.4 Mn _0.6 PO ₄ : in Situ and ex Situ Investigations on Long-Range and Local Structures
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Challenges for Rechargeable Li Batteries
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LiMn _0.8 Fe _0.2 PO ₄ : An Advanced Cathode Material for Rechargeable Lithium Batteries
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Solvothermal Synthesis of LiMn _{1– x} Fe _x PO ₄ Cathode Materials: A Study of Reaction Mechanisms by Time-Resolved in Situ Synchrotron X-ray Diffraction
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